Search results for " Detection"
showing 10 items of 1676 documents
The application of the supported liquid membrane and molecularly imprinted polymers as solid acceptor phase for selective extraction of biochanin A f…
2018
An efficient sample clean-up and preconcentration procedure for phytoestrogens analysis in urine has been developed. It was based on a combination of solid phase extraction with hollow-fiber supported liquid membrane and molecularly imprinted beads (MIPs-HF-SLM-SPE). The molecularly imprinted polymers (MIPs) were synthesized by precipitation polymerization technique with biochanin A (BCA) as a template, giving narrowly dispersed microspheres with a regular shape. As the functional monomer, (dimethylamino)ethyl methacrylate (-DEM) turned out to be better than methacrylic acid (MAA) to get the best-imprinted effects. The MIPs used as sorbents in the MIPs-HF-SLM-SPE extraction process exhibite…
Continuous-Variable Sampling from Photon-Added or Photon-Subtracted Squeezed States
2017
We introduce a new family of quantum circuits in Continuous Variables and we show that, relying on the widely accepted conjecture that the polynomial hierarchy of complexity classes does not collapse, their output probability distribution cannot be efficiently simulated by a classical computer. These circuits are composed of input photon-subtracted (or photon-added) squeezed states, passive linear optics evolution, and eight-port homodyne detection. We address the proof of hardness for the exact probability distribution of these quantum circuits by exploiting mappings onto different architectures of sub-universal quantum computers. We obtain both a worst-case and an average-case hardness re…
Correcting AVHRR Long Term Data Record V3 estimated LST from orbital drift effects
2012
Abstract NOAA (National Oceanic and Atmospheric Administration) satellite series is known to suffer from what is known as the orbital drift effect. The Long Term Data Record (LTDR [Pedelty et al., 2007]), which provides AVHRR (Advanced Very High Resolution Radiometer) data from these satellites for the 80s and the 90s, is also affected by this orbital drift. To correct this effect on Land Surface Temperature (LST) time series, a novel method is presented here, which consists in adjusting retrieved LST time series on the basis of statistical information extracted from the time series themselves. This method is as simple and straightforward as possible, in order to be implemented easily for s…
Novel algorithms for 3D surface point cloud boundary detection and edge reconstruction
2019
Abstract Tessellated surfaces generated from point clouds typically show inaccurate and jagged boundaries. This can lead to tolerance errors and problems such as machine judder if the model is used for ongoing manufacturing applications. This paper introduces a novel boundary point detection algorithm and spatial FFT-based filtering approach, which together allow for direct generation of low noise tessellated surfaces from point cloud data, which are not based on pre-defined threshold values. Existing detection techniques are optimized to detect points belonging to sharp edges and creases. The new algorithm is targeted at the detection of boundary points and it is able to do this better tha…
Continuous-Variable Instantaneous Quantum Computing is Hard to Sample
2017
Instantaneous quantum computing is a sub-universal quantum complexity class, whose circuits have proven to be hard to simulate classically in the Discrete-Variable (DV) realm. We extend this proof to the Continuous-Variable (CV) domain by using squeezed states and homodyne detection, and by exploring the properties of post-selected circuits. In order to treat post-selection in CVs we consider finitely-resolved homodyne detectors, corresponding to a realistic scheme based on discrete probability distributions of the measurement outcomes. The unavoidable errors stemming from the use of finitely squeezed states are suppressed through a qubit-into-oscillator GKP encoding of quantum information,…
Polarographic determination of tyrosinase activity in enzymatic reaction with tyrosine as a substrate
2003
A voltammetric investigation of tyrosinase activity is proposed as an alternative to the spectrophotometric method. Voltammetric approach provides low detection limit, high sensitivity and resistivity to the solution inhomogenity, as well as enables one to simultaneously monitor the dioxygen consumption in the reaction, which is an additional indicator of the tyrosinase enzymatic activity.
Selective chemisorption of carbon monoxide by organic-inorganic hybrid materials incorporating cobalt(III) corroles as sensing components.
2007
Twenty-one hybrid materials incorporating cobalt(III) corrole complexes were synthesized by a sol–gel process or by grafting the metallocorrole onto a mesostructured silica of the SBA-15 type. All the materials show an almost infinite selectivity for carbon monoxide with respect to dinitrogen and dioxygen in the low-pressure domain where the chemisorption phenomenon is predominant. This peculiar property is of prime importance for an application as a CO sensor. The selectivity slightly decreases at high pressures where nonselective physisorption phenomena mainly occur. The percentage of active sites for CO chemisorption ranges from 22 to 64 %. This low percentage may be attributable to inte…
Synthèse in situ de fluorophores organiques : formation de liaisons covalentes par déclenchement enzymatique et applications en biodétection
2017
Fluorescence imaging is a growing field of biology over the past decades. Intensive works mainly focused on instrumental developments and chemistry of contrast agents (probes), were already done to improve such bioanalytical technique. The main goal of this Ph. D. thesis was to explore various fluorogenic molecular platforms responsive to various (bio)chemical stimuli and capable of releasing organic fluorophores in the biological medium to analyze. This approach named "in-situsynthesis" is based on domino reactions belonging to the repertoire of "covalent chemistry", triggered by the target (bio)analyte. This kind of process should provide advanced fluorogenic probes with high signal-to-no…
Detection of damage in civil engineering structures by PCA on enviromental vibration data
2018
The dynamic behavior of civil engineering structures are usually studied by means of ambient vibration observations and their performance is analyzed by Peak Picking and/or Operational Modal Analysis methods. This paper reports the first results of a statistical multivariate approach, specifically Principal Component Analysis, to detect a suspected structural damage on a sicilian highway bridge. Furthermore, the damage simulated in a simple structural model made it possible to understand the characteristics of the method consisting in comparing the observed data on an undamaged structure with those coming from a damaged one.
Hyperspectral image classification using CNN: Application to industrial food packaging
2021
Abstract During food tray packaging, some contamination may exist due to the presence of undesired objects. It is essential to detect anomalies during the packaging process in order to discard the faulty tray and avoid human consumption. This study demonstrates the on-line classification feasibility when using hyperspectral imaging systems for real-time food packaging control by using Convolutional Neural Networks (CNN) as a classifier in heat-sealed food trays. A hyperspectral camera is used to capture individual food tray information and fed to a CNN classifier to detect faulty food trays with object contamination. The proposed system is able to detect up to eleven different contamination…