Search results for " GC"
showing 6 items of 86 documents
Polycyclic Aromatic Hydrocarbons (PAH) in Volcano island (Aeolian archipelago) mud utilized for therapeutic purpose
2007
This paper examines the possible presence, distribution, nature and sources of 18 Polycyclic Aromatic Hydrocarbons (PAH) as constituents of the mud pools collected in Vulcano Aeolian Island. PAH are important from environmental and toxicological point of view. Analysis was performed by gas chromatography/mass spectrometry (GC/MS) in selected ion monitoring (SIM). The total concentration of Polycyclic Aromatic Hydrocarbons ranged from 112 to 154 μ g/Kg of dry matrix. The volcanic mud, used for therapeutic purposes, are moderately contaminated.
Mass spectrometry coupled to chromatography systems and cultural heritage: a case study on the content of an ancient jar
2009
In this chapter an introduction to mass spectrometry will be given, with particular reference to mass spectrometry coupled to chromatography systems. Further some mass spectrometry applications in the field of cultural heritage will be briefly reported and discussed. Finally a experimental investigation on the content of an ancient jar will be reported. Together with experimental details a description of the techniques adopted, results obtained and forthcoming experiments will be also given.
Halogenated Anesthetics Determination in Urine by SPME/GC/MS and Urine Levels Relationship Evaluation with Surgical Theatres Contamination
2014
In this work, a new sensitive analytical method has been developed and evaluated for the determination of the most commonly used gaseous anesthetics, desflurane, sevoflurane, and this latter’s hepatic metabolite hexafluoroisopropanol (HFIP) in the urine. In addition, an evaluation of anesthetics exposition on the urine levels of a small population of surgical operators has been performed and results are briefly discussed.
Role of volatile and contact pheromones in the mating behaviour of Bagrada hilaris (Heteroptera: Pentatomidae)
2008
Volatiles and contact pheromones involved in the mating behaviour of the Painted bug, Bagrada hilaris Burmeister (Het- eroptera: Pentatomidae), were investigated in behavioural and chemical experiments. Vertical open Y-shaped olfactometer bioassays showed that odour from males attract females but not males, while that from females did not attract either gender. Adult females were also attracted by hexane extracts of volatile compounds collected from males. In open arena bioassays, males displayed the characteristic steps of courtship behaviour in the presence of virgin females. Such courtship behaviour was displayed in the presence of females killed by freezing, but not in the presence of f…
Volatile compounds released by disturbed and undisturbed adults of Anchomenus dorsalis (Coleoptera, Carabidae, Platynini) and structure of the pygidi…
2011
Volatile compounds produced by adults of Anchomenus dorsalis under undisturbed and disturbed conditions were investigated with an all-glass aeration apparatus. GC-MS analysis of the crude extracts from undisturbed and disturbed adults highlighted four major volatile compounds, undecane, heneicosane, Z-9 tricosene and tricosane, of which significantly more undecane was released by disturbed adults compared to undisturbed beetles. The pygidial glands of adults of A. dorsalis were investigated using light and Transmission Electron Microscopy (TEM). Each gland showed dense aggregates of secretory cells organized into visually distinct lobes; a long collecting canal that drains the secretion tow…
Coherent conditional probabilities and proper scoring rules
2011
In this paper we study the relationship between the notion of coherence for conditional probability assessments on a family of conditional events and the notion of admissibility with respect to scoring rules. By extending a recent result given in literature for unconditional events, we prove, for any given strictly proper scoring rule s, the equivalence between the coherence of a conditional probability assessment and its admissibility with respect to s. In this paper we focus our analysis on the case of continuous bounded scoring rules. In this context a key role is also played by Bregman divergence and by a related theoretical aspect. Finally, we briefly illustrate a possible way of defin…