Search results for " COMPOSITES"
showing 10 items of 1620 documents
On the influence of tool path in friction stir spot welding of aluminum alloys
2008
Abstract Friction stir spot welding (FSSW) has been proposed as an effective technology to spot weld the so-called “difficult to be welded” metal alloys. In the paper, a variation of the FSSW process has been considered. A tool path is given after the sinking phase nearby the initial penetration site; in this way a larger welding spot is obtained and more material is involved in the bonding process. The process mechanics of such modified FSSW process is highlighted and the joint strength undergoing tensile tests is considered at the varying both of the assigned tool path and of a few process parameters. Macro- and micro-analyses are made in order to analyze the local material microstructure…
On microstructural phenomena occurring in friction stir welding of aluminium alloys
2006
Abstract The results of experimental activity on friction stir welding (FSW) of aluminum alloys are reported. Butt joints of two different materials, namely AA2024-T4 and AA7075-T6, were investigated from a metallurgical point of view. Grain dimensions and insoluble particle densities were investigated both in the parent materials and in the joints. Furthermore, the effect of post-welding heat treatments on the joint strength was studied.
Two-dimensional self-assembly of disulfide functionalized bis-acylurea: a nanosheet template for gold nanoparticle arrays.
2010
A new functional bis-acylurea molecule allows a two-stage self-organization process. It self-organizes--at first--into 2D nanosheets with disulfide groups at the surface, which act--in the second stage--as a template for gold nanoparticle arrays.
Self-assembly of amphiphilic imidazolium-based hexa-peri-hexabenzo-coronenes into fibreous aggregates
2007
Imidazolium-based amphiphilic hexa-peri-hexabenzocoronenes were synthesized and shown to undergo ordered columnar self-assembly in solid-state as well as in solution to yield defined nanofibers upon solution drop casting onto solid substrate.
Low temperature catalytic combustion of propane over Pt-based catalyst with inverse opal microstructure in microchannel reactor
2007
A novel Pt-based catalyst with highly regular, periodic inverse opal microstructure was fabricated in a microchannel reactor, and catalytic testing revealed excellent conversion and stable activity for propane combustion at low temperatures.
Spin-crossover complex encapsulation within a magnetic metal-organic framework.
2016
The solid-state incorporation of a mononuclear iron(III) complex within the pores of a magnetic 3D metal–organic framework (MOF) in a single crystal to single crystal process leads to the formation of a new hybrid material showing both a guest-dependent long-range magnetic ordering and a spin-crossover (SCO) behaviour.
2D magnetic MOFs with micron-lateral size by liquid exfoliation
2020
The isolation in large amounts of high-quality flakes of 2D MOFs remains a challenge. In this work, we develop a liquid exfoliation procedure to obtain nanosheets for a whole family of Fe-based magnetic MOFs, MUV-1-X. High-quality crystalline layers with lateral sizes of 8 µm and thicknesses of 4 nm, which keep the structural integrity and magnetic properties, are obtained.
Folded Cr12Co12 and Cr12Ni12 wheels: a sharp increase in nuclearity of heterometallic chromium rings
2014
Two novel record-sized heterometallic Cr12M12 (M = Co, Ni) chromium wheels with an unusual saddle-like architecture are created by reacting appropriate precursor complexes with the bridging ligand 2,2'-bipyrimidine.
Improvement of flame spraying PEEK coating characteristics using lasers
2011
Flame spraying is frequently used for PEEK coatings elaboration on metallic surfaces. However, this process has a certain number of limitations particularly considering the quality of the coatings like high porosity or low interfacial adherence. For that reason a thermal post-processing is often necessary. From all of the processes which can be used (flame, oven, etc.), laser can be an interesting technology. Then, the aim of this study is to analyse the dependence of the morphological structure (compactness) and the adherence of the flame sprayed PEEK coatings to the stainless steel (304L) and aluminium alloy (AA2017) substrates on laser parameters. Moreover, the influence of the laser bea…
Prehnite: Structural similarity of the monoclinic and orthorhombic polymorphs and their Si/Al ordering
1990
Abstract Two modifications of the naturally occurring mineral prehnite, Ca 2 Al(Si 3 AlO 10 )(OH) 2 , are characterized by precise single crystal diffraction methods. The two forms are topologically identical. They differ only in the siting of one Al and one Si atom per unit cell: these switch their places in two of the tetrahedrally coordinated sites. This appears to be the only known case where a silicate occurs with two differently ordered tetrahedral distributions of Al and Si atoms. The two forms are not polytypes according to the current definition of polytypes. The two modifications are so similar to each other that they differ only in the eighth coordination sphere.