6533b826fe1ef96bd1284708

RESEARCH PRODUCT

Dynamics of Metal Centers Monitored by Nuclear Inelastic Scattering

Volker SchünemannGianfranco La MannaRudolf RüfferPatrick WegnerJuliusz A. WolnyChristian L. SchmidtAleksandr I. ChumakovHeiner WinklerIlya SergueevLars H. BöttgerArturo SilvestriGiampaolo BaroneHauke PaulsenAlfred X. Trautwein

subject

iron-sulfur proteinspin crossover complexeChemical Physics (physics.chem-ph)Nuclear and High Energy PhysicsMaterials scienceFOS: Physical sciencesSynchrotron radiationInfrared spectroscopyInelastic scatteringCondensed Matter Physicsvibrational spectroscopyAtomic and Molecular Physics and Opticsnuclear inelastic scatteringMetalSettore CHIM/03 - Chimica Generale E InorganicaSpin crossovervisual_artPhysics - Chemical PhysicsMössbauer spectroscopyvisual_art.visual_art_mediumMoleculedensity functional theory calculationsPhysical and Theoretical ChemistryAtomic physicsSettore CHIM/02 - Chimica Fisica

description

Nuclear inelastic scattering of synchrotron radiation has been used now since 10 years as a tool for vibrational spectroscopy. This method has turned out especially useful in case of large molecules that contain a M\"ossbauer active metal center. Recent applications to iron-sulfur proteins, to iron(II) spin crossover complexes and to tin-DNA complexes are discussed. Special emphasis is given to the combination of nuclear inelastic scattering and density functional calculations.

yearjournalcountryeditionlanguage
2005-09-01
10.1007/s10751-006-9242-4http://arxiv.org/abs/1206.2760