Search results for " DEGRADATION"

Oxidative degradation properties of Co-based catalysts in the presence of ozone

2007

Four series of cobalt-based catalysts, such as bare Co3O4 and CoO, CoOx-CeO2 mixed oxides, CoOx supported over alumina and alumina-baria and CoMgAl and CoNiAl hydrotalcites have been synthesized and investigated for the oxidative degradation of phenol in the presence of ozone. Characterizations were obtained by several techniques in order to investigate the nature of cobalt species and their morphological properties, depending on the system. Analyses by XRD, BET, TPR, UV-visible diffuse reflectance spectroscopy and TG/DT were performed. The CoNiAl hydrotalcite exhibits, after 4 h of reaction, the highest phenol ozonation activity followed by Co(3 wt%)/Al2O3-BaO and CoMgAl. The samples Co(1 …

PCSK9-D374Y mediated LDL-R degradation can be functionally inhibited by EGF-A and truncated EGF-A peptides. An in vitro study

2020

BIODEGRADABLE BILAYER FILMS PREPARED BY CO-EXTRUSION

2017

The sensitivity for reducing packaging waste drove academic and industrial efforts to search compostable or biodegradable bio-sourced polymeric materials. Multilayer systems represent a suitable strategy to obtain the required properties and to improve biopolymer performance. The aim of the current work is the coextrusion film blowing of a biodegradable bilayer film PLA/MaterBi with the purpose to overcome the drawbacks of the individual components.

Resource or waste? A perspective of plastics degradation in soil with a focus on end-of-life options.

2018

‘Capable-of-being-shaped’ synthetic compounds are prevailing today over horn, bone, leather, wood, stone, metal, glass, or ceramic in products that were previously left to natural materials. Plastic is, in fact, economical, simple, adaptable, and waterproof. Also, it is durable and resilient to natural degradation (although microbial species capable of degrading plastics do exist). In becoming a waste, plastic accumulation adversely affects ecosystems. The majority of plastic debris pollutes waters, accumulating in oceans. And, the behaviour and the quantity of plastic, which has become waste, are rather well documented in the water, in fact. This review collects existing information on pla…

Corrigendum to “The effect of silica nanoparticles on the morphology, mechanical properties and thermal degradation kinetics of PMMA [Pol. Degrad. St…

2012

Stability improvement of PMMA and Lumogen® coatings for hybrid white LEDs

2014

Hybrid white LEDs employing perylene-based dyes for the frequency down-conversion of blue light, generated by a standard inorganic source, suffer from colour rendering variations due to the degradation of the organic molecule under prolonged irradiation. To avoid such inconvenient, proper encapsulation of the dyes in resins or other polymer matrices can prevent their accelerated ageing; nevertheless, embedding polymers can also exhibit significant bleaching caused by chemico-physical agents. Among all, polymethyl methacrilate (PMMA) is one of the most used materials for the fabrication of hybrid LEDs' colour conversion coatings, therefore its stability needs to be investigated.

Automated multi-dimensional liquid chromatography

2004

A comprehensive on-line sample clean-up with an integrated two-dimensional HPLC system was developed for the analysis of natural peptides. Samples comprised of endogenous peptides with molecular weights up to 20 kDa were generated from human hemofiltrate (HF) obtained from patients with chronic renal failure. The (poly-)peptides were separated using novel silica-based restricted access materials with strong cation-exchange functionalities (SCX-RAM). The size-selective sample fractionation step is followed by cation-exchange chromatography as the first dimension. The subsequent second dimension of separation is based on hydrophobic interaction using four parallel short reversed-phase (RP) co…

The use of two-diode substitute model in predicting the efficiency of PV conversion in low solar conditions

2017

The article presents theoretical foundations of a two-diode equivalent model of a photovoltaic cell/module (PV), together with calculation procedures. A physical interpretation of individual components of an equivalent model was presented. Its practical application in predicting efficiency of operation of various PV cells and modules in low insulation conditions was demonstrated. The obtained predictions were verified with the actual results of their operation in open space (outdoor). The practical suitability of the “model” in early detection of ageing phenomena, such as, for example, absorber degradation taking place in PV modules, was demonstrated. The article was prepared on the basis o…

Application of the reduced I-V Blaesser’s characteristics in predicting PV modules and cells conversion efficiency in medium and high insolation cond…

2017

The article presents theoretical foundations of application of the reduced I-V Blaesser’s characteristics in predicting a photovoltaic cell/module (PV) efficiency, together with calculation procedures. A detailed analysis of the error of this transformation method of characteristics was carried out. Its practical application in predicting efficiency of operation of various PV cells and modules in medium and high insulation conditions was demonstrated. The practical suitability of the presented method in early detection of ageing phenomena, such as, for example, absorber degradation taking place in PV modules, was demonstrated. The article was prepared on the basis of the results of testing …

0331 : Pathophysiology of the ubiquitine ligase E3, PDZRN3, in the development of dilated cardiomyopathies

2015

Dilated cardiomyopathy is a major cause of heart failure with a poor prognostic. Molecular mechanisms underlying the transition toward the dilated phenotype are still not known. In heart, individual cardiomyocytes connect some with the others via their extremities by junctional platform (Intercalated Discs, ID) crucial for the mechanical coupling and the anisotropic conduction of the electric signal. In this project, we are interested in an Ubiquitine ligase E3 called PDZRN3, which is expressed and regulated in cardiomyocytes during their maturation. We have previously identified PDZRN3 involvement in the the Wnt Planar Cell Polarity (Wnt/PCP) signaling in vascular morphogenesis. In the hea…