Search results for " Detection"

Auditory cortical and hippocampal local-field potentials to frequency deviant tones in urethane-anesthetized rats: An unexpected role of the sound fr…

2015

The human brain can automatically detect auditory changes, as indexed by the mismatch negativity of event-related potentials. The mechanisms that underlie this response are poorly understood. We recorded primary auditory cortical and hippocampal (dentate gyrus, CA1) local-field potentials to serial tones in urethane-anesthetized rats. In an oddball condition, a rare (deviant) tone (p = 0.11) randomly replaced a repeated (standard) tone. The deviant tone was either lower (2200, 2700, 3200, 3700 Hz) or higher (4300, 4800, 5300, 5800 Hz) in frequency than the standard tone (4000 Hz). In an equiprobability control condition, all nine tones were presented at random (p = 0.11). Differential respo…

Multitemporal Unmixing of Medium-Spatial-Resolution Satellite Images: A Case Study Using MERIS Images for Land-Cover Mapping

2011

Data from current medium-spatial-resolution imaging spectroradiometers are used for land-cover mapping and land-cover change detection at regional to global scales. However, few landscapes are homogeneous at these scales, and this creates the so-called mixed-pixel problem. In this context, this study explores the use of the linear spectral mixture model to extract subpixel land-cover composition from medium-spatial-resolution data. In particular, a time series of MEdium Resolution Imaging Spectrometer (MERIS) full-resolution (FR; pixel size of 300 m) images acquired over The Netherlands is used to illustrate this study. The Netherlands was selected because of the following: 1) the fragmenta…

Development of a coupled diffusion denuder system combined with gas chromatography/mass spectrometry for the separation and quantification of molecul…

2009

This study concerns the development of a coupled diffusion denuder system capable of separating and quantifying gaseous molecular iodine (I(2)) and two other highly reactive iodine species, ICl and HOI, which are collectively named activated iodine compounds (AIC). Both I(2) and AIC are key species in the atmospheric chemistry of iodine. 1,3,5-Trimethoxybenzene (1,3,5-TMB)- and alpha-cyclodextrin/(129)I(-) (alpha-CD/(129)I(-))-coated denuders proved to be suitable for the collection of gaseous AIC and I(2), respectively. The experimental collection efficiencies for AIC (tested as ICl) and I(2) agreed well with the theoretical values for gas flow rates in the range between 300 and 1800 mL mi…

Light-Activated Sensitive Probes for Amine Detection

2017

Our new, simple, and accurate colorimetric method is based on diarylethenes (DAEs) for the rapid detection of a wide range of primary and secondary amines. The probes consist of aldehyde- or ketone-substituted diarylethenes, which undergo an amine-induced decoloration reaction, selectively to give the ring-closed isomer. Thus, these probes can be activated at the desired moment by light irradiation, with a sensitivity that allows the detection of amines at concentrations as low as 10exp−6 M in solution. In addition, the practical immobilization of DAEs on paper makes it possible to detect biogenic amines, such as cadaverine, in the gas phase above a threshold of 12 ppbv within 30 seconds. P…

Separation of aminoalkanephosphonic acid enantiomers by indirect UV detection capillary electrophoresis with application of cyclodextrins.

2003

Indirect UV detection capillary electrophoresis (CE) was used for the separation of aminoalkanephosphonic acid (AP) enantiomers by applying commercially available cyclodextrins as chiral discriminators. The results show that the separation of the enantiomers depends on pH of the background electrolyte, the molar ratio of cyclodextrin to aminophosphonic acid, and on the type of the applied chiral selector. Optimization of process conditions allowed enantiomeric baseline separation or partial separation of 12 out of 14 alpha-aminophosphonic acids studied. This type of CE might therefore be successfully used for routine determination of enantiomeric purity of aminophosphonic acids.

Out-of-phase second harmonic detection as a tool for the determination of relaxation times

2014

Chromogenic Detection of Aqueous Formaldehyde Using Functionalized Silica Nanoparticles

2016

Silica nanoparticles functionalized with thiol reactive units and bulky polar polyamines were used for the selective colorimetric detection of formaldehyde. The reaction of thiols groups in the nanoparticles surface with a squaraine dye resulted in loss of the pi-conjugation of the chromophores, and the subsequent bleaching of the solution. However, when formaldehyde was present in the suspension, the thiol-squaraine reaction was inhibited and a chromogenic response was observed. A selective response to formaldehyde was observed only when the thiol and polyamine groups were anchored to the silica surface. The observed selective response was ascribed to the fact that bulky polyamines generat…

Series arc faults in AC and DC electrical circuits. Characterization and detection methods

2013

This paper analyzes the problem of the arc faults in both AC and DC low voltage electrical circuits. The state-of-the-art of the arc fault detection methods is analyzed together with the UL 1699 and UL 1699B Standard requirements for protection devices against arc faults (AFCIs). An experimental characterization is carried out of the arc fault phenomenon, for both AC and DC systems, focusing the attention on series arcs. The experimental measurements are carried out on a proper test bench, which has been developed in order to reproduce significant arcing conditions, in accordance with the UL 1699 Standard requirements.

Caratterizzazione e metodi di riconoscimento degli arc faults per applicazioni in sistemi di bassa tensione

2013

Decision-cache based XACML authorisation and anonymisation for XML documents

2012

Author's version of an article in the journal: Computer Standards and Interfaces. Also available from the publisher at: http://dx.doi.org/10.1016/j.csi.2011.10.007 This paper describes a decision cache for the eXtensible Access Control Markup Language (XACML) that supports fine-grained authorisation and anonymisation of XML based messages and documents down to XML attribute and element level. The decision cache is implemented as an XACML obligation service, where a specification of the XML elements to be authorised and anonymised is sent to the Policy Enforcement Point (PEP) during initial authorisation. Further authorisation of individual XML elements according to the authorisation specifi…