Search results for " Chemistry"

The Influence of Industrial Waste on the Magnetic Properties of Salt-Affected Soils from Two Soda Ash Manufacturing Sites

2021

The aim of this study was to characterize the impact of soda ash manufacturing on the magnetic properties of soils located in the agricultural landscape in north-central Poland. Two study sites were chosen: Mątwy (SM) and Janikowo (SJ). Highly saline soils with halophyte communities were selected in order to develop an understanding of the relationship between salinization of water–soil interface and the potential contamination risk of the environment. Basic chemical and physicochemical properties of topsoil (0–25 cm) and water (surface and groundwater) samples from five locations were characterized. The characteristics of soil contamination were based on the content of sel…

Assessing the quality of dissolved organic matter in forest soils using ultraviolet absorption spectrophotometry

2007

Abbreviations: DOC, dissolved organic carbon; SUVA, specifi c ultraviolet absorbance; UV, ultraviolet. Ultraviolet spectrophotometry was used to investigate the effects, 30 yr after planting, of tree species substitution on the aromatic C content and related properties of dissolved organic carbon (DOC). Precautions were taken to correct measurements for the absorbance of NO 3 and dissolved Fe. In litter leachates, a signifi cant reduction in the aromatic content of DOC was found in the Douglas-fi r [Pseudotsuga menziesii (Mirb.) Franco] plantation but not in the beech (Fagus sylvatica L.) plantation. The disturbance of short-term C dynamics thus revealed agreed well with fi eld observations…

Ti Alloyed α-Ga2O3: Route towards Wide Band Gap Engineering

2020

The suitability of Ti as a band gap modifier for &alpha

Bi-2212 and Y123 highly curved single-crystal-like objects: whiskers, bows and ring-like structures

2012

High-temperature superconducting objects of Bi2Sr2CaCu2O8 and Y Ba2Cu3O7 highly curved in the ab-plane, such as curved/kinked whiskers, bows and ring-like structures, were obtained within a solid?liquid?solid (SLS) grass-like growth mechanism. As-grown objects are crystals with three-dimensional epitaxy similar to conventional single crystals: they can be viewed as crystal parts ?cut? from a conventional rectangular crystal. Between our curved objects and conventional crystals, whiskers or thin films there are some differences in the superconducting properties induced only by the shape factors and no new physics is observed. Some details of the growth mechanism are discussed, emphasizing cu…

Synthesis and Biological Evaluation of a Multiantigenic Tn/TF-Containing Glycopeptide Mimic of the Tumor-Related MUC1 Glycoprotein

2006

Combined Use of Structure Analysis, Studies of Molecular Association in Solution, and Molecular Modelling to Understand the Different Propensities of…

2021

The arrangement of hydroxyl groups in the benzene ring has a significant effect on the propensity of dihydroxybenzoic acids (diOHBAs) to form different solid phases when crystallized from solution. All six diOHBAs were categorized into distinctive groups according to the solid phases obtained when crystallized from selected solvents. A combined study using crystal structure and molecule electrostatic potential surface analysis, as well as an exploration of molecular association in solution using spectroscopic methods and molecular dynamics simulations were used to determine the possible mechanism of how the location of the phenolic hydroxyl groups affect the diversity of solid phases formed…

Effect of different processing techniques and presence of antioxidant on the chitosan film performance

2022

In the last two decades, the naturally occurring polysaccharides have gained great attention because of their potential applications in different sectors, for example, from food to biomedical sectors. Chitosan is a cationic polysaccharide with good transparency, and currently, it has been considered also as suitable material for the formulation film and coating in cultural heritage protection. In this work, the chitosan films (Ch), with and without natural antioxidant such as citric acid (CA), are formulated considering two different processing techniques: (i) conventional solvent casting and (ii) compression molding, that is an unconventional method for this polysaccharide, giving the poss…

Chasing Weak Forces: Hierarchically Assembled Helicates as a Probe for the Evaluation of the Energetics of Weak Interactions.

2017

London dispersion forces are the weakest interactions between molecules. Because of this, their influence on chemical processes is often low, but can definitely not be ignored, and even becomes important in cases of molecules with large contact surfaces. Hierarchically assembled dinuclear titanium(IV) helicates represent a rare example in which the direct observation of London dispersion forces is possible in solution even in the presence of strong cohesive solvent effects. Hereby, the dispersion forces do not unlimitedly support the formation of the dimeric complexes. Although they have some favorable enthalpic contribution to the dimerization of the monomeric complex units, large flexible…

Sonication-Induced Modification of Carbon Nanotubes: Effect on the Rheological and Thermo-Oxidative Behaviour of Polymer-Based Nanocomposites.

2018

The aim of this work is the investigation of the effect of ultrasound treatment on the structural characteristics of carbon nanotubes (CNTs) and the consequent influence that the shortening induced by sonication exerts on the morphology, rheological behaviour and thermo-oxidative resistance of ultra-high molecular weight polyethylene (UHMWPE)-based nanocomposites. First, CNTs have been subjected to sonication for different time intervals and the performed spectroscopic and morphological analyses reveal that a dramatic decrease of the CNT's original length occurs with increased sonication time. The reduction of the initial length of CNTs strongly affects the nanocomposite rheological behavio…

Evaluation of the Behavior of Phenolic Compounds and Steviol Glycosides of Sonicated Strawberry Juice Sweetened with Stevia (Stevia rebaudiana Berton…

2019

In this study, the influence of stevia addition and sonication processing parameters on the phenolic content and profile as well as the steviol glycosides of strawberry juice-based samples was investigated. For this purpose, three matrices&mdash