Search results for " Fisica"

NONEQUILIBRIUM PHENOMENA AND METASTABILITY IN MESOSCOPIC AND QUANTUM SYSTEMS

2020

Here we summarize some relevant results related to nonequilibrium phenomena in mesoscopic and quantum systems. A common phenomenon in the dynamics of out-of-equilibrium systems is the metastability, and the problem of the lifetime of metastable states involves fundamental aspects of nonequilibrium statistical mechanics. Metastability (see Fig. 1) is a signature of a first order phase transition, often characterized by a long-living metastable state. In particular, the stability of a metastable state can be enhanced by Gaussian and non-Gaussian noise sources. This counterintuitive effect has been found in different physical areas, ranging from spintronics, aggregation kinetics of Brownian pa…

Metodi adattativi e modelli multi agente per la valutazione del comfort indoor

2008

Trasmissione del calore nei letti fluidizzati con liquidi

2007

Lo studio dei fenomeni relativi all’idrodinamica ed allo scambio termico nei letti fluidizzati è di grande interesse nell’Energetica industriale. Infatti è necessaria la loro comprensione per proporre modelli affidabili ai fini della progettazione e della simulazione del funzionamento delle tante apparecchiature nelle quali essi si manifestano. In molti processi industriali i contatti e le interazioni tra fluidi, siano essi liquidi o gas, e particolati solidi consentono una grande varietà di utili applicazioni. Si tratta del campo dell’ingegneria della fluidizzazione, che ha suscitato un ampio interesse fin dalla realizzazione, durante la Seconda Guerra Mondiale, dei reattori a letto fluido…

An Iranian booklet: non destructive examination by Energy Dispersive X-Ray Diffractometry and Micro-Raman Spectroscopy

2009

Energy Dispersive X-Ray Diffractometry was used in combination with micro-Raman Spectroscopy to study an undated illuminated Iranian booklet. In both cases, no preliminary preparation of the samples was needed: the data were acquired in a non-destructive way in a natural environment. The book is of particular interest because of the unusual presence of miniatures on some pages. The two techniques were used to collect data from small areas of the pages and in different regions of the miniature in order to identify inks and pigments and to attempt chronological assignment. Raman spectra were affected by strong background fluorescence. In spite of this, different peaks were detected and identi…

Energy and economic assessment of a small domestic wind turbine in Palermo

2016

The cost effectiveness of micro-wind technology is closely linked to the annual energy production plants, which strongly depends on the wind characteristics and on the morphological properties of the installation site. The power curve of a wind turbine, supplied by manufacturers, characterizes the theoretical energy performance that it should have at a particular site. The behavior of a wind turbine in the field is affected by the speed but also by wind direction variations. At each change of direction and speed, the turbine will try to adapt to new conditions and the phase transition negatively influences the energy production. In order to experimentally confirm what above mentioned, the a…

A microwave cylindrical cavity made of bulk MgB2 superconductor produced by reactive liquid Mg infiltration process

2007

Dielectric properties of myoglobin at 10 GHz by microwave cavity perturbation measurements

2010

We report on the temperature dependence, at microwave (mw) frequency, of the imaginary part of the dielectric constant (En) in myoglobin powder samples with different hydration levels (h). The measurements have been performed by the cavity perturbation technique, in the range of temperature 80-345 K. The sample is located inside a glass capillary along the axis of a cylindrical copper cavity, resonating in the TE011 mode at 9.6 GHz, where the mw electric field has a node. By measuring the variation of the quality factor of the resonant cavity, one can extract the imaginary part of the dielectric constant. At temperatures higher than 230 K we observe an evident increase of the dielectric los…

Microwave response of bulk MgB2 samples of different granularity

2006

The microwave response of three high-density bulk MgB2 samples has been investigated in the linear and nonlinear regimes. The three samples, characterized by different mean size of grains, have been obtained by reactive infiltration of liquid Mg in powdered B preforms. The linear response has been studied by measuring the microwave surface impedance; the nonlinear response by detecting the power radiated by the sample at the second-harmonic frequency of the driving field. Our results suggest that bulk MgB2 prepared by the liquid Mg infiltration technique is particularly promising for manufacturing resonant cavities operating at microwave frequencies.

Green conditions for the Suzuki reaction using microwave irradiation and a new HNT- supported ionic liquid-like phase (HNT-SILLP) catalyst

2014

A new catalytic system based on modified halloysite nanotubes was employed in the Suzuki reaction under microwave irradi- ation. A set of solvents, times and bases was screened and the best experimental conditions were obtained when the reactions were carried out for 10 min in water–ethanol at 120 °C in presence of K2CO3 as base. Good recyclability was observed. The new catalytic system was employed using either 1 mol% or 0.1 mol%. The palladium catalyst displayed good activity, allowing the synthesis of several biphenyl compounds in high yield working with only 0.1 mol% palladium loading. The application of mi- crowave irradiation decreased the reaction time and also improved conversion wi…

Investigation on the stability of dispersion of zirconia nanoparticles prepared by microwave- hydrothermal synthesis

2005

Difficulties in reproducing the performances of nanoparticles dispersions are obstructive for the progress of the nanotechnology. A plausible reason for this variability is the lack of the control of the stability as well as the dimensions of the nanoparticles in the dispersions. In this work we report results of investigations on the stability of zirconia nanoparticles in aqueous medium, monitoring nanoparticles sizes by means of Transmission Electron Microscopy (TEM), Dynamic Light Scattering (DLS). Nanocrystalline zirconia powders, prepared by microwave-hydrothermal synthesis, were determined to be 6-8 nm in size by TEM observations. By using DLS technique the as-prepared dispersions wit…