6533b873fe1ef96bd12d5f14

RESEARCH PRODUCT

A new Co(II) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC ≈ K

Simon M. HumphreyAntonio AlberolaCarlos José Gómez GarcíaPaul T. Wood

subject

CoOxygenMercaptonicotinic acidCo ; Oxygen ; Carboxylate ; Pyridine ; Sodium salt ; Mercaptonicotinic acid ; AntiferromagnetPyridineUNESCO::QUÍMICACarboxylateSodium salt:QUÍMICA::Química macromolecular [UNESCO]UNESCO::QUÍMICA::Química macromolecularAntiferromagnet:QUÍMICA [UNESCO]

description

Reaction of Co(II) chloride with the sodium salt of 2-mercaptonicotinic acid in water at 200 ºC results in the formation of Co4(2-mna)4(H2O), which orders as a canted antiferromagnet at 68 K. Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es

10.1039/b600347hhttp://hdl.handle.net/10550/16680