6533b873fe1ef96bd12d4ecf
RESEARCH PRODUCT
On the photoreaction of some 1,2,4-oxadiazoles in the presence of2,3-dimethyl-2-butene. Synthesis of N-imidoyl-aziridines
Nicolò VivonaAntonio Palumbo-piccionelloIvana PibiriAndrea PaceRosa Angela RaccugliaSilvestre BuscemiGianluca GiorgiNicolò Vivonasubject
PharmacologyphotochemistryOrganic Chemistry124-oxadiazoleGeneral MedicineRing (chemistry)Photochemistrypyrolysi2-ButeneAnalytical Chemistrychemistry.chemical_compoundN-allylamidinechemistryScientific methodOrganic chemistryIrradiationAcetonitrilePyrolysisN-imidoylaziridinedescription
Fhe photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-10-30 |