6533b871fe1ef96bd12d1a37

RESEARCH PRODUCT

Metal-free regioselective C–C bond cleavage in 1,3,5-triazine derivatives of β-diketones

Armando J. L. PombeiroMatti HaukkaKamran T. MahmudovKamran T. MahmudovMaximilian N. Kopylovich

subject

ChemistryHydrogen bondRegioselectivityGeneral ChemistryCatalysisCatalysischemistry.chemical_compound135-TriazineMetal freeIntramolecular forcePolymer chemistryMaterials ChemistryOrganic chemistryta116Bond cleavage

description

Metal-free regioselective activation of a carbon–carbon bond in 1,3,5-triazine derivatives of β-diketones is easily achieved, in the absence of a catalyst, with the assistance of intramolecular hydrogen bonding.

https://doi.org/10.1039/c3nj01292a