Search results for " Circular dichroism"

Photoionization of Oriented Systems and Circular Dichroism

1996

Circular dichroism (CD) spectroscopy is a modification of normal absorption spectroscopy using circularly polarized light instead of unpolarized light for determining the difference in the absorption coefficients for right and left circularly polarized light, respectively, in optically active samples. Thus, there is nothing mysterious about CD spectroscopy. However, relative to most other spectroscopic techniques there seems to be a large psychological barrier in its application and at least physicists often regard CD, and optical activity in general, as a rather obscure technique without any useful application. There are some understandable reasons for this attitude, manifesting themselves…

Circular dichroism in atomic vapors: magnetically induced transitions responsible for two distinct behaviors

2021

Atomic transitions of alkali metals for which the condition $F_e-F_g = \pm2$ is satisfied have null probability in a zero magnetic field, while a giant increase can occur when an external field is applied. Such transitions, often referred to as magnetically-induced (MI) transitions, have received interest because their high probabilities in wide ranges of external magnetic fields which, in some cases, are even higher than that of usual atomic transitions. Previously, the following rule was established: the intensities of MI transitions with $\Delta F=\pm2$ are maximum when using respectively $\sigma^\pm$ radiation. Within the same ground state, the difference in intensity for $\sigma^+$ and…

4D texture of circular dichroism in soft-x-ray photoemission from tungsten

2019

Brief treatment and crisis intervention 21(1), 013017 (2019). doi:10.1088/1367-2630/aaf4cd

Circular dichroism in x-ray photoemission from core levels of nonmagnetic species

1992

Circular dichroism in the angular distribution of photoelectrons (CDAD) has been observed in core-level photoemission from spherically symmetric initial states of nonmagnetic species utilizing circularly polarized soft-x-ray radiation from BESSY. Up to now, CDAD was predicted and observed only for aligned initial states. The data for oriented CO molecules prove that circular x-ray dichroism in photoemission from core levels is a general phenomenon that is not restricted to ferromagnets. High asymmetries of 50% suggest future applications as an effective circular x-ray analyzer.

Energy- and angle-dependent threshold photoemission magnetic circular dichroism from an ultrathin Co/Pt(111) film

2010

Threshold photoemission magnetic circular dichroism (TPMCD) in one-photon photoemission (1PPE) and two-photon photoemission (2PPE) is measured at an ultrathin Co film grown on Pt(111). Energy-dependent measurements reveal maximum asymmetries directly at the photoemission threshold (1.90% for 1PPE and 11.7% for 2PPE) which weakly decrease with increasing photon energy. The measured TPMCD asymmetries are discussed in two excitation models on the basis of spin-resolved band-structure calculations. For the model of direct band-to-band transitions in other k directions than the direction of observation (Gamma-L) ab initio calculations for 1PPE and 2PPE are performed. The theory is in reasonable …

Beyond the Heisenberg Model: Anisotropic Exchange Interaction between a Cu-Tetraazaporphyrin Monolayer andFe3O4(100)

2013

The exchange coupling of a single spin localized at the central ion of Cu-tetraazaporphyrin on a magnetite(100) surface has been studied using x-ray magnetic circular dichroism (XMCD). Sum rule analysis of the XMCD spectra results in Cu spin and orbital magnetic moments as a function of the applied external field at low temperatures (20 K). The exchange coupling is positive for magnetization direction perpendicular to the surface (ferromagnetic) while it is negative for in-plane magnetization direction (antiferromagnetic). We attribute the anisotropy of the Heisenberg exchange coupling to an orbitally dependent exchange Hamiltonian.

2008

ZnO doped with a few per cent (<10%) of magnetic ions such as Co exhibit room temperature (RT) ferromagnetism, transforming it into a very promising candidate for future spin electronic applications. We present x-ray magnetic circular dichroism (XMCD) spectroscopy, which has been used in total electron yield, total fluorescence yield, and reflection mode to investigate the origin of ferromagnetism in such diluted magnetic semiconductor materials in a surface, bulk and interface sensitive way, respectively. We investigated three different types of samples: ZnO doped with 5% Co, artificially layered films, and layered films with additional co-doping of 10% Li. These films are prepared by puls…

Element-specific magnetic properties of mixed 3d−4f metallacrowns

2018

Single molecule magnets comprising rare earth metals are of high interest due to the unquenched orbital moments of the rare earth ions that result in a large energy barrier for magnetization reversal. We investigate the magnetic properties of polynuclear $3d\text{\ensuremath{-}}4f15$-MC-5 metallacrowns using x-ray magnetic circular dichroism of powder samples at a temperature of 7 K in a magnetic field of 7 T. The sum rule analysis reveals element-specific spin and orbital moments. The magnetic moments of the $3d$ transition metal Ni(II) ions are coupled antiferromagnetically to each other and contribute only little to the total molecular moment. The spin and orbital moments of the rare ear…

Taming conformational heterogeneity in and with vibrational circular dichroism spectroscopy

2019

Chemical science 10, 7680 -7689 (2019). doi:10.1039/C9SC02866H

Energy- and k -resolved mapping of the magnetic circular dichroism in threshold photoemission from Co films on Pt(111)

2017

The magnetic circular dichroism in threshold photoemission (TPMCD) for perpendicularly magnetized fcc Co films on Pt(111) has been revisited. A complete mapping of the spectral function $I({E}_{B},{k}_{x},{k}_{y})$ (binding energy ${E}_{B}$, momentum parallel to surface ${k}_{x}$, ${k}_{y}$) and the corresponding TPMCD asymmetry distribution ${A}_{\mathrm{MCD}}({E}_{B},{k}_{x},{k}_{y})$ has been performed for one-photon and two-photon photoemission using time-of-flight momentum microscopy. The experimental results allow distinguishing direct from indirect transitions. The measurements reveal clear band features of direct transitions from bulk bands that show a nontrivial asymmetry pattern. …