Search results for " Fisica"

Geminal Ionic Liquids: A Combined Approach to Investigate their Tridimensional Structure

2009

Different investigations, such as 1D and 2D NMR spectroscopy, resonance light scattering spectroscopy and molecular dynamics simulations, have been jointly used to achieve a deeper understanding of the degree of structural order in two geminal ionic liquids. In particular, 3,3’-di-n-butyl-1,1’-(1,3- phenylenedimethylene)diimidazolium and 3,3’-di-n-butyl-1,1’-(1,4-phenylenedimethylene) diimidazolium bis- ACHTUNGTRENUNG[bis(trifluoromethanesulfonyl)imide] have been studied. These geminal ionic liquids were chosen because of the presence of both a rigid phenylenedimethylene link between two imidazolium rings, which should give a high degree of order to the solvent system, and the different sha…

Controlling laser assisted radiative recombination with few-cycle laser pulse

2007

We report on the radiative recombination of a free electron with a hydrogenic ion in the presence of a few-cycle pulses. It has been shown that the main features of the emission spectra may be described in the framework of a semiclassical model in which the recombination is viewed as a two-step process. The spectra width of the emitted photon energy is practically confined in a range of values in which the emission is classically allowed. Moreover, it has been found that spectra width can be controlled by varying the carrier envelope phase and/or the pulse peak intensity

Ligand-Centred Fluorescence and Electronic Relaxation Cascade at Vibrational Time Scales in Transition-Metal Complexes

2015

Using femtosecond-resolved photoluminescence up-conversion, we report the observation of the fluorescence of the high-lying ligand-centered (LC) electronic state upon 266 nm excitation of an iridium complex, Ir(ppy)(3), with a lifetime of 70 +/- 10 fs. It is accompanied by a simultaneous emission of all lower-lying electronic states, except the lowest triplet metal-to-ligand charge-transfer ((MLCT)-M-3) state that shows a rise on the same time scale. Thus, we observe the departure, the intermediate steps, and the arrival of the relaxation cascade spanning similar to 1.6 eV from the (LC)-L-1 state to the lowest 3MLCT state, which then yields the long-lived luminescence of the molecule. This …

Dynamics of Metal Centers Monitored by Nuclear Inelastic Scattering

2005

Nuclear inelastic scattering of synchrotron radiation has been used now since 10 years as a tool for vibrational spectroscopy. This method has turned out especially useful in case of large molecules that contain a M\"ossbauer active metal center. Recent applications to iron-sulfur proteins, to iron(II) spin crossover complexes and to tin-DNA complexes are discussed. Special emphasis is given to the combination of nuclear inelastic scattering and density functional calculations.

Concentration growth and thermal stability of gamma-ray induced Germanium lone pair center in Ge-doped sol-gel SiO2

2008

Jet mass and substructure of inclusive jets in $ \sqrt {s} = 7\;{\text{TeV}} $ pp collisions with the ATLAS experiment

2012

Recent studies have highlighted the potential of jet substructure techniques to identify the hadronic decays of boosted heavy particles. These studies all rely upon the assumption that the internal substructure of jets generated by QCD radiation is well understood. In this article, this assumption is tested on an inclusive sample of jets recorded with the ATLAS detector in 2010, which corresponds to 35 pb-1 of pp collisions delivered by the LHC at √s = 7TeV. In a subsample of events with single pp collisions, measurements corrected for detector efficiency and resolution are presented with full systematic uncertainties. Jet invariant mass, kt splitting scales and N-subjettiness variables are…

Monitoring Risk Factors and Improving Adherence to Therapy in Patients With Chronic Kidney Disease (Smit-CKD Project): Pilot Observational Study

2022

Background Chronic kidney disease is a major public health issue, with about 13% of the general adult population and 30% of the elderly affected. Patients in the last stage of this disease have an almost uniquely high risk of death and cardiovascular events, with reduced adherence to therapy representing an additional risk factor for cardiovascular morbidity and mortality. Considering the increased penetration of mobile phones, a mobile app could educate patients to autonomously monitor cardiorenal risk factors. Objective With this background in mind, we developed an integrated system of a server and app with the aim of improving self-monitoring of cardiovascular and renal risk factors and…

Improving statistical methodologies for landslide susceptibility modelling at regional and basin scale. Applications in the Sicilian and Salvadoran t…

2022

Landslides susceptibility stochastic modelling under earthquakes and rainfalls triggering: applications to 2001 earthquakes (13th January and 13th Fe…

2022

Fabrication and characterization of Metal and Metal Oxide Nanostructures Grown by metal displacement deposition into anodic alumina membranes

2011

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