Search results for " Force"

Direct Visualization of Molecule Deprotonation on an Insulating Surface

2012

Elucidating molecular-scale details of basic reaction steps on surfaces is decisive for a fundamental understanding of molecular reactivity within many fields, including catalysis and on-surface synthesis. Here, the deprotonation of 2,5-dihydroxybenzoic acid (DHBA) deposited onto calcite (101;4) held at room temperature is followed in situ by noncontact atomic force microscopy. After deposition, the molecules form two coexisting phases, a transient striped phase and a stable dense phase. A detailed analysis of high-resolution noncontact atomic force microscopy images indicates the transient striped phase being a bulk-like phase, which requires hydrogen bonds between the carboxylic acid moie…

Asymmetric Organocatalytic Synthesis of 4-Aminoisochromanones via a Direct One-Pot Intramolecular Mannich Reaction

2016

Synthesis 48(24), 4451 - 4458(2016). doi:10.1055/s-0035-1562522

Donor-π-acceptors containing the 10-(1,3-dithiol-2-ylidene)anthracene unit for dye-sensitized solar cells

2012

Two donor-acceptor molecular tweezers incorporating the 10-(1,3-dithiol-2-ylidene)anthracene unit as donor group and two cyanoacrylic units as accepting/anchoring groups are reported as metal-free sensitizers for dye-sensitized solar cells. By changing the phenyl spacer with 3,4-ethylenedioxythiophene (EDOT) units, the absorption spectrum of the sensitizer is red-shifted with a corresponding increase in the molar absorptivity. Density functional calculations confirmed the intramolecular charge-transfer nature of the lowest-energy absorption bands. The new dyes are highly distorted from planarity and are bound to the TiO(2) surface through the two anchoring groups in a unidentate binding for…

Optical and structural properties of Al 2 O 3 /ZnO nanolaminates deposited by ALD method

2014

International audience; We report on the investigation of optical and structural properties of Al2O3/ZnO nanolaminates. The nanolaminates were deposited on Si and glass substrates by Atomic layer deposition method. Structural properties of nanolaminates were studied by SEM, GIXRD, and AFM. Optical characterization was performed by transmittance and photoluminescence spectroscopy. Complex analysis of monolayer properties was done by ellipsometry. Optical constants for Al2O3 and ZnO monolayer were calculated.

Specificity of weightlifting bench exercises in kayaking sprint performance: A perspective for neuromuscular training

2022

Several studies showed significant differences between bench lift exercises without investigating which is more related, in biomechanical and neuromuscular terms, to improve the sprint flatwater kayak performance. This study aims to compare the power-load and velocity-load neuromuscular parameters performed in prone bench pull (PBP), and bench press (BP) exercises to identify which of them meet the gesture specificity in sprint flatwater kayak performance. Ten elite kayakers participated in this study. Power-load, velocity-load relationships, the maximum dynamic strength, and the kayak sprint performance test were assessed. The power-load and velocity-load relationships showed significant d…

Interactions of membranes with coarse-grain proteins: a comparison

2012

We study the interactions between lipid bilayers and rigid transmembrane proteins by Monte Carlo simulations of generic coarse-grain models. Different popular protein models are considered and compared with each other, and key parameters such as the hydrophobicity and the hydrophobic mismatch are varied systematically. Furthermore, the properties of the membrane are manipulated by applying different tensions. The response of the membrane to the insertion of single proteins is found to be mostly generic and independent of the choice of the protein model. Likewise, the orientational distributions of single proteins depend mainly on the hydrophobic mismatch and the hydrophobicity of the protei…

Relational Dialectics in Intercultural Couples' Relationships

2011

El procés de patrimonialització de les festes de la Mare de Déu de la Salut d'Algemesí (1959-2020)

2022

L’objecte d’estudi d’aquesta investigació és el procés de patrimonialització de les festes de la Mare de Déu de la Salut d’Algemesí –en endavant la Festa–. Des de 1880, la Festa s’estructura en una trilogia de seguicis processionals (la Processó de les Promeses, la Processoneta del Matí i la Processó de Volta General), realitzats els dies 7 i 8 de setembre, cada un amb un itinerari diferent i en el qual participen una sèrie de danses (Muixeranga, Nova Muixeranga, Bastonets, Arquets, Carxofa, Pastorets, Llauradores i Tornejants), la música que les acompanya, realitzada en la majoria de les danses amb dolçaina i tabal, i una sèrie d'elements religiosos, el més important la imatge de la Mare d…

Noncovalent axial I∙∙∙Pt∙∙∙I interactions in platinum(II) complexes strengthen in the excited state

2021

Abstract Coordination compounds of platinum(II) participate in various noncovalent axial interactions involving metal center. Weakly bound axial ligands can be electrophilic or nucleophilic; however, interactions with nucleophiles are compromised by electron density clashing. Consequently, simultaneous axial interaction of platinum(II) with two nucleophilic ligands is almost unprecedented. Herein, we report structural and computational study of a platinum(II) complex possessing such intramolecular noncovalent I⋅⋅⋅Pt⋅⋅⋅I interactions. Structural analysis indicates that the two iodine atoms approach the platinum(II) center in a “side‐on” fashion and act as nucleophilic ligands. According to c…

Struttura galleggiante ad elevata stabilità (Floating structure with high stability)

2015

DESCRIZIONE GENERALE La struttura galleggiante innovativa è composta da diversi elementi modulari collegati fra loro. La composizione modulare della struttura consente di conferirle la lunghezza dettata dalle particolari esigenze da soddisfare. Tipiche applicazioni della struttura galleggiate innovativa sono i pontili, le passerelle pedonali o ciclabili su specchi d'acqua, e in generale le opere finalizzate a consentire lo spostamento di persone, merci e/o veicoli fra punti di uno specchio d'acqua (marino o lacustre) utilizzando strutture galleggianti. Ogni modulo, lungo 10-15 m, è tenuto a galla dalla spinta di Archimede sulle sue parti immerse (le carene), spinta che nella struttura innov…