Preparation of 4-substituted 1,3-oxathiolan-5-onesviathe sulphenium ion intermediate generated by the pummerer rearrangement

6533b872fe1ef96bd12d2c6d

RESEARCH PRODUCT

Preparation of 4-substituted 1,3-oxathiolan-5-onesviathe sulphenium ion intermediate generated by the pummerer rearrangement

Teresa Picher Jose Antonio Ramirez Vicente Añó Sanz J. V. Frechina Pedro Palanca

subject

chemistry.chemical_classification chemistry.chemical_compound Chemistry Pummerer rearrangement Organic Chemistry Pyridine Thiolactone Molecule Medicinal chemistry Lactone Ion

description

4-Substituted 1,3-oxathiolan-5-ones have been synthesized via the Pummerer rearrangement from the S-oxide of the parent molecule. The 4,5-dione is obtained in the presence of pyridine N-oxide.

year	journal	country	edition	language
1993-05-01	Journal of Heterocyclic Chemistry

https://doi.org/10.1002/jhet.5570300314

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