6533b871fe1ef96bd12d222d
RESEARCH PRODUCT
Tetranitroresorcin[4]arene: synthesis and structure of a new stereoisomer
N. Kodiah BeyehKari Rissanensubject
Crystallography1h nmr spectroscopychemistry.chemical_compoundchemistryYield (chemistry)Electrospray ionizationOrganic ChemistryDrug DiscoverySolid-stateAcetaldehydeDirect reactionBiochemistrySingle crystaldescription
The direct reaction between 2-nitroresorcinol and acetaldehyde in alkaline medium yields tetranitro-C1-resorcin[4]arene in a moderate 8.2% overall yield which was characterized by single crystal X-ray crystallography, 1H NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS). In solution and in the solid state, the product adopts a unique, thermally stable and unprecedented rcct-boat conformation.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-12-01 | Tetrahedron Letters |