Search results for " Emission spectroscopy"

Chemical characterization of ancient potteries from Himera and Pestavecchia necropolis (Sicily, Italy) by Inductively Coupled Plasma–Optical Emission…

2011

Abstract Thirty-eight samples of pottery were analyzed for determining chemical composition in order to establish their provenance. The potteries tested in the present research come from Himera and Pestavecchia archaeological sites. After digestion in microwave oven, the samples have been analyzed for fourteen minor elements (Ba, Cd, Co, Cr, Cu, Ga, Li, Mn, Ni, Pb, Sr, Ti, Tl, and Zn) and six major elements (Al, Ca, Fe, K, Mg, and Na). Chemical analysis was carried out by Inductively Coupled Plasma–Optical Emission Spectroscopy (ICP–OES). The most abundant minor elements are Cr, Ba and Ni. Cr concentration ranged from 66 to 3635 mg kg − 1 , Ba concentration ranged from 388 to 2677 mg kg − 1…

Determination of Calcium in Certain Fertilizers by Inductively Coupled Plasma Atomic Emission Spectrometry: Studies of Some Spectral and Interelement…

1997

Abstract Four analytical wavelengths (393.366, 396.847, 317.933, and 422.673 nm) were used to determine Ca in 2 fertilizers by inductively coupled plasma atomic emission spectroscopy (ICP-AES). Matrix effects were studied by adding to real fertilizer solutions fertilizer elements that are known or believed to interfere with Ca determination. Matrix effects were calculated by multiple linear regression. Interference was caused by S, K, or B. At 422.673 nm, the interference of B and K is a spectral effect, and at 396.847 and 317.933 nm, the interference of S and K is an interelement effect. At 393.366 nm, no linear interference was found. The best wavelength for determining Ca in fertilizers …

Iron Determination in Fertilizers by Inductively Coupled Plasma Atomic Emission Spectrometry: Study of Spectral and Interelement Effects at Different…

1996

Abstract Four analytical wavelengths of iron (238.204, 239.562, 259.940, and 240.488 nm) were tested for determination of Fe in fertilizers by inductively cou pled plasma atomic emission spectroscopy (ICP AES). Variations in measurements were caused by the changing interference pattern at different wave lengths evaluated by multiple linear regression. Thus, results obtained with different wavelengths are not comparable. Ca, P, and K were typical ele ments causing interference in almost all examined Fe wavelengths. Wavelength Fe II 238.204 nm is the best wavelength for determination of Fe in fertiliz ers by ICP-AES. Method accuracy is ± 8% at the ex amined Fe levels in fertilizers.

Determination of Magnesium in Fertilizers by Inductively Coupled Plasma Atomic Emission Spectrometry: Studies of Some Spectral and Interelement Effec…

1995

Abstract Four analytical wavelengths of magnesium were tested for determination of Mg from fertilizers by inductively coupled plasma atomic emission spectroscopy (ICP-AES): 202.528, 285.213, and 383.826 nm (Mg I) and 279.553 (Mg II). The effects of fertilizer matrix elements on Mg determination were examined by adding matrix elements to fertilizer solutions. Multiple linear regression calculations proved a valuable technique for evaluating the effects of matrix elements on Mg determination. The observed interferences at Mg wavelengths may be both spectral and interelement. Interelement effects were typically caused by Na, K, and Ca, and spectral effects, by P, Fe, and S. The best wavelength…

The Complex Morphology of the X-ray and Optical Emission from HH 154: The Pulsed Jet Scenario

2009

We study the optical and X-ray emission from protostellar jets, focusing, in particular, on the case of HH 154. This project consists of two different and complementary approaches: the development of hydrodynamical models of the jet/ambient interaction, and the analysis of multi-wavelength observations. Comparing the results derived from the simulations with the observations we can infer the physical mechanisms leading to the complex morphology of the X-rays source observed at the base of HH 154.

Optical Spectroscopy of Short-Lived Isotopes

1979

This chapter will concentrate on a special branch of the large field of optical spectroscopy, namely, the study of hyperfine structure (hfs) and isotope shift (IS) of short-lived isotopes. Such investigations give information on some basic properties of these nuclei: the spin ( ), the magnetic moment (μI), the spectroscopic quadrupole moment (Q s ), and the change of the mean square charge radius between different isotopes (δ〈r 2〉).

Optical Plasma Diagnostics During Reactive Magnetron Sputtering

2008

Liquid sample introduction in inductively coupled plasma atomic emission and mass spectrometry — Critical review

2014

Abstract Inductively coupled plasma optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS) can be considered as the most important tools in inorganic analytical chemistry. Huge progress has been made since the first analytical applications of the ICP. More stable RF generators, improved spectrometers and detection systems were designed along with the achievements gained from advanced microelectronics, leading to overall greatly improved analytical performance of such instruments. In contrast, for the vast majority of cases liquid sample introduction is still based on the pneumatic principle as described in the late 19th century. High flow pneumatic nebulizers typically deman…

Chemical characterization of ancient liturgical vestment (chasuble) by Inductively Coupled Plasma–Optical Emission Spectrometry (ICP–OES)

2016

Abstract This paper presents the chemical characterization of the yarns of an ancient liturgical vestment (chasuble). The samples have been analyzed for Al, Ag, Au, Cd, Co, Cr, Cu, Ni, Pb and Zn using amounts always less than 1 mg by Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES). Except a sample, silver is the most abundant element in all the yarns. In the samples containing silver, it ranged from 68 to 97%. Only two samples contain aluminum. Although the investigated chasuble is recorded in the inventory as an artifact of the XV century, a part of the yarns is composed of materials attributed to later period. In fact, the voluntary use of aluminum in metal alloys is du…

Partial least squares modelization of energy dispersive X-ray fluorescence.

2019

As a proof of concept, a green methodology has been developed for the energy dispersive X-ray fluorescence (ED-XRF) determination of calcium, potassium, iron, magnesium, aluminum, chromium, strontium, phosphorus and nickel in the peel of untreated kaki fruit (Diospyros kaki. L) samples. ED-XRF spectra of fifty-six kakis purchased in the local area of LLombay (Valencia) were obtained directly from samples without any previous treatment and without sample damage just after cleaning the fruit with distilled water. Inductively Couple Plasma Optical Emission Spectrometry (ICP-OES) was used as a reference method to determine the mineral elements after microwave assisted acid digestion. XRF spectr…