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showing 10 items of 67 documents

Synthèse de mono et diphosphines dérivées d'amino acides ou de peptides, appliquées en chimie de coordination et pour le greffage de fullerène C60

2013

The synthesis of secondary phosphine borane amino acids or dipeptides and their applications for the preparation of chiral ligands or for the grafting of fullerene, is described. These compounds were synthesized in good yield (up to 98%) without racemization. The principle of the synthesis is based on the alkylation of primary phosphine borane with a γ-iodo amino acid using phase transfer conditions. Tertiary diphosphine amino acids are obtained with 70% yield after a second alkylation. These compounds are one of the first examples of diphosphine grafted with a P-C bond on the side chain of amino acid. First of all, mono and diphosphine amino acid derivatives were used in asymmetric allylic…

Secondary PhosphineFullerene by hydrophosphinationPhase transfer conditionDiphosphinesAlkylation[CHIM.ORGA]Chemical Sciences/Organic chemistryCytotoxicityHydrophosphination du fullerène[CHIM.ORGA] Chemical Sciences/Organic chemistryElectrochimieAsymetric catalysisPhosphines secondairesDiphosphineCatalyse asymétrique[ CHIM.ORGA ] Chemical Sciences/Organic chemistryCytotoxicitéElectrochemistryTransfert de phase
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As the change in ternary agent structure influence the chiral recognition ability of pyrene/heptakis-(6-amino)-(6-deoxy)-b-cyclodextrin

Settore CHIM/06 - Chimica OrganicaCyclodextrin fullerene
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Cyclodextrin-[60]fullerene conjugates: Synthesis, characterization and electrochemical behavior

Settore CHIM/06 - Chimica Organicacyclodextrin fullerene
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Full scale tests of the base-isolation system for an emergency hospital

2019

The paper presents the results of some full-scale tests regarding the base-isolation system of the emergency room building of the polyclinic hospital in Palermo (Italy). This building has been recently realized and its base isolation system is characterized by double friction pendulum isolators. Static lateral pushing tests were aimed at identifying fundamental mechanical properties of the whole isolation level (e.g. friction forces and stiffness) in order to verify the agreement with the design hypotheses. Further dynamic tests provided different displacements of the isolated base followed by the instantaneous release (snap-back tests), in order to verify the effectiveness, the mechanical …

Settore ICAR/09 - Tecnica Delle Costruzionifull-scale experimental tests.Computer scienceseismic isolationsnap-back testSeismic isolationfrictionFriction pendulum bearing seismic isolation snap-back test friction in-situ testing full-scale experimental tests.Full scale testBase isolationFriction pendulum bearingin-situ testingMarine engineering
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Rateless Codes Performance Analysis in Correlated Channel Model for GEO Free Space Optics Downlinks

2012

Settore ING-INF/03 - TelecomunicazioniFree Space Optics (FSO) technologies for satellite communications offer several advantages: wide bandwidth high rate capability immunity to electromagnetic interference and small equipment size. Thus they are suitable for inter-satellite links deep space communications and also for high data rate ground-to-satellite/satellite-to-ground communications. Nevertheless FSO links suffer impairments that cause power signal degradation at the receiver. Scattering and absorption cause power signal attenuations predictable by suitable deterministic models. Optical turbulence causes random irradiance fluctuations which can generate signal fading events and can thereby only be predicted by statistical models. Attenuation and fading events can corrupt FSO links and so it would be recommended to add mitigation error codes on the communication link. FSO channel can be described as an erasure channel: fading events can cause erasure errors. We have identified in rateless codes (RCs) a suitable solution to be employed in FSO links. RCs do not need feedback and they add a redundant coding on the source data that allows the receiver to recover the whole payload despite erasure errors. We implemented two different of rateless codes: Luby Transform (LT) and Raptor. We analyzed their performances on a simulated turbulent GEO FSO downlink (1 Gbps - OOK modulation) at a 106 μm wavelength and for different values of zenith angles. Assuming a plane-wave propagation and employing Hufnagel-Valley we modeled the downlink using: 1) a temporal correlated channel model based on Gamma-Gamma probability distribution and 2) an irradiance covariance function that we converted on a time function using Taylor frozen eddies hypothesis. Our new channel model is able to simulate irradiance fluctuations at different turbulence conditions as it will be shown in the full paper. We will also report performance results of LT and Raptor codes at overhead range varying between 0 and 50% and for different values of source packets.Settore ING-INF/01 - Elettronica
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Assessing the Effect of Drivers’ Gender on Their Intention to Use Fully Automated Vehicles

2021

Although fully automated vehicles (SAE level 5) are expected to acquire a major relevance for transportation dynamics by the next few years, the number of studies addressing their perceived benefits from the perspective of human factors remains substantially limited. This study aimed, firstly, to assess the relationships among drivers’ demographic factors, their assessment of five key features of automated vehicles (i.e., increased connectivity, reduced driving demands, fuel and trip-related efficiency, and safety improvements), and their intention to use them, and secondly, to test the predictive role of the feature’ valuations over usage intention, focusing on gender as a key …

TechnologyQH301-705.5QC1-999vehicle automation; features; fully automated cars; Multi-Group Structural Equation Modeling (MGSEM); gender; intention; drivers; roadway technologiesCarreteresgenderfeaturesGeneral Materials ScienceBiology (General)QD1-999InstrumentationAutomatitzacióFluid Flow and Transfer ProcessesSeguretat viàriaTPhysicsProcess Chemistry and TechnologyGeneral EngineeringVehiclesfully automated carsEngineering (General). Civil engineering (General)vehicle automationComputer Science ApplicationsMulti-Group Structural Equation Modeling (MGSEM)ChemistryintentionTecnologiaTA1-2040Applied Sciences
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Surveying in the Valley of the Temples

2014

Full-waveform terrestrial laser scanning enables high-precision 3D topographic modelling of unstable rock valleys that is valuable for various geomorphological investigations. The area below the archaeological site of Temple of Juno in Agrigento, Sicily, is characterised by the presence of large sections of rock that have fallen down from the upper ridge. In this context, full-waveform laser scanning technology was tested for the production of a highly detailed 3D topographic model at two resolutions (2cm and 20cm) for simulating potential rockfall paths at the site.

