Search results for " Contamination"
showing 10 items of 571 documents
Effects of pentachlorophenol in forest soil: a microcosm experiment for testing ecosystem responses to anthropogenic stress
1996
Changes in the structure and function of a soil decomposer community and growth of birch (Betula pendula) due to chemical contamination were studied in laboratory microcosms. Sodium pentachlorophenate (PCP) was added to the humus layer of a simulated forest soil at three nominal concentrations (0, 50 and 500 mg kg-1 dry mass). After two growing periods (48 weeks), there were more small soft-bodied mites, but less collembolans and microbial biomass, in the higher PCP concentration treatment than in the other treatments. Number of enchytraeids were significantly reduced and fungal-feeding nematodes became extinct in the soil with the higher PCP concentration. Soil respiration did not change d…
Contamination of soil by copper affects the dynamics, diversity, and activity of soil bacterial communities involved in wheat decomposition and carbo…
2009
ABSTRACT A soil microcosm experiment was conducted to evaluate the influence of copper contamination on the dynamics and diversity of bacterial communities actively involved in wheat residue decomposition. In the presence of copper, a higher level of CO 2 release was observed, which did not arise from greater wheat decomposition but from a higher level of stimulation of soil organic matter mineralization (known as the priming effect). Such functional modifications may be related to significant modifications in the diversity of active bacterial populations characterized using the DNA stable-isotope probing approach.
Devonian Clay Modification for the Improvement of Heavy Metal Sorption Properties
2013
Contamination with heavy metals is an important problem as bioaccumulation effects of those are creating direct and indirect hazards to environment and human health. Contaminated soil remediation can be done by various technologies and using of soil amendments is the one. Clay modification experiments were done to study heavy metal sorption from spiked solutions and leaching from contaminated soils. The aim of this paper is to give an overview of Devonian clay modification possibilities in order to improve heavy metal sorption capacity and immobilization options. Modification was done by using Ca, Na salts, HNO 3 (protonated forms), Fe-oxyhydroxide. Research has shown better sorption due to…
Selenium and heavy metals content in some Mediterranean soils
2010
Abstract The study of metal contents in industrial, agricultural or/and polluted soils compared with natural or unpolluted soils is currently necessary to obtain reference values and to assess soil contamination. Nonetheless, very few works published appear in international journals on elements like Se, Li and Sr in Spanish soils. This study determines the total levels of Se, Li, Sr, As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, Fe, Mn and Ba in 14 natural (unpolluted) soils (Gypsisols, Leptosols, Arenosols and Acrisols), 14 agricultural soils (Anthrosols, Fluvisols and Luvisols), and 4 industrial–urban affected-surface soil horizons (Anthrosols and Fluvisols) of Eastern Spain. The geochemical baselin…
Horizontal distribution of copper, nickel and enchytraeid worms in polluted soil
1999
We studied the horizontal distribution of Cu, Ni and enchytraeid worms (Cognettia sphagnetorum, Vejdovsky, Oligochaeta, Enchytraeidae) in forest soil near a Cu–Ni smelter in SW Finland. Soil samples were taken from a polluted site (2 km from the smelter) and a reference area (8 km from the smelter). We used a hierarchical sampling design in the polluted area for studying possible scale-dependent variability in parameters measured, distance between the samples (different scales) being 5, 50 and 500 cm. Distribution of metals was moderately heterogeneous in the polluted soil; coefficient of variances (CV), 26% for Cu and 32% for Ni. Instead, distribution of enchytraeids in the area was highly…
Determination of organophosphate flame retardants in soil and fish using ultrasound-assisted extraction, solid-phase clean-up, and liquid chromatogra…
2017
A solid–liquid extraction method in combination with high‐performance liquid chromatography and tandem mass spectrometry was developed and optimized for extraction and analysis of organophosphorus flame retardants in soil and fish. Methanol was chosen as the optimum extraction solvent, not only in terms of extraction efficiency, but also for its broader analyte coverage. The subsequent clean‐up by solid‐phase extraction is required to eliminate matrix coextractives and reduce matrix effects. Recoveries of the optimized method were 50–121% for soil and 47–123% for biota, both with high precision (RSDs <12% in soil and <23% in biota). The method limits of detection ranged from 0.06 to 0.20 ng…
Current trends in solid-phase-based extraction techniques for the determination of pesticides in food and environment
2006
Solid-phase extraction (SPE) procedures for pesticide residues in food and environment are reviewed and discussed. The use of these procedures, which include several approaches such as: matrix solid-phase dispersion (MSPD), solid-phase micro-extraction (SPME) and stir-bar sorptive extraction (SBSE), represents an opportunity to reduce analysis time, solvent consumption, and overall cost. SPE techniques differ from solvent extraction depending on the interactions between a sorbent and the pesticide. This interaction may be specific for a particular pesticide, as in the interaction with an immunosorbent, or non-specific, as in the way a number of different pesticides are adsorbed on apolar or…
Pesticide analysis in coffee leaves using a quick, easy, cheap, effective, rugged and safe approach and liquid chromatography tandem mass spectrometr…
2017
An analytical method using a quick, easy, cheap, effective, rugged and safe (QuEChERS) procedure for multi-residue determination of 52 pesticides in coffee leaf extractshas been developed and validated according to SANTE/11945/2015 guidelines. Different sorbent combinations for dispersive solid phase extraction (d-SPE) clean-up as well as dispersive liquid-liquid microextraction (DLLME) were tested. The relative standard deviations (RSDs) for the recovery of 87-94% of pesticides added to coffee leaf extracts,was ≤20% for samples spiked at concentrations up to 50ng*g-1 depending on the clean-up procedures. However, samples spiked with a 100ng*g-1 pesticide mixture gave RSDs>20% for most pest…
Sustainable soy protein microsponges for efficient removal of lead (II) from aqueous environments
2023
Protein-based materials recently emerged as good candidates for water cleaning applications, due to the large availability of the constituent material, their biocompatibility and the ease of preparation. In this work, new adsorbent biomaterials were created from Soy Protein Isolate (SPI) in aqueous solution using a simple environmentally friendly procedure. Protein microsponge-like structures were produced and characterized by means of spectroscopy and fluorescence microscopy methods. The efficiency of these structures in removing Pb2+ ions from aqueous solutions was evaluated by investigating the adsorption mechanisms. The molecular structure and, consequently, the physico-chemical propert…
Spaces of cultural contamination. Creative places of sociality, integration, inclusion
2023
The well-being of the person is closely linked to the spaces in which they live and the resources they access. The recent slogan and urban paradigm "happy city and healthy city" bring attention back to the person and investigates the role of the built environment, individual, social and cultural well-being, as indicated in the sustainable development objectives of the 2030 Agenda. However, combining the city with the health and well-being of citizens requires an overall vision. It is necessary to graft a plot that can create - through resilient planning - interconnected and engaging open spaces, open and multiform specialized areas and, at the same time, incorporate pre-existing places and …