6533b872fe1ef96bd12d37a0

RESEARCH PRODUCT

Syntheses, Mössbauer and infrared spectroscopic investigations on tin(II) chloride adducts with purine and pyrimidine bases and nucleosides

Susan M. GrimesJohn D. DonaldsonM.t. Lo GiudiceLorenzo PelleritoGiuseppe Ruisi

subject

PyrimidineInorganic chemistrychemistry.chemical_elementTin(II) chlorideCytidineChlorideAdductInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMaterials ChemistrymedicinePhysical and Theoretical ChemistryTinInosineCytosinemedicine.drug

description

Abstract The synthesis of two types of tin(II) complex SnCl2·L·CH3OH (L = adenosine, cytidine and inosine) and SnCl2·L2·CH3OH (L = adenine and cytosine) are described. The complexes are characterised by their infrared and 119Sn Mossbauer data. The Mossbauer shift data suggest that the bonds between tin(II) chloride and the donor atoms of the ligands are relatively weak.

https://doi.org/10.1016/s0020-1693(00)90218-4