Search results for " CYCLING"

showing 10 items of 94 documents

Kit Is Expressed by Epithelial Cells In Vivo

2003

In mammalian skin, stem cell factor (SCF) regulates the proliferation and maturation of mast cells and melanocytes, which are thought to be the only cutaneous cells that express the Kit-tyrosine kinase receptor (Kit) and respond to epithelial and mesenchymal-derived SCF. We previously had noted, however, the presence of Kit+ cells in murine hair follicles, in an introepithelial tissue compartment devoid of melanocytes and mast cells. Here we have identified the nature of this Kit+ population of cells in hair follicles of C57BL/6 mice. Anagen hair follicles showed strong Kit immunoreactivity not only in the pigmentary unit above the follicular dermal papilla but also in a much more proximall…

Pathologymedicine.medical_specialtyPopulationStem cell factorDermatologyBiochemistryMicemedicineAnimalseducationMolecular BiologyMelanosomeKit-neutralizing antibodyOncogene ProteinsStem Cell Factoreducation.field_of_studyhair cycling6 mouseintegumentary systembiologyDesmoplakinSCFEpithelial CellsCell BiologyHair follicleImmunohistochemistryMolecular biologyEpitheliumMice Inbred C57BLC57BLProto-Oncogene Proteins c-kitmedicine.anatomical_structureDermal papillaeepithelial cell biologybiology.proteinProto-Oncogene Proteins c-kitFemaleHair FollicleSignal TransductionJournal of Investigative Dermatology
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Stimulated 7^Li echo NMR spectroscopy of slow ionic motions in a solid electrolyte

2000

Abstract Lithium spin-alignment spectroscopy is presented as an NMR technique for studying slow translational motions in solid and solid-like ionic conductors. We employ phase cycling that allows to measure two-time translational correlation functions via the generation of a pure quadrupolar ordered state. Correlation functions of the crystalline electrolyte Li 3 Sc 2 (PO 4 ) 3 were recorded for times ranging from about 0.1 ms to more than 10 s, implying that translational diffusion coefficients smaller than 10 −20 m 2 /s become accessible.

Phase cyclingChemistryDiffusionAnalytical chemistryGeneral Physics and AstronomyIonic bondingchemistry.chemical_elementElectrolyteNuclear magnetic resonance spectroscopy530LithiumPhysical and Theoretical ChemistrySpectroscopyElectrical conductor
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Low-temperature polymorphism in tungsten trioxide powders and its dependence on mechanical treatments

1999

The polymorphism of WO3 powder samples, resulting from mild mechanical treatments and from temperature changes between 30 K and room temperature, has been investigated by using Raman spectroscopy and X-ray di⁄raction. A transition from the monoclinic (I) c-phase to the triclinic d-phase after moderate mechanical treatments has been observed for untreated powder, just what happens when the same samples are rapidly cooled to low-temperature. Evidences of the low temperature monoclinic (II) polar e-phase have been found at room temperature in samples after a stronger milling treatment. The sequence of the low-temperature phase transitions appears to be strongly dependent on the mechanical hist…

Phase transitionChemistrylow-temperature polymorphismAnalytical chemistryTemperature cyclingTriclinic crystal systemCondensed Matter PhysicsTungsten trioxideElectronic Optical and Magnetic MaterialsInorganic ChemistryNanocrystalline tungsten trioxide powderschemistry.chemical_compoundCrystallographysymbols.namesakePolymorphism (materials science)X-ray crystallographyNanocrystalline tungsten trioxide powders low-temperature polymorphism mechanical treatments Raman spectroscopyRaman spectroscopyMaterials ChemistryCeramics and CompositessymbolsPhysical and Theoretical Chemistrymechanical treatmentsRaman spectroscopyMonoclinic crystal system
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Thermochromic Meltable Materials with Reverse Spin Transition Controlled by Chemical Design

2020

International audience; We report a series of meltable FeII complexes, which, depending on the length of aliphatic chains, display abrupt forward low‐spin to high‐spin transition or unprecedented melting‐triggered reverse high‐spin to low‐spin transition on temperature rise. The reverse spin transition is perfectly reproducible on thermal cycling and the obtained materials are easily processable in the form of thin film owing to their soft‐matter nature. We found that the discovered approach represents a potentially generalizable new avenue to control both the location in temperature and the direction of the spin transition in meltable compounds.

