6533b873fe1ef96bd12d4b6e

RESEARCH PRODUCT

Palladium-Catalyzed Alkoxy- and Aminocarbonylation of α-Halomethyl Oxime Ethers: Synthesis of 1,3-Alkoxyimino Esters and 1,3-Alkoxyimino Amides

Bárbara NovergesGregorio AsensioMercedes Medio-simón

subject

Regioselectivitychemistry.chemical_elementGeneral ChemistryOximeCatalysischemistry.chemical_compoundchemistryAlkoxy groupOrganic chemistryheterocyclic compoundsCarbonylationAminationCarbon monoxidePalladium

description

The three component reactions of α-bromomethyl oxime ethers, carbon monoxide, and alcohols or aromatic amines give imino esters and amides, respectively.

https://doi.org/10.1002/adsc.201400710