6533b872fe1ef96bd12d3804
RESEARCH PRODUCT
Apparent content curves: description and analytical applications. Resolution of binary mixtures
M. D. San Martín CigesM. Llobat EstellésR. Marín Saezsubject
AnalyteAbsorption spectroscopyResolution (mass spectrometry)ChemistryComponent (thermodynamics)Content (measure theory)Analytical chemistryBinary numberInterference (wave propagation)Biological systemBiochemistryAnalytical Chemistrydescription
The apparent content curves and their analytical applications are described. Basing on these curves a mathematical method, which permits the identification of the interfering component present in a binary mixture as well as the determination of the contents of both constituents, is proposed. The existence of considerable interaction coefficients is not an impediment for its application. Besides, the analyte contents in the mixture can be obtained without the use of standard interference solutions. The proposed procedure is applied to the analysis of mixtures of dyes with overlapping absorption spectra.
year | journal | country | edition | language |
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1992-01-01 | Fresenius' Journal of Analytical Chemistry |