6533b874fe1ef96bd12d6456

RESEARCH PRODUCT

Efficient photoluminescent thin films consisting of anchored hybrid perovskite nanoparticles

Pablo P. BoixLaura Martínez-sartiMaria-grazia La-placaTeck Ming KohMichele SessoloSubodh MhaisalkarHenk J. Bolink

subject

Materials sciencePhotoluminescencePhotoluminescent Thin FilmsPerovskite NanoparticlesInorganic chemistryNanoparticleQuantum yield02 engineering and technology010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundMaterials ChemistryThin filmBifunctionalPerovskite (structure):Materials [Engineering]LigandMetals and AlloysGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsChemical engineeringchemistryCeramics and Composites0210 nano-technologyDispersion (chemistry)

description

Methylammonium lead bromide nanoparticles are synthetized with a new ligand (11-aminoundecanoic acid hydrobromide) by a non-template method. Upon dispersion in toluene they show a remarkable photoluminescence quantum yield of 80%. In addition, the bifunctional ligand allows anchoring of the nanoparticles on a variety of conducting and semiconducting surfaces, showing bright photoluminescence with a quantum yield exceeding 50%. This opens a path for the simple and inexpensive preparation of multilayer light-emitting devices. NRF (Natl Research Foundation, S’pore) ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version

https://doi.org/10.1039/c6cc05549d