Pd2Au36(SR)(24) cluster: structure studies

6533b872fe1ef96bd12d2f4a

RESEARCH PRODUCT

Pd2Au36(SR)(24) cluster: structure studies

Elina Kalenius Bei Zhang Noelia Barrabés Sameh Kaziz Hannu Häkkinen Igor Dolamic Olga V. Safonova Thomas Bürgi Sami Malola Jordi Llorca Dawid Wodka Clément Mazet Latévi Max Lawson Daku Houhua Li Maarten Nachtegaal

subject

spectroscopy Atoms Electronic-properties nanoclusters Mass-spectrometry chemistry.chemical_element Nanotechnology Crystal structure Spectral line Àtoms Condensed Matter::Materials Science X-ray photoelectron spectroscopy Optical-properties Condensed Matter::Superconductivity Ray-absorption spectroscopy Cluster (physics):Física::Electromagnetisme [Àrees temàtiques de la UPC]General Materials Science Gold nanoclusters ta116 Theoretical-analysis ta114 Extended X-ray absorption fine structure Doping Protected au-25 nanoclusters Espectroscòpia de raigs X Crystallography Ligand-exchange chemistry Crystal-structure ddc:540 X-ray spectroscopy Nanoparticles :Física::Física molecular [Àrees temàtiques de la UPC]Absorption (chemistry)Palladium

description

The location of the Pd atoms in Pd2Au36(SC2H4Ph)(24), is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.

year	journal	country	edition	language
2015-09-30

10.1039/c5nr04324g https://dx.doi.org/10.1039/c5nr04324g

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