Search results for " Carbonates"

Pedogenic carbonates and carbon pools in gypsiferous soils of a semiarid Mediterranean environment in south Italy

2013

Abstract Soil carbonates are key features in soils of arid and semiarid environment, playing an important role from pedogenetic, landscape history, paleoclimatic and environmental points of view. The objectives of this work were (i) to study pathways of pedogenic carbonate (PC) formation, (ii) to distinguish between lithogenic and pedogenic inorganic C by using the natural C isotope abundance, and (iii) to estimate the soil C pools in a gypsiferous semiarid Mediterranean environment (Sicily, Italy). Five soil pedons developed on calcareous and non-calcareous parent materials from Holocene (10,000 years BP) to Upper Tortonian (7.2–5.3 Ma BP) in age were surveyed. During field soil descriptio…

A study on the stability of carbon nanoforms–polyimidazolium network hybrids in the conversion of co2 into cyclic carbonates

2021

Three different carbon nanoforms (CNFs), single-walled and multi-walled carbon nanotubes (SWCNTs, MWCNTs) and carbon nanohorns (CNHs), have been used as supports for the direct polymerization of variable amounts of a bis-vinylimidazolium salt. Transmission electron microscopy confirmed that all CNFs act as templates on the growth of the polymeric network, which perfectly covers the nanocarbons forming a cylindrical (SWCNTs, MWCNTs) or spherical (CNHs) coating. The stability of these hybrid materials was investigated in the conversion of CO2 into cyclic carbonate under high temperature and CO2 pressure. Compared with the homopolymerized monomer, nanotube-based materials display an improved c…

Formation mechanisms of Neptunian dikes in the Jurassic carbonates of Monte Maranfusa (western Sicily)

2013

Younger sediment infilling open fissures exposed on the sea floor are defined as neptunian dikes. These are peculiar features of carbonate platform successions deposited along the plate margins bounding the western Tethys during the Late Triassic time. During middle-Early Jurassic, a large part of these carbonate platforms were drowned, and became submerged plateaux covered by pelagic sediments during Jurassic (“Rosso Ammonitico”) and Cretaceous times (“Scaglia”). In western Sicily, several Neptunian dikes crop out (Monte Kumeta, Rocca Busambra, Monte Maranfusa, Monte Magaggiaro, etc.). They cut across mainly the carbonate sediments of the Inici Formation and in some cases the pelagic limes…

High-pressure NMR spectroscopy: An in situ tool to study tin-catalyzed synthesis of organic carbonates from carbon dioxide and alcohols. Part 2 [1]

2015

Dialkoxide diorganotin(IV) complexes are known to readily react with carbon dioxide under pressure and they are considered as suitable catalyst precursor models for the direct synthesis of organic carbonates. To gain a better understanding of CO2 insertion processes with Sn-OR bonds, the reactivity of n-Bu2Sn(OCH(CH3)(2))(2) (2) was investigated using high-pressure NMR (HP-NMR) spectroscopy. In deuterated solvents (isopropanol-d(8) and toluene-d(8)) under 50 bar of CO2 pressure at 80 degrees C, Sn-119{H-1} NMR experiments revealed the exclusive formation of an unprecedented tetraorganodistannoxane species, characterized as the bis[diisopropycarbonatotetrabutyldistannoxane] complex, {[n-Bu2S…

Source of calcium for pedogenic CaCO3 formation in benchmark soils of a Mediterranean semiarid environment

2004

Calcic and petrocalcic horizons (Bk and Bkm, respectively) commonly occur in soils of arid and semiarid regions. Studies carried out to investigate the source of calcium in CaCO3 formation have shown that dust and parent materials represent the main sources. The aim of this study was to investigate if gypsum may be a source of calcium for calcium carbonate formation and, eventually, to quantify it. Five soil pedons, developing on “Serie Gessoso- Solfifera”, were selected in a very representative forest Mediterranean ecosystem in Sicily (I). Pedons were opened, described in field and sampled according to the sequence of genetic horizons. Soil samples were analyzed to investigate 87/86Sr rati…

Design of novel imidazolium based nanostructures for sustainable catalytic applications

2019

Multidisciplinary approach for outcropping and subsurface Permian-Cenozoic deepwater carbonates (Central Sicily): outcome for paleogeography of the S…

2016

An integrated stratigraphic study of the outcropping and buried Permian-Cenozoic deep-water carbonate successions have been performed. These successions form some of the tectonic units, mostly buried beneath the Late Neogene sedimentary cover, in the fold and thrust belt of Central Sicily. Three main successions, pertaining to the well known Lercara, Imerese and Sicanian domains, have been reconstructed on the basis of a detailed facies analysis, seismostratigraphic interpretation, biostratigraphy (mostly based on palynological data) and comparison between outcropping and subsurface deep-water sediments. The main results reveal a continuous sedimentation of the deep-water Southern Tethyan S…

Seismically-induced soft-sediment deformation structures in Upper Triassic deepwater carbonates (Central Sicily)

2016

We describe soft-sediment deformation structures into the Upper Triassic cherty limestone outcropping in the Pizzo Lupo section (Central Sicily, Italy), pertaining to the deep-water palaeodomain of the Southern Tethyan margin. In the study section, mainly consisting of thin-bedded mudstone/marl alternations with bedded chert intercalations, some lithofacies have been separated on the basis of the abundance of the calcium carbonate/clay content and the overall textural features. The deformational structures, displaying different deformational styles as folded and faulted beds, disturbed layers, clastic dikes, and slumps occur mainly in the deformed horizons that involve marl-dominated lithof…

Multi-scale properties of strike-slip faults corss-cutting the Pleistocene carbonate grainstones of Favignana Island (NW Sicily, Italy)

2010

Past aquatic environments in the Levant inferred from stable isotope compositions of carbonate and phosphate in fish teeth

2019

Here we explore the carbon and oxygen isotope compositions of the co-existing carbonate and phosphate fractions of fish tooth enameloid as a tool to reconstruct past aquatic fish environments and harvesting grounds. The enameloid oxygen isotope compositions of the phosphate fraction (δ18OPO4) vary by as much as ~4‰ for migratory marine fish such as gilthead seabream (Sparus aurata), predominantly reflecting the different saline habitats it occupies during its life cycle. The offset in enameloid Δ18OCO3-PO4 values of modern marine Sparidae and freshwater Cyprinidae from the Southeast Mediterranean region vary between 8.1 and 11.0‰, similar to values reported for modern sharks. The mean δ13C …