6533b872fe1ef96bd12d3804

RESEARCH PRODUCT

Apparent content curves: description and analytical applications. Resolution of binary mixtures

M. D. San Martín CigesM. Llobat EstellésR. Marín Saez

subject

AnalyteAbsorption spectroscopyResolution (mass spectrometry)ChemistryComponent (thermodynamics)Content (measure theory)Analytical chemistryBinary numberInterference (wave propagation)Biological systemBiochemistryAnalytical Chemistry

description

The apparent content curves and their analytical applications are described. Basing on these curves a mathematical method, which permits the identification of the interfering component present in a binary mixture as well as the determination of the contents of both constituents, is proposed. The existence of considerable interaction coefficients is not an impediment for its application. Besides, the analyte contents in the mixture can be obtained without the use of standard interference solutions. The proposed procedure is applied to the analysis of mixtures of dyes with overlapping absorption spectra.

https://doi.org/10.1007/bf00321910