6533b872fe1ef96bd12d3a45

RESEARCH PRODUCT

All-experimental values of self-quenching cross-sections for nf states (n=5-8) of potassium atoms

J. KlavinsA. HuzandrovI. SydorykJ. SzonertM. Głódź

subject

DipoleMaterials scienceQuenching (fluorescence)chemistryPotassiumQuadrupoleAnalytical chemistryGeneral Physics and Astronomychemistry.chemical_elementAtomic physicsFluorescenceExcitation

description

All-experimental self-quenching cross-sections σ nf are reported for K(nf) states (n = 5, 6, 7, 8). The experiment was performed at varied temperatures of K vapour in a spectral cell. Time-resolved fluorescence was observed following pulsed step-wise excitation with dipole and quadrupole transitions K(4s) → K(4p) → K(nf). The values: σ 5f = 2.4 ± 1.7, σ 6f = 4.5±1.4, σ 7f = 8.1±1.8, and σ 8f = 18.2±3.0 (in units of 10−13 cm−1) were obtained from a Stern-Volmer-type plot.

https://publons.com/publon/7982263/