Phase transitionMaterials scienceBistabilitySpin transitionsSpin transition02 engineering and technologyTemperature cycling010402 general chemistry01 natural sciencesCatalysisSpin crossover[CHIM.COOR]Chemical Sciences/Coordination chemistrySoft matterThin filmThermochromismCondensed matter physics010405 organic chemistryReverse spin transitionGeneral MedicineGeneral Chemistry021001 nanoscience & nanotechnologySpin crossover0104 chemical sciencesCondensed Matter::Strongly Correlated ElectronsSoft matter0210 nano-technology
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Conformational relaxation of a low-temperature protein as probed by photochemical hole burning. Horseradish peroxidase

1991

For the first time, conformational relaxation processes have been measured in a small protein, mesoporphyrin-horseradish peroxidase via their influence on spectral diffusion broadening of holes burnt in the fluorescence excitation spectrum of free base mesoporphyrin. Holes were burnt in three 0----0 bands of different tautomeric forms of the chromophore at 1.5 and 4 K, and the spectral diffusion broadening was measured in temperature cycling experiments between 4 and 30 K. The inhomogeneous linewidth for the tautomeric 0----0 bands was estimated to be 60-70 cm-1; the hole width was found narrow, being in the order of 350 MHz (10(-2) cm-1) at 1.5 K what allowed for an extremely sensitive det…

PhotochemistryProtein ConformationChemistryDiffusionRelaxation (NMR)Fluorescence spectrometryBiophysicsTemperature cyclingChromophorePhotochemistryTautomerLaser linewidthSpectrometry FluorescenceThermodynamicsHorseradish PeroxidaseExcitationResearch ArticleBiophysical Journal
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Valutazione in vitro dell’affaticamento di strumenti rotanti in nichel-titanio

2012

Riassunto Obiettivo L’obiettivo di questo lavoro e quello di valutare, in vitro, la fatica ciclica di ProFile, K3 e Twisted File, strumenti rotanti in nichel-titanio, in canali radicolari simulati aventi angoli di curvatura di 45°, 60° e 90°. Materiali e metodi Per effettuare questo studio sono stati utilizzati: 18 file 25/.06 ProFile; 18 file 25/.06 K3; 18 file 25/.06 Twisted File. La resistenza a fatica ciclica degli strumenti rotanti Ni-Ti e stata testata ad angolazioni di 45°, 60° e 90° mediante un modello sperimentale creato specificatamente. Risultati e conclusioni Dall’analisi dei dati e emersa una buona resistenza alla fatica ciclica per quanto concerne le sistematiche ProFile e Twi…

PhysicsMedicine(all)nickel-titanium cycling fatigue analysisSettore MED/28 - Malattie OdontostomatologicheGeneral DentistryHumanitiesGiornale Italiano di Endodonzia
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The effect of dentine pre-treatment using bioglass and/or polyacrylic acid on the interfacial characteristics of resin-modified glass ionomer cements.

2018

Objective To evaluate the effect of load-cycle aging and/or 6 months artificial saliva (AS) storage on bond durability and interfacial ultramorphology of resin-modified glass ionomer cement (RMGIC) applied to dentine air-abraded using Bioglass 45S5 (BAG) with/without polyacrylic acid (PAA) conditioning.Methods RMGIC (Ionolux, VOCO) was applied onto human dentine specimens prepared with silicon-carbide abrasive paper or air-abraded with BAG with or without the use of PAA conditioning. Half of bonded-teeth were submitted to load cycling (150,000 cycles) and half immersed in deionised water for 24 h. They were cut into matchsticks and submitted immediately to microtensile bond strength (μTBS) …

