6533b872fe1ef96bd12d36b3
RESEARCH PRODUCT
Inside Cover: Bidirectional Chemo-Switching of Spin State in a Microporous Framework (Angew. Chem. Int. Ed. 26/2009)
Ana B. GasparMasaaki OhbaMikio YamasakiShigeyoshi SakakiM. Carmen MuñozSusumu KitagawaHideo AndoJosé Antonio RealGloria AgustíYoshihide NakaoKo Yonedasubject
Spin statesChemistryMagnetismCoordination polymerNanotechnologyGeneral ChemistryMicroporous materialCatalysisParamagnetismCrystallographychemistry.chemical_compoundSpin crossoverDiamagnetismCondensed Matter::Strongly Correlated ElectronsMetal-organic frameworkdescription
Bidirectional chemo-switching of magnetism occurs in a microporous coordination polymer containing spin-crossover subunits, as described by M. Ohba, J. A. Real, S. Kitagawa, and co-workers in their Communication on page 4767 ff. In situ magnetic measurements reveal that most guest molecules transform the framework spin state from diamagnetic low spin (red) to paramagnetic high spin (yellow), whereas the guest CS2 stabilizes the low-spin state. These induced spin states are retained as a memory effect after the release of the guest.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-06-15 | Angewandte Chemie International Edition |