Search results for " DIP"
showing 10 items of 1273 documents
CCDC 1048422: Experimental Crystal Structure Determination
2015
Related Article: Suraj Mondal, Shuvankar Mandal, Luca Carrella, Arpita Jana, Michel Fleck, Andreas Köhn, Eva Rentschler, and Sasankasekhar Mohanta|2015|Inorg.Chem.|54|117|doi:10.1021/ic501900d
CCDC 755833: Experimental Crystal Structure Determination
2011
Related Article: A.N.Georgopoulou, R.Adam, C.P.Raptopoulou, V.Psycharis, R.Ballesteros, B.Abarca, A.K.Boudalis|2010|Dalton Trans.|39|5020|doi:10.1039/b925525g
A.D. 2008: i colori ritrovati della Madonna del cardellino di Raffaello
2008
The manifestation of dipoles clustering in paraelectric phase of disordered ferroelectrics
2001
Abstract We predict the existence of Griffiths phase in the dielectrics with concentrational crossover between dipole glass (electric analog of spin glass) and ferroelectricity. The peculiar representatives of above substances are KTaO3: Li, Nb, Na or relaxor ferroelectrics like Pb1−xLaxZr0.65Ti0.35O3. Since this phase exists above ferroelectric phase transition temperature (but below that temperature for ordered substance), we call it “para-glass phase”. We assert that the difference between paraelectric and para-glass phase of above substances is the existence of clusters (inherent to “ordinary” Griffiths phase in Ising magnets) of correlated dipoles. We show that randomness play a decisi…
UV resistance of Bacillus subtilis spores - Involvement of DPA and characterization by photonic microscopy
2022
The aim of this project was to study the UVc resistance of Bacillus subtilis spores. The first part of this project focused on the dipicolinic acid molecule (DPA) which is known to be involved in the UV resistance of spores. However, some points remain unresolved. In particular, it is known that this molecule forms fluorescent photoproducts (DPAp), which were not identified at the beginning of this project. No information concerning the role of these DPAp in UVC resistance was available at that time. During this project, a protocol was established to follow the appearance of these photoproducts directly inside the spore core. A method was also set up to artificially introduce DPAp into the …
The anomalous magnetic moment of the muon in the Standard Model
2020
We are very grateful to the Fermilab Directorate and the Fermilab Theoretical Physics Department for their financial and logistical support of the first workshop of the Muon g -2 Theory Initiative (held near Fermilab in June 2017) [123], which was crucial for its success, and indeed for the successful start of the Initiative. Financial support for this workshop was also provided by the Fermilab Distinguished Scholars program, the Universities Research Association through a URA Visiting Scholar award, the Riken Brookhaven Research Center, and the Japan Society for the Promotion of Science under Grant No. KAKEHNHI-17H02906. We thank Shoji Hashimoto, Toru Iijima, Takashi Kaneko, and Shohei Nis…
Wait-and-switch stochastic model of the non-Debye relaxation. Derivation of the Burr survival probability
2006
Abstract Stochastic mechanism of relaxation, in which a dipole waits until a favourable condition for reorientation exists, is discussed. Assuming that an imposed direction of a dipole moment may be changed when a migrating defect reaches the dipole, we present a mathematically rigorous scheme relating the local random characteristics of a macroscopic system to its effective relaxation behaviour. We derive a relaxation function (the Burr survival probability) that is characterized by the stretched exponential or the power-law behaviour.
A hypothetical model of the influence of inorganic phosphate on the kinetics of pyruvate kinase
2000
This paper presents a simple solution to the problem of approximating the calculated curve of reaction progress to the measured curve which is usually disturbed by initial oscillation of auxiliary lactate dehydrogenase (LDH) reaction. The experiments leading to the determination of the apparent Km for phosphoenolpyruvate (PEP) and Vm were performed. For precise estimation of kinetic parameters (Km and Vm) of the M1 isozyme of pyruvate kinase (PK), measured by coupling it to LDH reaction, the sequence of Michaelis‐Menten for pyruvate kinase and second-order kinetics for lactate dehydrogenase reaction as well as a non-zero initial concentration of lactate was assumed. The functions of apparen…
Individual stereoisomers of phosphinic dipeptide inhibitor of leucine aminopeptidase
2008
Abstract Individual stereoisomers of the phosphinic pseudodipeptide hPheψ[P(O)(OH)CH2]Phe were obtained by stereoselective liquid chromatographic separation as N- and C-terminally protected derivative on quinidine carbamate modified silica stationary phase. The stereoisomeric purity, exceeding 95% for each fraction, was determined before and after deprotection using two independent methods. The absolute configuration was rationally assigned by application of enantiomerically pure phosphinic acid substrates in the synthetic procedure and correlation with biological activity of the products. Substantial differences in inhibition of leucine aminopeptidase by the individual isomers revealed nov…
Trimeric Hemibastadin Congener from the Marine Sponge Ianthella basta
2012
The first naturally occurring trimeric hemibastadin congener, sesquibastadin 1 (1), and the previously reported bastadins 3, 6, 7, 11, and 16 (2-6) were isolated from the marine sponge Ianthella basta, collected in Indonesia. The structure of 1 was elucidated on the basis of 1D and 2D NMR measurements and by HRMS. Among all the isolated compounds, the linear sesquibastadin 1 (1) and bastadin 3 (2) showed the strongest inhibition rates for at least 22 protein kinases (IC(50) = 0.1-6.5 μM), while the macrocyclic bastadins (3-6) demonstrated a strong cytotoxic potential against the murine lymphoma cell line L5178Y (IC(50) = 1.5-5.3 μM).