Search results for " Gc-MS"
showing 10 items of 32 documents
Comparison between Different Techniques for Volatiles Analyses in Coriander (Coriandrum sativum L.)
2011
Although many papers have been devoted to the study of Coriander fruits aromatic pattern, many differences show up according not only to the provenience of seeds, but also to the analytical methods chosen. In our work, samples from one Coriander small-seeded biotype has been analysed, verifying the differences between (1) the oil extracted by means of a Soxhlet apparatus (2) the same oil sampled by means of HS-SPME and (3) the HS-SPME on the roughly ground seeds, all analysed by direct injection in the GC-MS. The volatile composition detected by means of HS-SPME on oil resembles tightly that performed on Soxhlet extract. With respect to the direct injection, the HS-SPME shows a higher sensi…
La Tecnica della microestrazione in fase solida (SPME) per l'analisi quantitativa e qualitativa dei feromoni sessuali degli insetti fitofagi: il caso…
2002
Determination of selected phthalates by gas chromatography–mass spectrometry in mural paintings from Palermo (Italy)
2013
Abstract Phthalate esters for decades, and probably even now, were used as softeners in water-based paintings. In general, these compounds are dangerous owing to their carcinogenicity and reproductive effects. Phthalates are not chemically but only physically bound to the matrices, hence, they may be leached into the environment and are ubiquitously found in environmental matrices. Considering that, construction is one of most important fields in Europe, and probably worldwide, with respect to its economic, technological and environmental impact. In the present work the phthalate esters content of several mural paintings was evaluated by gas chromatography–mass spectrometry (GC-MS). Because…
Photodegradation of selected phthalates on mural painting surfaces under UV light irradiation
2014
Abstract The esters of phthalic acid are considered as hazardous pollutants due to their mutagenicity, carcinogenicity and are also classified as endocrine disruptor chemicals. Several compounds of this class of substances for decades, and probably even now, were used as softeners in water-based synthetic paintings. Surfaces and structures, such as house walls painted with phthalates based paintings, can be a concern to construction workers engaged in demolition, restore and paint removal activities if they are not protected from hazardous dust inhalation. In this paper we report the results of an investigation about phthalate ester degradation by direct UV irradiation at 254 nm. The result…
CHEMICAL AND BOTANICAL CHARACTERIZATION OF A ROSMARINUS OFFICINALIS L. BIOTYPE FROM SICILY
2006
Rosemary (Rosmarinus officinalis L.) is widely cultivated all over the world as ornamental and aromatic plant. Today, the interest towards its cultivation is strongly arising, due to the many biological activities exerted by the essential oil extracted from its leaves and flowers. Which compounds confer to Rosemary's essential oil its properties is still unclear, but it seems likely that these effects must be attributed to a mixture of different principles, acting contemporarily and synergically. The diverse composition of the essential oils of Rosemary's ecotypes coming from different geographical areas could be the reason of their various level of activity. With the aim of obtaining furth…
Indagini di laboratorio sui composti che inducono l'aggregazione delle neanidi di I età in Leptoglossus occidentalis (Hemiptera, Coreidae)
2011
Leptoglossus occidentalis è una cimice che si alimenta degli strobili e dei semi delle conifere appartenenti alla famiglia delle Pinaceae. Le neanidi di I età hanno un comportamento gregario che favorisce la sopravvivenza degli individui, in analogia a quanto visto in altre specie appartenenti allo stesso genere (Wheeler et al., 1990). L’individuazione dei composti semiochimici che influenzano questo comportamento potrebbe portare allo sviluppo di nuovi metodi di controllo di L. occidentalis. Le estrazioni (whole body) sono state realizzate su gruppi di 7-27 neanidi di I età per 30 minuti utilizzando un quantitativo di 40µl di esano o di acetone per neanide. Gli estratti sono stati biosaggi…
Il feromone sessuale a breve raggio del parassitoide oofago Trissolcus brochymenae
2009
Il comportamento sessuale dei parassitoidi presenta una fase di pre-copula, in cui si ha ricerca, corteggiamento e riconoscimento dell’altro sesso, alla quale seguono le fasi di copula ed eventualmente post-copula. Durante la pre-copula, la localizzazione e il riconoscimento sono per lo più stimolati da composti feromonali con diversa volatilità. I composti feromonali ad alta volatilità, rilasciati dalle femmine, sono utilizzati dai maschi per l’orientamento a lunga distanza, mentre quelli scarsamente volatili mediano il comportamento di corteggiamento. In questo lavoro si riportano dati sperimentali sul feromone sessuale a breve raggio emesso dalle femmine di Trissolcus brochymenae (Hymeno…
Sexual communication in the egg parasitoid Trissolcus brochymenae
2009
The males of the egg parasitoid Trissolcus brochymenae (Hymenoptera Scelionidae) exploit a short range pheromone for recognition of the other gender. To evaluate the role of this pheromone, the behavior of virgin males has been studied in closed arena when exposed to the following cues: 1) virgin females (alive, dead "washed" with solvents, dead" unwashed"); 2) dissected and re-assembled virgin females (females dissected into head, mesosoma, and gaster, then reassembled using two solvent "washed" parts and an "unwashed” part, or "unwashed" legs assembled with entire" washed" body); 3) "washed" females treated with acetone extracts (of virgin females and of legs). Males antennate and mount v…
Modifications over time of volatile compounds in coriander (Coriandrum sativum L.)
2007
Coriander (Coriandrum sativum L.) is an annual strongly-smelling herb belonging to the family Apiaceae, which is cultivated all over the world for its aromatic fruits (“seeds”) and, in many Asiatic and South American countries, for its green leaves. The aromatic features of leaves and fruits are sharply different, and the strong smell coming from leaves (many times referred to as a “bug” scent) is not always pleasant to many consumers from western countries. In our work, one Coriander small-seeded biotype has been grown in plastic covered greenhouses, and at given time intervals samples of leaves, flowers and fruits have been analyzed by means of HS-SPME and GC-MS to study the evolution ove…