Pre treatmentAdultCeramicsMaterials scienceSurface PropertiesGlass ionomer cementAcrylic Resins02 engineering and technologylaw.invention03 medical and health scienceschemistry.chemical_compoundTooth FracturesYoung Adult0302 clinical medicinestomatognathic systemlawBioglass 45S5Tensile StrengthLoad cyclingMaterials TestingHumansDental Restoration FailureComposite materialGeneral DentistryDental LeakageBond strengthPolyacrylic acidDental BondingResin modified030206 dentistry021001 nanoscience & nanotechnologyMolarResin CementsAir Abrasion DentalchemistryGlass Ionomer CementsBioactive glassDentin-Bonding AgentsDentinGlass0210 nano-technologyJournal of dentistry
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Long-Term Stability of (Ti/Zr/Hf)CoSb1−xSnxThermoelectric p-Type Half-Heusler Compounds Upon Thermal Cycling

2015

The effect of thermal cycling upon the thermoelectric performance of state-of-the-art p-type half-Heusler materials was investigated and correlated with the impact on the structural properties. We simulated a heat treatment of the material similar to actual applications in the mid-temperature range, such as occurs during the energy conversion from an automotive exhaust pipe. We compared three different compositions based on the (Ti/Zr/Hf)CoSb1−xSnx system. The best and most reliable performance was achieved using Ti0.5Hf0.5CoSb0.85Sn0.15, which reached a maximum figure of merit ZT of 1.1 at 700 °C. The intrinsic phase separation and resulting microstructuring, which are responsible for the …

Range (particle radiation)Materials sciencebusiness.industryMetallurgyThermodynamicsTemperature cyclingThermoelectric materialsGeneral EnergySemiconductorThermoelectric effectFigure of meritEnergy transformationThermal stabilitybusinessEnergy Technology
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Assessing hydrological connectivity inside a soil by fast-field-cycling nuclear magnetic resonance relaxometry and its link to sediment delivery proc…

2017

Connectivity is a general concept used to represent the processes involving a transfer of matter among the elements of an environmental system. The expression “hydrological connectivity inside the soil” has been used here to indicate how spatial patterns inside the soil (i.e., the structural connectivity) interact with physical and chemical processes (i.e., the functional connectivity) in order to determine the subsurface flow (i.e., the water transfer), thereby explaining how sediment transport due to surface runoff (i.e., the soil particle transfer) can be affected. This paper explores the hydrological connectivity inside the soil (HCS) and its link to sediment delivery processes at the p…

Relaxometry010504 meteorology & atmospheric sciencesSoil testSoil Science01 natural sciencesNuclear magnetic resonanceNuclear magnetic resonanceEnvironmental ChemistrySettore AGR/08 - Idraulica Agraria E Sistemazioni Idraulico-ForestaliFast field cyclingSubsurface flowSediment delivery processe0105 earth and related environmental sciencesEarth-Surface ProcessesWater Science and TechnologyGlobal and Planetary ChangeChemistrySedimentGeology04 agricultural and veterinary sciencesHydrological connectivityPollutionSoil water040103 agronomy & agricultureErosion0401 agriculture forestry and fisheriesSurface runoffRelaxometrySediment transport
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Dynamics of hyaluronan aqueous solutions as assessed by fast field cycling NMR relaxometry.

2010

Fast field cycling (FFC) NMR relaxometry has been used to study the conformational properties of aqueous solutions of hyaluronan (HYA) at three concentrations in the range 10 to 25 mg mL(-1). Results revealed that, irrespective of the solution concentration, three different hydration layers surround hyaluronan. The inner layer consists of water molecules strongly retained in the proximity of the HYA surface. Because of their strong interactions with HYA, water molecules in this inner hydration layer are subject to very slow dynamics and have the largest correlation times. The other two hydration layers are made of water molecules which are located progressively further from the HYA surface.…

RelaxometryAqueous solutionMagnetic Resonance SpectroscopyField cyclingChemistrySettore AGR/13 - Chimica AgrariaDynamics (mechanics)Analytical chemistryWaterBiochemistryAnalytical ChemistryIntramolecular forceQuadrupoleMolecular motionCarbohydrate ConformationMoleculeFFC-NMR Relaxometry Correlation time Quadrupole interactions Hydration layerHyaluronic AcidAnalytical and bioanalytical chemistry
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