Search results for " Deriva"

showing 10 items of 718 documents

Initial Data for Non-Linear Evolution Equations and Differentiable Vectors of Group Representations

1995

Regularity properties of non-linear Lie algebra representations are defined. These properties are satisfied in examples given by evolution equations. We prove that this regularity implies that the set of C ∞ vectors for the non-linear group representation obtained by integration of the Lie algebra representation coincide with the set of C ∞ vectors of the linear part (the order one term) of this group representation.

AlgebraNonlinear systemLie algebra representationLie algebraDifferentiable functionWeak derivativeGroup representationMathematics
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The role of virtual work in Levi-Civita's parallel transport

2015

The current literature on history of science reports that Levi-Civita’s parallel transport was motivated by his attempt to provide the covariant derivative of the absolute differential calculus with a geometrical interpretation (For instance, see Scholz in The intersection of history and mathematics, Birkhauser, Basel, pp 203–230, 1994, Sect. 4). Levi-Civita’s memoir on the subject was explicitly aimed at simplifying the geometrical computation of the curvature of a Riemannian manifold. In the present paper, we wish to point out the possible role implicitly played by the principle of virtual work in Levi-Civita’s conceptual reasoning to formulate parallel transport.

AlgebraRicci calculusCurrent (mathematics)IntersectionParallel transportComputer scienceCalculusVirtual workRiemannian manifoldCurvatureCovariant derivativePAMM
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Stimulated emission and optical properties of pyranyliden fragment containing compounds in PVK matrix

2017

This work has been supported by National Research program “Multifunctional materials and composites, photonics and nanotechnology (IMIS2)”. Financial support provided by Scientific Research Project for Students and Young Researchers No. SJZ2015/12 realised at the Institute of Solid State Physics, University of Latvia is greatly acknowledged.

Amplified spontaneous emissionPhotoluminescenceMaterials scienceQuantum yieldElectron donor02 engineering and technologyPhotochemistry01 natural sciences010309 opticschemistry.chemical_compound0103 physical sciences:NATURAL SCIENCES:Physics [Research Subject Categories]Stimulated emissionElectrical and Electronic EngineeringAmplified spontaneous emissionGlass forming low molecular weight compoundsDCMLaser dyeDye laser021001 nanoscience & nanotechnologyThreshold energyAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialschemistryPyranyliden derivatives0210 nano-technologyMethyl group
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Headspace–mass spectrometry determination of benzene, toluene and the mixture of ethylbenzene and xylene isomers in soil samples using chemometrics

2007

A simple and fast method has been developed for the determination of benzene, toluene and the mixture of ethylbenzene and xylene isomers (BTEX) in soils. Samples were introduced in 10 mL standard glass vials of a headspace (HS) autosampler together with 150 microL of 2,6,10,14-tetramethylpentadecane, heated at 90 degrees C for 10 min and introduced in the mass spectrometer by using a transfer line heated at 250 degrees C as interface. The volatile fraction of samples was directly introduced into the source of the mass spectrometer which was scanned from m/z 75 to 110. A partial least squares (PLS) multivariate calibration approach based on a classical 3(3) calibration model was build with m…

Analytical chemistryBTEXXylenesMass spectrometryBiochemistryEthylbenzeneGas Chromatography-Mass SpectrometryMass SpectrometryAnalytical ChemistryChemometricsSoilchemistry.chemical_compoundIsomerismBenzene DerivativesEnvironmental ChemistryBenzeneSpectroscopyChromatographyChromatographyXyleneTemperatureBenzeneTolueneHydrocarbonsBiodegradation EnvironmentalModels ChemicalchemistryCalibrationGas chromatographyTolueneAnalytica Chimica Acta
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Influence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnets

2017

The syntheses, structures, magnetic, and proton conductivity properties of a family of bimetallic anilate-based compounds with inserted alkylammonium cations are presented. The structures of (Me2NH2)[MnIICrIII(Br2An)3]·2H2O (1), (Et2NH2)[MnIICrIII(Br2An)3] (2), (Et3NH)[MnIICrIII(Cl2An)3] (3), and [(Et)(i-Pr)2NH]-[MnIICrIII(Br2An)3]·(CHCl3)0.5·(H2O) (4) contain a 2D anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands. In 1, 2, and 3, the hexagonal holes of this network are occupied by Me2NH2+, Et2NH2+, or Et3NH+ cations. Interestingly, the small increase of size of the templating cation in 4 ([(Et)(i-Pr)2NH]+ in the place of Me2NH2+, Et2NH2+ or Et3NH+), gives ris…

Anilate-Based Magnets25-Dihydroxy-14-benzoquinone Dianion DerivativesProton010405 organic chemistryHexagonal crystal systemChemistryConductivity010402 general chemistry01 natural sciencesProton-conductivity0104 chemical sciencesIonInorganic ChemistryEspectroscopíaCrystallographyImanes superconductoresFerrimagnetismMagnetAnionesPhysical and Theoretical ChemistryBimetallic strip
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FRACTIONAL-ORDER GENERALIZATION OF TRANSPORT EQUATIONS IN FRACTAL POROUS MEDIA

