Search results for " FRAMEWORK"
showing 10 items of 893 documents
Reversible Solvatomagnetic Switching in a Spongelike Manganese(II)-Copper(II) 3D Open Framework with a Pillared Square/Octagonal Layer Architecture
2012
The concept of "molecular magnetic sponges" was introduced for the first time in 1999 by the creative imagination of the late Olivier Kahn. It refers to the exotic spongelike behavior of certain molecule-based materials that undergo a dramatic change of their magnetic properties upon reversible dehydration/rehydration processes. Here we report a unique example of a manganese(II)-copper(II) mixed-metal-organic framework of formula [Na(H(2)O)(4)](4)[Mn(4){Cu(2)(mpba)(2)(H(2)O)(4)}(3)]·56.5H(2)O (1) (mpba=N,N'-1,3-phenylenebis(oxamate)). Compound 1 possesses a 3D Mn(II)(4)Cu(II)(6) pillared layer structure with mixed square and octagonal pores of approximate dimensions 1.2×1.2 nm and 2.1×3.0 n…
Adopting XML for Large-Scale Information
2011
This book has presented many different ways to encode information in XML format and the purposes for doing so. In this concluding chapter we consider problems related to managing XML information assets and the methods available to address those problems. Approaches for persistently storing XML data can be divided into file storage and database storage, and the research community has been especially active in designing new solutions for XML databases. However, adoption of XML often means massive migration procedures from some legacy data into the XML format; examples of migration cases are given. While describing the problems related to adopting XML, we give examples of the kinds of data fo…
Why Use XML?
2011
Since its inception a decade ago, XML has become a standard technology for software engineers, all Web browsers are able to parse and show XML documents, and huge XML data resources are available from the Internet. Many of the documents are in XHTML, but other XML applications are quite common as well. XML has also become a format that is increasingly common in the files of local disks. This success would not have been possible without collaborative efforts throughout the Web community. Such world-wide collaborative development has included standards, software applications, and case implementations that can serve as models when developing new solutions. In this chapter we consider what ki…
Solvent-free synthesis of ZIFs: a route toward the elusive Fe(II) analogue of ZIF-8
2019
Herein we report the synthesis of an elusive metal-organic framework, the iron(II) analogue of ZIF-8 with the formula Fe(2-methylimidazolate) , here denoted as MUV-3. The preparation of this highly interesting porous material, inaccessible by common synthetic procedures, occurs in a solvent-free reaction upon addition of an easily detachable template molecule, yielding single crystals of MUV-3. This methodology can be extended to other metals and imidazolate derivatives, allowing the preparation of ZIF-8, ZIF-67, and the unprecedented iron(II) ZIFs Fe(2-ethylimidazolate) and Fe(2-methylbenzimidazolate) . The different performance of MUV-3 toward NO sorption, in comparison to ZIF-8, results …
A Mobile Computing Framework for Pervasive Adaptive Platforms
2012
International audience; Ubiquitous computing is now the new computing trend, such systems that interact with their environment require self-adaptability. Bioinspiration is a natural candidate to provide the capability to handle complex and changing scenarios. This paper presents a programming framework dedicated to pervasive platforms programming. This bioinspired and agentoriented framework has been developed within the frame of the PERPLEXUS European project that is intended to provide support for bioinspiration-driven system adaptability. This framework enables the platform to adapt itself to application requirements at high-level while using hardware acceleration at node level. The resu…
Land use functions — a multifunctionality approach to assess the impact of land use changes on land use sustainability
2008
Part 5. Regional and local evaluation - 17; International audience; The dramatic changes in land use observed in Europe in the last fifty years have generally resulted in improvement of human welfare and economic development. On the other hand, they have caused serious environmental problems. There is therefore a need for approaches that help to understand in an integrative way the economic, environmental and societal impacts that land use changes have on sustainability. Sustainability Impact Assessment(SIA), which assesses the impact of policies on sustainability, addresses this challenge. SIA partly builds on the concept of the multifunctionality of land which helps to deal with the compl…
Développement d’un outil d’aide à la décision pour la gestion intégrée des adventices
2016
Integrated weed management consists in using several weed management techniques in a long-term approach. The vast number of techniques precludes cropping systems from being easily conceived and climatic interactions render the systems difficult to pursue. Farmers and farm advisors need decision support systems (DSS) to develop weed management strategies adapted to multicriteria/multiobjectives of weed management, to the economic, social and environmental stakes and to the constraints of farmers. Such a DSS is developed from the mechanistic weed dynamic model FLORSYS. This model is a “virtual field” allowing the evaluation of the performance of agricultural systems over a large range of agri…
University Governance and Finance: The Impact of Changes in Resource Allocation on Decision Making Structures
2002
When trying to account for changes that take place over time in the structure of any organisation, social scientists often use a conceptual framework known as resource dependency theory. This theory assumes that organisations survive only if they are able to react to changes that occur in the world around them in order to obtain the resources they need to stay in operation. Since they have the capacity for independent action, organisations are not passively shaped by their environment; they sometimes are also able to influence it.
Developing a framework for designing humanitarian blockchain projects
2021
International audience; Blockchain technology promises to improve the efficiency, transparency, and accountability of humanitarian operations. Yet at the same time, especially the humanitarian context with its characteristic volatility poses unique challenges to any technology. Most prominent are the humanitarian principles that are fundamental to humanitarian operations. These ethical principles are set to protect the most vulnerable populations. Designing blockchain projects in the humanitarian context therefore requires a systematic framework that helps humanitarians make critical choices.While some design instructions can be found for commercial applications, the humanitarian context re…
A 3D multispectral integrated acquisition system : acquisition, data coding and compression
2010
We have developed an integrated system permitting the simultaneous acquisition of the 3D shape and the spectral spectral reflectance of scanned object surfaces. We call this system a 3D multispectral scanner because it combines within a stereopair, a multispectral video camera and a structured light projector. We see several application possibilities for a such acquisition system but we want to highlight applications in the field of digital archiving and broadcasting for heritage objects. In the manuscript we first introduce the acquisition system and its necessary calibrations and treatments needed for his use. Then, once the acquisition system is functional, data that are generated are ri…