6533b872fe1ef96bd12d2dfb
RESEARCH PRODUCT
Optical and magneto‐optical studies of Mn‐activated LiBaF 3
Uldis RogulisUldis RogulisM. SecuJ.-m. SpaethB. HenkeStefan Schweizersubject
Emission bandPhotoluminescenceDopantMagnetic circular dichroismlawChemistryAnalytical chemistryElectron paramagnetic resonanceExcitationMagneto opticallaw.inventiondescription
The photoluminescence (PL) of Mn-doped LiBaF3 shows a weak Mn2+ emission band at 710 nm; the corresponding excitation bands are between 210 and 620 nm. After X-irradiation the PL spectrum shows two new bands peaking at 600 and 670 nm that are tentatively assigned to perturbed Mn2+ emissions; the intensity of all PL bands is increased. Magnetic circular dichroism (MCD) and the MCD-detected electron paramagnetic resonance (EPR) measurements show that F-type centres are formed after X-irradiation. The EPR measurements indicate that there is a spatial correlation between the F-type centre and the Mn2+ dopant. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-01-01 | physica status solidi (c) |