2014

Anomalous diffusionHausdorff dimensionFractional derivativeTransport equations.
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Synthesis, biological evaluation, and molecular docking studies of aldotetronic acid-based LpxC inhibitors

2022

: In order to develop novel inhibitors of the bacterial deacetylase LpxC bearing a substituent to target the UDP binding site of the enzyme, a series of aldotetronic acid-based hydroxamic acids was accessed in chiral pool syntheses starting from 4,6-O-benzylidene-d-glucose and l-arabinitol. The synthesized hydroxamic acids were tested for LpxC inhibitory activity in vitro, revealing benzyl ether 17a ((2S,3S)-4-(benzyloxy)-N,3-dihydroxy-2-[(4-{[4-(morpholinomethyl)phenyl]ethynyl}benzyl)oxy]butanamide) as the most potent LpxC inhibitor. This compound was additionally tested for antibacterial activity against a panel of clinically relevant Gram-negative bacteria, bacterial uptake, and suscepti…

AntibioticsBacterial uptakeLpxC inhibitorsOrganic ChemistryDrug DiscoveryAldotetronic acid derivativesMolecular-docking studiesLasBMolecular BiologyBiochemistrySettore CHIM/08 - Chimica Farmaceutica
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New antifungals selected by molecular topology.

1999

Abstract Molecular topology has been applied to find the new lead antimycotic compounds. Among the selected compounds stands out 3,3′-(4,4′ - Biphenylene)bis(2,5-diphenyl-2H-tetrazolium chloride), Benztropine mesylate and Dicyclopentamethylenethiuram disulphide, with minimum inhibitory concentrations between 1.6 and 2 μg / mL.

Antifungal AgentsMolecular modelStereochemistryClinical BiochemistryBiphenyl derivativesPharmaceutical ScienceMicrobial Sensitivity TestsSaccharomyces cerevisiaeBiochemistryChloridechemistry.chemical_compoundStructure-Activity RelationshipDrug DiscoveryCandida albicansmedicineMolecular BiologyTopology (chemistry)Organic ChemistryDiscriminant AnalysisBiphenylenechemistryDrug DesignMolecular MedicineBenztropine MesylateMolecular topologymedicine.drugBioorganicmedicinal chemistry letters
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Chemical composition of essential oils of Anthemis secundiramea Biv. subsp. secundiramea (Asteraceae) collected wild in Sicily and their activity on …

2016

In the present study, the chemical composition of the essential oil from the aerial parts of Anthemis secundiramea Biv. subsp. secundiramea L. collected in Sicily was evaluated by GC and gas chromatography–mass spectrometry. The main components of A. secundiramea were (Z)-lyratyl acetate (14.6%), (Z)-chrysanthenyl acetate (9.9%), (Z)-chrysanthenol (8.7%) and (E)-chrysanthenyl acetate (7.7%). The comparing with other studied oils of genus Anthemis belonging to the same clade is discussed. Antibacterial and antifungal activities against some micro-organisms infesting historical art craft, were also determined.

AntifungalAntifungal Agentsmedicine.drug_classPlant compositionchrysanthenyl derivatives antibacterial and antifungal activityPlant ScienceAsteraceaeBiology01 natural sciencesBiochemistryGas Chromatography-Mass SpectrometryAnalytical Chemistrylaw.inventionBridged Bicyclo CompoundsGenuslawBotanyOils VolatilemedicinePlant OilsAnthemisSettore BIO/15 - Biologia FarmaceuticaSicilyChemical compositionEssential oilAnthemis secundiramea010405 organic chemistryOrganic ChemistrySettore CHIM/06 - Chimica OrganicaAsteraceaebiology.organism_classificationAnti-Bacterial Agents0104 chemical sciences(Z)-lyratyl acetatevolatile component010404 medicinal & biomolecular chemistryAnthemis secundiramea Biv. subsp. secundirameaMonoterpenesAnthemisArtNatural Product Research
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Novel isoquinoline derivatives as antimicrobial agents.

2013

The wide variety of potent biological activities of natural and synthetic isoquinoline alkaloids encouraged us to develop novel antimicrobial isoquinoline compounds. We synthesized a variety of differently functionalized 1-pentyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinolines (THIQs), including dihydroisoquinolinium salts (2 and 5), methyl pentanoate-THIQ (6), 1-pentanol-THIQ (7), ester derivatives (8-15) and carbamate derivatives (16-23). We employed classic intramolecular Bischler-Napieralski cyclodehydration to generate the isoquinoline core. All the structures were characterized by nuclear magnetic resonance and mass spectrometry. The bactericide and fungicide activities were evaluated f…

AntifungalCarbamateAntifungal Agentsmedicine.drug_classmedicine.medical_treatmentClinical BiochemistryPharmaceutical ScienceMicrobial Sensitivity TestsGram-Positive BacteriaBiochemistrychemistry.chemical_compoundStructure-Activity RelationshipAnti-Infective AgentsDrug DiscoveryGram-Negative BacteriamedicineOrganic chemistryStructure–activity relationshipIsoquinolineMolecular BiologyEster derivativesChemistryOrganic ChemistryFungiAntimicrobialIsoquinolinesAnti-Bacterial AgentsIntramolecular forceMolecular MedicineBioorganicmedicinal chemistry
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