Search results for " Conductivity"
showing 10 items of 794 documents
Possibility of unconventional superconductivity of SrTiO3−δ
2003
Abstract SrTiO3−δ can show metallic behavior and superconductivity at T It is demonstrated that by variation of the annealing temperature in vacuum the transport properties of SrTiO3−δ can be tuned continuously from semiconducting to metallic. We present measurements of the upper critical field Bc2(T) which show near Tc a positive curvature. This unusual temperature dependence is consistent with a model of weakly interacting charged bosons which condense in the superconducting state (local pairing). However, measurements of current–voltage curves reveal only small critical currents of our samples. This observation is discussed in the framework of doping inhomogeneities.
Superconductivity in Nb21S8, a Phase with Metal Cluster Chains
1998
Phase pure samples of Nb21S8 are obtained by chemical transport and molten flux reactions in sealed niobium containers at 850−950 °C. In the temperature range from 5 to 290 K the electrical conductivity is found to be moderate metallic with a specific resistivity of 3.90 mΩ cm at 273 K. Magnetic susceptibility measurements give weak, almost temperature independent paramagnetism above ∼40 K. These metallic properties are compared with the structure of Nb21S8, which contains linear single and double chains of fused body centered niobium cubes, separated by S and additional Nb atoms. Both physical measurements consistently show a transition into the superconducting state below 4.1(5) and 3.7(2…
Coexistence of superconductivity and magnetism by chemical design.
2010
Although the coexistence of superconductivity and ferromagnetism in one compound is rare, some examples of such materials are known to exist. Methods to physically prepare hybrid structures with both competing phases are also known, which rely on the nanofabrication of alternating conducting layers. Chemical methods of building up hybrid materials with organic molecules (superconducting layers) and metal complexes (magnetic layers) have provided examples of superconductivity with some magnetic properties, but not fully ordered. Now, we report a chemical design strategy that uses the self assembly in solution of macromolecular nanosheet building blocks to engineer the coexistence of supercon…
New magnetic conductors and superconductors based on BEDT-TTF and BEDS-TTF
2005
Abstract Here we present our last results in the search for multifunctionality in conducting molecular materials obtained by combining paramagnetic molecular complexes with organic donors to produce paramagnetic molecular metals and superconductors. The structural and physical characterization of two new molecular paramagnetic superconductors ET 4 [H 3 OM(C 2 O 4 ) 3 ].PhBr (M III = Cr and Fe) are presented (ET = BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene). These salts present a superconductor transition at T c = 1.5 and 4.0 K, respectively and very anisotropic critical fields H c2a ≈ H c2b ≈0.5 T and H C2C ≈ 8 T for the Fe derivative. We will also present the structural and physica…
Preparation and characterization of (Hg0.7Mo0.3)Sr2(Ca0.7Y0.3)Cu2Ox and (Hg0.9Re0.1)Ba2CaCu2Oy superconducting films by laser ablation
2000
Abstract Oriented (Hg 0.7 Mo 0.3 )Sr 2 (Ca 0.7 Y 0.3 )Cu 2 O x and (Hg 0.9 Re 0.1 )Ba 2 CaCu 2 O y superconducting films were prepared on SrTiO 3 substrates using laser ablation and post-Hg-vapor annealing. Due to the stability of Mo 0.3 Sr 2 (Ca 0.7 Y 0.3 )Cu 2 O x and Re 0.1 Ba 2 CaCu 2 O y in air, no special handling was needed during the grinding, mixing and pressing of the precursor targets. The superconductivity of the films was characterized with the temperature dependence of the ac susceptibility ( χ - T ) and the resistance ( R - T ) while the crystallography was probed with x-ray diffraction (XRD) and scanning electron microscopy (SEM).
Effect of film thickness on the transport properties of MgB2 synthesized by spray pyrolysis
2011
Abstract Polycrystalline MgB2 films of different thickness have been prepared by employing spray pyrolysis technique on MgO (1 0 0) substrate. The MgB2 and other phases have been confirmed using X-ray diffraction technique and no trace of impurities phases have been found. The resistivity behavior shows that the superconducting transition temperature lies in the range of 37–39 K with narrow transition width. The transport critical current density vary with films thickness and achieved highest value ∼1.2 × 106 A/cm2 at 20 K for 2.0 μm thick film and its values increase as thickness increases.
Complex conductivity in high-Tc single crystal superconductors
1994
The electromagnetic surface impedance of single crystal high-T c superconductors has been examined within the framework of the two-fluid model and the hypothesis that the em field modulates the partial concentrations of both normal and condensate fluids. A comparison with experimental data is reported
Possible light-induced superconductivity in K3C60 at high temperature.
2015
The non-equilibrium control of emergent phenomena in solids is an important research frontier, encompassing effects such as the optical enhancement of superconductivity. Nonlinear excitation of certain phonons in bilayer copper oxides was recently shown to induce superconducting-like optical properties at temperatures far greater than the superconducting transition temperature, Tc. This effect was accompanied by the disruption of competing charge-density-wave correlations, which explained some but not all of the experimental results. Here we report a similar phenomenon in a very different compound, K3C60. By exciting metallic K3C60 with mid-infrared optical pulses, we induce a large increas…
Depinning frequency in a heavily neutron-irradiated MgB2 sample
2008
The magnetic-field-induced variations of the microwave surface resistance have been investigated in a heavily neutron-irradiated MgB2 sample, in which the irradiation has caused the merging of the two gaps into a single value. The experimental results have been analyzed in the framework of the Coffey and Clem model. By fitting the experimental data, we have determined the field dependence of the depinning frequency, omega_0, at different values of the temperature. Although the pinning is not particularly effective, the value of omega_0 obtained at low temperatures is considerably higher than that observed in conventional low-temperature superconductors.
Microwave response of a cylindrical cavity made of bulk MgB2 superconductor
2008
We report on the microwave properties of a resonant cylindrical cavity made of bulk MgB2 superconductor, produced by the reactive liquid Mg infiltration process. The frequency response of the cavity has been measured in the range 5-13GHz. Among the various modes, the TE011, resonating at 9.79GHz, exhibits the highest quality factor. For this mode, we have determined the temperature dependence of the quality factor, obtaining values of the order of 10^5 in the temperature range 4.2-30K. The values of the surface resistance deduced from the measurements of the quality factor agree quite well with those independently measured in a small sample of MgB2 extracted from the same specimen from whic…