Search results for " Conductivity"
showing 10 items of 794 documents
Ab initio computational study on the lattice thermal conductivity of Zintl clathrates [Si19P4]Cl4 and Na4[Al4Si19]
2016
The lattice thermal conductivity of silicon clathrate framework Si23 and two Zintl clathrates, [Si19P4]Cl4 and Na4[Al4Si19], is investigated by using an iterative solution of the linearized Boltzmann transport equation in conjunction with ab initio lattice dynamical techniques. At 300 K, the lattice thermal conductivities for Si23, [Si19P4]Cl4, and Na4[Al4Si19] were found to be 43 W/(m K), 25 W/(m K), and 2 W/(m K), respectively. In the case of Na4[Al4Si19], the order-of-magnitude reduction in the lattice thermal conductivity was found to be mostly due to relaxation times and group velocities differing from Si23 and [Si19P4]Cl4. The difference in the relaxation times and group velocities ar…
Emerging dynamics in surfactant-based liquid mixtures: octanoic acid/bis(2-ethylhexyl) amine systems.
2012
This work focuses on the dynamic phenomena emerging in self-assembled transient intermolecular networks formed when two different surfactants are mixed. In particular, the relaxation processes in liquid mixtures composed by bis(2-ethylhexyl)amine (BEEA) and octanoic acid (OA) in the whole composition range has been investigated by dielectric spectroscopy and Brillouin spectroscopy. A thorough analysis of all the experimental data consistently suggests that, mainly driven by acid-base interactions arising when the two surfactants are mixed, supra-molecular aggregates formation causes the slowing down of molecular dynamics. This, in turn, reflects to longer-range relaxations. These changes ha…
MULTIFUNCTIONAL FIBERS BASED ON POLYAMIDE 6 AND PLASMA FUNCTIONALIZED CARBON NANOTUBES MoDeSt 2012 Conference, Praga, 2-6 Settembre 2012.
2012
Commercial (CNT 1) and ad hoc synthesized carbon nanotubes (CNT 2) were plasma treated under oxygen atmosphere and then added to polyamide 6 (PA 6) in order to prepare multifunctional fibres by melt spinning. For comparison, pristine nanofillers were used too. The effect of functionalization and of filler characteristics on the morphological, rheological, mechanical and electrical properties of the fibers was studied by TEM and SEM, rheological measurements, tensile tests and electrical conductivity tests. The amalysis of Raman spectra put into evidence that the intensity of D-band (correlated with the degree of functionalization by the different vibration mode of carbon atoms in the presen…
Field testing parameter sensitivity of the two-term infiltration equation using differentiated linearization
2003
Knowledge of soil hydraulic conductivity in the vadose zone is important in many agronomic, engineering and environmental areas. Transient tension infiltrometer experiments can be used to estimate the hydraulic conductivity, K0, corresponding to a given pressure head by the single-test (TST) method that uses the coefficients C1 and C2 of the two-term infiltration equation. The “Differentiated Linearization” (DL) method has been proposed to estimate these coefficients when a layer of contact material is used for the experiment. A field test of the DL and TST methods was conducted on a sandy loam and a clay soil. Eliminating the early-time influence of the contact layer was easy when the sorp…
Hydraulic conductivity and strength of pervious concrete for deep trench drains
2019
Abstract Pervious concrete for deep trench drains, used to stabilise slopes, must meet many requirements, namely, adequate hydraulic conductivity, adequate shear strength a few days after pouring, capacity to act as a protective filter for soils in which the drain is installed, good resistance to clogging and adequate residual hydraulic conductivity. In current engineering practice, the composition of pervious concrete for drains is improperly selected according to criteria used for no-fines concrete for road pavements. To detect more suitable and specific criteria, a laboratory investigation has been conducted aimed at identifying the composition and the properties of pervious concrete sat…
Effect of Sheep Wool Fibers on Thermal Insulation and Mechanical Properties of Cement-Based Composites
2019
The use of sheep wool as a filler of cement in order to produce mortar or plaster involves several advantages for environment and energy. Moreover, it is considered as a waste and, therefore, its use is characterized by low cost. The aim of this paper is to evaluate the influence of wool fibers on thermal conductivity and mechanical properties of cement. The samples were prepared using wool fibers, obtained from a breed of Sicilian sheep, with three different lengths (i.e., 1, 6, and 20 mm). Furthermore, in order to evaluate the influence of fiber content, the samples were prepared by varying the fiber weight fraction. The thermal conductivity of the samples was analyzed by using a heat flo…
Ring diameter effects on determination of field-saturated hydraulic conductivity of different loam soils
2017
Abstract Establishing ring diameter effects on the field-saturated soil hydraulic conductivity, Kfs, determined with ponding infiltrometer methods can help to find a compromise between the need to sample a large area with an individual measurement and the impracticality of using large rings in the field. Five ring sizes (diameter, D = 5.5, 10.9, 16.0, 27.8 and 31.8 cm) were used to determine Kfs by the simplified falling head (SFH) technique in four loamy soils with different salinity (electrical conductivity of saturated extract, ECe = 0.9–29.4 dS/m) and sodicity (exchangeable sodium percentage, ESP = 2.7–81.3%) levels. According to USDA classification, two soils were non-saline, non-sodic…
Spark Plasma Sintering (SPS)-Assisted Synthesis and Thermoelectric Characterization of Magnéli Phase V6O11
2018
The Magneli phase V6O11 was synthesized in gram amounts from a powder mixture of V6O11/V7O13 and vanadium metal, using the spark plasma sintering (SPS) technique. Its structure was determined with synchrotron X-ray powder diffraction data from a phase-pure sample synthesized by conventional solid-state synthesis. A special feature of Magneli-type oxides is a combination of crystallographic shear and intrinsic disorder that leads to relatively low lattice thermal conductivities. SPS prepared V6O11 has a relatively low thermal conductivity of κ = 2.72 ± 0.06 W (m K)-1 while being a n-type conductor with an electrical conductivity of σ = 0.039 ± 0.005 (μΩ m)-1, a Seebeck coefficient of α = -(3…
Transport equations of electrodiffusion processes in the laboratory reference frame.
2006
The transport equations of electrodiffusion processes use three reference frames for defining the fluxes: Fick's reference in diffusion, solvent-fixed reference in transference numbers, and laboratory fluxes in electric conductivity. The convenience of using only one reference frame is analyzed here from the point of view of the thermodynamics of irreversible processes. A relation between the fluxes of ions and solvent and the electric current density is deduced first from a mass and volume balance. This is then used to show that (i) the laboratory and Fick's diffusion coefficients are identical and (ii) the transference numbers of both the solvent and the ion in the laboratory reference fr…
Structural relaxation in a molten salt probed by time-dependent dc conductivity measurements
1998
Abstract Time-dependent dc conductivity was measured after cooling steps of about 2 K in the glass transformation range of 2Ca(NO 3 ) 2 -3RbNO 3 . The shape and time scale of the structural relaxation function was thus monitored for times 60 s t 6 s. The time scale could be compared with results from scanning calorimetry measurements and good agreement was found. From the heat capacity data and from the solid state conductivity the expected liquid state conductivity relaxation time was calculated using several models. The good compatibility of these calculations with the experimental results provides evidence that near the calorimetric glass transition the mobile ions perform concerted moti…