6533b829fe1ef96bd1289b2e

RESEARCH PRODUCT

Spin-crossover complex encapsulation within a magnetic metal-organic framework.

João C. WaerenborghEugenio CoronadoEmilio PardoAlexandre AbhervéJesús Ferrando-soriaMiguel Clemente-leónFrancesc LloretThais Grancha

subject

Materials scienceMetals and AlloysPhysics::OpticsNanotechnology02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsEncapsulation (networking)Chemical engineeringSpin crossoverMaterials ChemistryCeramics and CompositesMetal-organic framework0210 nano-technologyHybrid materialSingle crystal

description

The solid-state incorporation of a mononuclear iron(III) complex within the pores of a magnetic 3D metal–organic framework (MOF) in a single crystal to single crystal process leads to the formation of a new hybrid material showing both a guest-dependent long-range magnetic ordering and a spin-crossover (SCO) behaviour.

10.1039/c6cc03667hhttps://pubmed.ncbi.nlm.nih.gov/27189207