Search results for " Ga"
showing 10 items of 12404 documents
Noble gas magmatic signature of the Andean Northern Volcanic Zone from fluid inclusions in minerals
2021
Trace volatile elements like He are key for understanding the mantle source signature of magmas and to better constrain the relative roles of subduction and crustal processes to the variability of along-arc chemical and isotopic signatures of magmatic fluids. Here we report on noble gas abundances and isotopic data of Fluid Inclusions (FIs) in eruptive products and/or fumarolic gases from the Colombia-Ecuador segment of Andean Northern Volcanic Zone (NVZ). FIs in olivine phenocrysts from Ecuador (El Reventador, Cotopaxi and Tungurahua) yield air-normalized corrected He-3/He-4 ratios of 7.0-7.4 R-A, within the MORB range (8 +/- 1 R-A). With exception of the Cotopaxi lavas (opx = 50 km at the…
Geochemistry of Noble Gases and CO2 in Fluid Inclusions From Lithospheric Mantle Beneath Wilcza Góra (Lower Silesia, Southwest Poland)
2018
Knowledge of the products originating from the subcontinental lithospheric mantle (SCLM) is crucial for constraining the geochemical features and evolution of the mantle. This study investigated the chemistry and isotope composition (noble gases and CO2 ) of fluid inclusions (FI) from selected mantle xenoliths originating from Wilcza Góra (Lower Silesia, southwest Poland), with the aim of integrating their petrography and mineral chemistry. Mantle xenoliths are mostly harzburgites and sometimes bear amphiboles, and are brought to the surface by intraplate alkaline basalts that erupted outside the north-easternmost part of the Eger (Ohře) Rift in Lower Silesia. Olivine (Ol) is classified int…
Reaction path models of magmatic gas scrubbing
2016
Gas-water-rock reactions taking place within volcano-hosted hydrothermal systems scrub reactive, water-soluble species (sulfur, halogens) from the magmatic gas phase, and as such play a major control on the composition of surface gas manifestations. A number of quantitative models of magmatic gas scrubbing have been proposed in the past, but no systematic comparison of model results with observations from natural systems has been carried out, to date. Here, we present the results of novel numerical simulations, in which we initialized models of hydrothermal gas-water-rock at conditions relevant to Icelandic volcanism. We focus on Iceland as an example of a "wet" volcanic region where scrubb…
High-resolution spectroscopy and analysis of the nu3/2nu4 dyad of CF4
2011
International audience; CF4 is a strong greenhouse gas of both anthropogenic and natural origin [D.R. Worton et al., Environ. Sci. Technol. 41, 2184 (2007)]. However, high-resolution infrared spectroscopy of this molecule has received only a limited interest up to now. Until very recently, the public databases only contained cross-sections for this species, but no detailed line list. We reinvestigate here the strongly absorbing ν3 region around 7.8 μm. New Fourier transform infrared (FTIR) spectra up to a maximal resolution of 0.0025 cm−1 have been recorded: (i) room-temperature spectra in a static cell and (ii) a supersonic expansion jet spectrum at a 23 K estimated temperature. Following …
Pre- and syn-eruptive geochemistry of volcanic gases from Soufriere Hills of Montserrat, West Indies
1998
International audience; Soufriere Hills fumaroles contained magmaderived volatiles before and during the eruption initiated in 1995 but also preserved a typical and quite steady hydrothermal coinposition. Chemical changes due to increased boiling and a greater input of oxidizing magmatic gas occurred only at Galway's Soufriere, the most active fumarolic field. Hydrothermal buffering of the fumaroles has been favoured by their remote location (!-2 km) froin the eruptive vents and by a preferential degassing of the uprising magma through intrusive conduits under the crater. High temperature (720øC) gas collected froin the extruding lava dome in Feb. 1996 was chemically and isotopically repres…
Understanding volcanoes in the Vanuatu arc
2016
We report the first helium isotope survey of volcanic gases, hot springs and some olivine phenocrysts along the Vanuatu island arc, from Tanna in the south to Vanua Lava in the north. Low CO2 content and low He-3/He-4 ratios in thermal fluids of Epi (4.0 +/- 0.1 R-a), Efate (4.5 +/- 0.1 R-a) and Pentecost (5.3 +/- 0.5 R-a) islands coherently indicate reduced mantle gas leakage and crustal contamination by radiogenic helium on these extinct volcanic systems of the former (Pliocene) arc. Instead, presently active Vanuatu volcanoes display He-3/He-4 and C/He-3 ratios typical of subduction-related volcanic arcs: He-3/He-4 ratios range from 6.4 +/- 0.5 Ra in southernmost Tanna and 7.23 +/- 0.09 …
Prodigious emission rates and magma degassing budget of major, trace and radioactive volatile species from Ambrym basaltic volcano, Vanuatu island Arc
2016
Abstract Ambrym volcano, in the Vanuatu arc, is one of the most active volcanoes of the Southwest Pacific region, where persistent lava lake and/or Strombolian activity sustains voluminous gas plume emissions. Here we report on the first comprehensive budget for the discharge of major, minor, trace and radioactive volatile species from Ambrym volcano, as well as the first data for volatiles dissolved in its basaltic magma (olivine-hosted melt inclusions). In situ MultiGAS analysis of H 2 O, CO 2 , SO 2 and H 2 S in crater rim emissions, coupled with filter-pack determination of SO 2 , halogens, stable and radioactive metals demonstrates a common magmatic source for volcanic gases emitted by…
Using mosses as biomonitors to study trace element emissions and their distribution in six different volcanic areas
2017
Volcanoes emit SO2, CO2, and H2S, but also trace elements gases and particles such as As, Cd, Cr, Cu, Hg, Ni, Pb, and Sb. Active moss bag biomonitoring, an easy to apply and low budget method, was used to determine trace element release from volcanic areas of different geological context and climates. Exposure height variations (0.7â1.6 m above ground) due to different availability of natural tie points did not affect the results. Accumulation was linear for exposure durations from three days to nine weeks, so values were comparable by normalization to moss exposure time. Uncovered moss bags showed higher accumulation than co-exposed covered ones because of additional dust and wet deposit…
Top-of-Atmosphere Retrieval of Multiple Crop Traits Using Variational Heteroscedastic Gaussian Processes within a Hybrid Workflow.
2021
In support of cropland monitoring, operational Copernicus Sentinel-2 (S2) data became available globally and can be explored for the retrieval of important crop traits. Based on a hybrid workflow, retrieval models for six essential biochemical and biophysical crop traits were developed for both S2 bottom-of-atmosphere (BOA) L2A and S2 top-of-atmosphere (TOA) L1C data. A variational heteroscedastic Gaussian process regression (VHGPR) algorithm was trained with simulations generated by the combined leaf-canopy reflectance model PROSAILat the BOA scale and further combined with the Second Simulation of a Satellite Signal in the Solar Spectrum (6SV) atmosphere model at the TOA scale. Establishe…
Exploitation of SAR and Optical Sentinel Data to Detect Rice Crop and Estimate Seasonal Dynamics of Leaf Area Index
2017
This paper presents and evaluates multitemporal LAI estimates derived from Sentinel-2A data on rice cultivated area identified using time series of Sentinel-1A images over the main European rice districts for the 2016 crop season. This study combines the information conveyed by Sentinel-1A and Sentinel-2A into a high-resolution LAI retrieval chain. Rice crop was detected using an operational multi-temporal rule-based algorithm, and LAI estimates were obtained by inverting the PROSAIL radiative transfer model with Gaussian process regression. Direct validation was performed with in situ LAI measurements acquired in coordinated field campaigns in three countries (Italy, Spain and Greece). Res…