Terrestrial Laser Scanner 3D Model Full Waveform DTM Geomorphology.Settore ICAR/06 - Topografia E Cartografia
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Il ruolo del white paper sulle offerte al pubblico di cripto-attività alla luce della proposta MiCA

2022

La proposta MiCA, nel regolare il white paper sulle offerte di crypto-assets, sembra tenere in considerazione i benefici e i limiti dei sistemi di voluntary e di mandatory disclosure, non optando integralmente né per il primo, né per il secondo. In quest’ottica, se può condividersi l’approccio regolamentare diretto a graduare, a seconda della tipologia di token offerto, sia il contenuto che l’assoggettamento del documento a mera notifica o ad approvazione ex ante da parte dell’Autorità competente, dubbi sorgono in ordine all’indistinta allocazione dell’onere della prova in capo all’oblato, nei casi di violazione della disciplina del relativo white paper.

The MiCa proposal in the regular white paper on crypto-assets offerings seems to take into account the benefits and limitations of voluntary and mandatory disclosure systems not opting for either the former or the latter in full. On one hand one can agree with the regulatory approach aimed at adapting the content of the white paper to the type of token offered and at making the white paper either subject to mere notification or to the approval by the competent Authority depending on the asset offered. On the other hand doubts arise on the indistinct allocation of the burden of proof to the user in case of infringement of the relevant white paper framework.Settore IUS/04 - Diritto Commerciale
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Il lavoro etero-organizzato prima e dopo il caso Foodora Italia.

2019

l contributo ripropone la discussione sull’esegesi della fattispecie disciplinata dall’art. 1 comma 2 del d. lgs. n. 81 del 2015 (nel testo anteriore alla riforma del 2019) trattata dall’autore nei Colloqui Giuridici sul Lavoro del 2015 (a cura) di Antonio Vallebona per il Massimario di Giurisprudenza del Lavoro. Lo studio rigettava la tesi che il lavoro organizzato dal committente fosse la terza fattispecie e anzi con riferimento delle condizioni di applicazio­ne dimostrava la necessità di una lettura includente. La conclusione era che la nuova disciplina aveva natura antifraudolenta e determinava un allargamento (relativo) dell’area della subordi­nazione conseguente alla riduzione del cam…

This article republishes (after the Italian Supreme Court judgement n.166/2020 on the Foodora Italia case) the contribution to the exegesis of the case brought by art. 1 para­graph 2 of the d. lgs. n. 81 of 2015 (in the text before the 2019 reform) delivered by the author in the 2015's "Colloqui Giuridici sul Lavoro" (edited) by Antonio Vallebona for the "Massimario di Giurisprudenza del Lavoro". The study rejected the thesis that the job organ­ised by the client was an intermediate regulation between the employee and the self-employed ones. Indeed regarding the conditions for its application it showed the need for extensive reading. The conclusion was that the new discipline was (and is) an anti-fraudulent one. It led to a (relative) expansion of the area ofsubordination as a consequence of a reduction in the scope of coordinated self-employed work. A little more than four years after that article the Italian Supreme Court (with the judgement n.166/2020) on the Foodora Italia case addresses for the first time the issue of the hetero-organised work (by art. 1 paragraph 2 of the d. lgs. n. 81 of 2015). The Supreme Court fully adheres to the paper's thesis. So in terms of the "re­medial" function of the standardthe nature of the organisation's specific conditionand eventually reducing the legal frame for coordinated work. The fact that the procedural matter dealt with the riders was (then and now is) utterly irrelevant for the correct interpretation of such a new provision. Giving to riders of the employee status is not an effect of the peculiarit­ies of the work through digital platforms. It is a consequence of the remedial nature of such a case-law.
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Full-Waveform Terrestrial Laser Scanning for Extracting a High-Resolution 3D Topographic Model: a Case Study on an Area of Archaeological Significance

2014

AbstractThis paper describes a method, which uses full-waveform terrestrial laser scanning to survey the surface of the slope below the Temple of Juno, located in the Valley of the Temples in Agrigento (Sicily, Southern Italy). The surface is characterized by the presence of large rock blocks, which have fallen down from the upper side; possible further detachments of rock blocks would cause a situation of general instability, with a very high risk to the archaeological structures in the near future. The methodology was designed to evaluate the potential of full-waveform laser scanning technology for the production of a very high resolution 3D topographic model of the slope, to be used as a…

Very high resolutionAtmospheric Science010504 meteorology & atmospheric sciencesLaser scanningTopographic modelApplied MathematicsResolution (electron density)0211 other engineering and technologiesTerrestrial laser scanning02 engineering and technologyGeotechnical analysisTerrestrial Laser Scanner 3D Model Full Waveform DTM Geomorphology01 natural sciencesArchaeologyComputers in Earth SciencesVery high riskGeologyFull waveformSettore ICAR/06 - Topografia E Cartografia021101 geological & geomatics engineering0105 earth and related environmental sciencesGeneral Environmental Science
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