6533b874fe1ef96bd12d64e2

RESEARCH PRODUCT

More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs

Hanh LyJani MoilanenHeikki TuononenMasood ParvezRoland Roesler

subject

cyclopentadienyl analoguessyklopentadienyylianalogit

description

Ruthenium and iron sandwich complexes incorporating cyclopentadienyl analogs with CB2N2− skeletons were characterized. Electrochemical measurements supported by computational studies revealed that in combination with larger metal ions such as Ru the CB2N2− ligand can be more electron-rich than its organic counterpart. peerReviewed

http://urn.fi/URN:NBN:fi:jyu-201511243778