Search results for " Conductivity"

Observing the anisotropic optical response of the heavy-fermion compound UNi2 Al3

2010

The optical conductivity of heavy fermions can reveal fundamental properties of the charge carrier dynamics in these strongly correlated electron systems. Here we extend the conventional techniques of infrared optics on heavy fermions by measuring the transmission and phase shift of THz radiation that passes through a thin film of UNi 2 Al 3 , a material with hexagonal crystal structure. We deduce the optical conductivity in a previously not accessible frequency range, and furthermore we resolve the anisotropy of the optical response (parallel and perpendicular to the hexagonal planes). At frequencies around 7 cm -1 , we find a strongly temperature-dependent and anisotropic optical conducti…

PEDOT:Poly(1-vinyl-3-ethylimidazolium) dispersions as alternative materials for optoelectronic devices

2008

Composite Polymer Electrolytes with Improved Lithium Metal Electrode Interfacial Properties: I. Elechtrochemical Properties of Dry PEO‐LiX Systems

1998

Several types of lithium ion conducting polymer electrolytes have been synthesized by hot-pressing homogeneous mixtures of the components, namely, poly(ethylene oxide) (PEO) as the polymer matrix, lithium trifluoromethane sulfonate (LiCF{sub 3}SO{sub 3}), and lithium tetrafluoroborate (LiBF{sub 4}), respectively, as the lithium salt, and lithium gamma-aluminate {gamma}-LiAlO{sub 2}, as a ceramic filler. This preparation procedure avoids any step including liquids so that plasticizer-free, composite polymer electrolytes can be obtained. These electrolyte have enhanced electrochemical properties, such as an ionic conductivity of the order of 10{sup {minus}4} S/cm at 80--90 C and an anodic bre…

Intrinsic electrical conductivity of nanostructured metal-organic polymer chains

2012

One-dimensional conductive polymers are attractive materials because of their potential in flexible and transparent electronics. Despite years of research, on the macro- and nano-scale, structural disorder represents the major hurdle in achieving high conductivities. Here we report measurements of highly ordered metal-organic nanoribbons, whose intrinsic (defect-free) conductivity is found to be 104 S m−1, three orders of magnitude higher than that of our macroscopic crystals. This magnitude is preserved for distances as large as 300 nm. Above this length, the presence of structural defects (~ 0.5%) gives rise to an inter-fibre-mediated charge transport similar to that of macroscopic crysta…

Bis(2-ethylhexyl)phosphoric acid/bis(2-ethylhexyl)amine mixtures as solvent media for lithium-ions: A dynamical study

2016

Abstract The self-diffusion coefficient, the spin-lattice relaxation times and ionic conductivity of lithium ions in liquid mixtures composed of bis(2-ethylhexyl)amine (BEEA) and bis(2-ethylhexyl)phosphoric acid (HDEHP) have been thoroughly investigated as a function of composition and temperature by NMR spectroscopy and conductometry. While the temperature and composition dependence of diffusion coefficients of lithium ions follow the same trend observed for those of the surfactant molecules, the spin-lattice relaxation times of lithium ions and 1 H are remarkably different. The observed behavior has been interpreted in terms of lithium ions diffusion occurring through its association with…

Development and analysis of the Soil Water Infiltration Global database

2018

27 Pags.- 11 Tabls.- 8 Figs. © Author(s) 2018. This work is distributed under the Creative Commons Attribution 4.0 License.

Analysis of thermally induced flows in the laboratory by geoelectrical 3-D tomography

2010

[1] Many natural bodies as well as materials inside industrial installations, such as the Earth's mantle and the glass inside melting furnaces, exchange matter through convection. These processes result from differences in temperature, density, and chemical concentration. In this analysis, we focus on the visualization of thermally driven flows in the laboratory. In nature and in industrial installations, it is difficult to measure the temperature inside the object of interest directly. We benchmark a new DC-geoelectrical 3-D tomography method for temperature measurements that allows obtaining temperature values without influencing the flow pattern. For verification of the method, we use di…

In-flight temperature of solid micrometric powders during cold spray additive manufacturing

2020

Abstract During cold dynamic gas spray additive manufacturing, the thermal field within particles is generally simplified by a state of an instantaneous uniform distribution over the particle's media at any position inside and outside the De-Laval nozzle. This paper addresses critical discussions using analytical and computational analysis of the transient heat transfer within the solid particles due to the convective exchange with the flowing gas. An analytical criterion depicts conditions of instantaneous uniform temperature over the range of typical cold spray data including various particle thermal conductivity, particle size range, dragging velocities, gas nature and gas setting condit…

Analysis of the dopant segregation effects at the floating zone growth of large silicon crystals

1997

Abstract A computer simulation is carried out to study the dopant concentration fields in the molten zone and in the growing crystal for the floating zone (FZ) growth of large (> 100mm) Si crystals with the needle-eye technique and with feed/crystal rotation. The mathematical model developed in the previous work is used to calculate the shape of the molten zone and the velocity field in the melt. The influence of melt convection on the dopant concentration field is considered. The significance of the rotation scheme of the feed rod and crystal on the dopant distribution is investigated. The calculated dopant concentration directly at the growth interface is used to determine the normalized …

A study of hydrothermal convection in saturated porous media

1993

Abstract Because of its relevance to many geological and technical problems, hydrothermal convection is investigated here mainly with the aid of numerical models by a systematic analysis of the properties of this type of convection for a range of super-critical Rayleigh numbers. Calculations were performed for two-dimensional models with constant properties in a region of aspect ratio 2. The principal results in the case of temperature fixed at the impermeable top and bottom are the following for the Nusselt number Nu, the cell aspect ratio a, and the boundary layer thickness δ: Nu ≈ 1.7 R0.5, a ≈ 1.3 R−0.4, δc ≈ 0.4 R−0.4 for 2.5 R = R f /R f ∗ and Rf and R f ∗ are the ambient and critical…