6533b871fe1ef96bd12d264d
RESEARCH PRODUCT
3d/4f Sandwich Complex Based on Metallacrowns.
Andreas RauguthAlexander KredelEva RentschlerLuca M. Carrellasubject
Inorganic ChemistryLanthanideMagnetic measurementsNickelCrystallographyCoordination sphereZero fieldChemistrychemistry.chemical_elementPhysical and Theoretical ChemistryMetallacrownIondescription
A novel lanthanide double-decker complex with nickel metallacrowns (MCs) as coordinating ligands has been synthesized. In the 3d/4f metallacrown complex TbIII[12-MCNiIIN(shi)-4]2, the central lanthanide ion is sandwiched between two [12-MC-4] units, forming an almost ideal square-antiprismatic coordination sphere. The resulting zenithal angles at the central lanthanide ion are smaller than those for previously reported sandwich compounds. Magnetic measurements reveal an energy barrier of 346 K under zero field and up to 585 K under 3200 Oe, the highest reported for metallacrowns with D4d symmetry.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-08-31 | Inorganic chemistry |