Search results for " Humidity"

Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F–BEACh 2014 field study

2017

Abstract. The chemical composition of organic aerosols was analyzed using complementary mass spectrometric techniques during a field study in Central Europe in July 2014 (Fichtelgebirge – Biogenic Emission and Aerosol Chemistry, F–BEACh 2014). Aerosols were analyzed in real-time by Aerosol Flowing Atmospheric-Pressure Afterglow Mass Spectrometry (AeroFAPA–MS), Aerosol Mass Spectrometry (AMS), and Chemical Ionization Atmospheric-Pressure interface Time-of-Flight Mass Spectrometry (CI–APiToF–MS). In addition, offline detection of acidic organic compounds was conducted by non-target screening of filter samples using High Resolution Mass Spectrometry (HRMS) in combination with Ultra-High Pressu…

2016

Abstract. Gaseous formaldehyde (HCHO) is an important precursor of OH radicals and a key intermediate molecule in the oxidation of atmospheric volatile organic compounds (VOCs). Budget analyses reveal large discrepancies between modeled and observed HCHO concentrations in the atmosphere. Here, we investigate the interactions of gaseous HCHO with soil surfaces through coated-wall flow tube experiments applying atmospherically relevant HCHO concentrations of  ∼  10 to 40 ppbv. For the determination of uptake coefficients (γ), we provide a Matlab code to account for the diffusion correction under laminar flow conditions. Under dry conditions (relative humidity  =  0 %), an initial γ of (1.1 ± …

2018

Abstract. Accurate measurement of water vapor in the climate-sensitive region near the tropopause is very challenging. Unexplained systematic discrepancies between measurements at low water vapor mixing ratios made by different instruments on airborne platforms have limited our ability to adequately address a number of relevant scientific questions on the humidity distribution, cloud formation and climate impact in that region. Therefore, during the past decade, the scientific community has undertaken substantial efforts to understand these discrepancies and improve the quality of water vapor measurements. This study presents a comprehensive intercomparison of airborne state-of-the-art in s…

Properties of individual contrails: a compilation of observations and some comparisons

2017

International audience; Mean properties of individual contrails are characterized for a wide range of jet aircraft as a function of age during their life cycle from seconds to 11.5 h (7.4-18.7 km altitude, -88 to -31 °C ambient temperature), based on a compilation of about 230 previous in situ and remote sensing measurements. The airborne, satellite, and ground-based observations encompass exhaust contrails from jet aircraft from 1972 onwards, as well as a few older data for propeller aircraft. The contrails are characterized by mean ice particle sizes and concentrations, extinction, ice water content, optical depth, geometrical depth, and contrail width. Integral contrail properties includ…

The scavenging of two different types of marine aerosol particles calculated using a two-dimensional detailed cloud model

2011

Our 2-D dynamic model including spectral microphysics and scavenging has been evaluated for a warm precipitating convective cloud at Day 261 (18 September 1974) of the GATE campaign. Two different chemical species ((NH 4 ) 2 SO 4 and NaCl) of aerosol particles were followed in the air, inside the drops in the cloud, and inside the drops reaching the ground. Concerning the dynamics and microphysics, as well as the scavenging and wet deposition, the model results agree quite well with available observations. The cloud rained after 19 min of cloud life time. For the considered aerosol loading of the atmosphere, rough estimates are derived for the total material processed by such a warm convect…

Fluorescent biological aerosol particle measurements at a tropical high-altitude site in southern India during the southwest monsoon season

2016

An ultraviolet aerodynamic particle sizer (UV-APS) was continuously operated for the first time during two seasons to sample the contrasting winds during monsoon and winter to characterize the properties of fluorescent biological aerosol particles (FBAPs), at a high-altitude site in India. Averaged over the entire monsoon campaign (1 June–21 August 2014), the arithmetic mean number and mass concentrations of coarse-mode (> 1 µm) FBAPs were 0.02 cm−3 and 0.24 µg m−3, respectively, which corresponded to  ∼  2 and 6 % of total aerosol loading, respectively. Average FBAP number size distribution exhibited a peak at  ∼  3 µm, which is attributed to the fungal spores, as supported by scanning …

2012

Abstract. One of the major uncertainties in the understanding of Earth's climate system is the interaction between solar radiation and aerosols in the atmosphere. Aerosols exposed to high humidity will change their chemical, physical, and optical properties due to their increased water content. To model hydrated aerosols, atmospheric chemistry and climate models often use the volume weighted mixing rule to predict the complex refractive index (RI) of aerosols when they interact with high relative humidity, and, in general, assume homogeneous mixing. This study explores the validity of these assumptions. A humidified cavity ring down aerosol spectrometer (CRD-AS) and a tandem hygroscopic DMA…

Contrast in column-integrated aerosol optical properties during heating and non-heating seasons at Urumqi — Its causes and implications

2017

Abstract Aerosol optical properties were retrieved from two years' worth of Sunphotometer measurements at Urumqi, an urban station in western China. Distinct seasonal variations of aerosol optical properties were revealed. During the heating season, mean aerosol optical depth at 550 nm (τ a ), Angstrom exponent calculated from aerosol optical depth at wavelength of 440 and 870 nm (α) as well as PM 2.5 concentration were 0.58 ± 0.33, 1.11 ± 0.34 and 79.5 ± 69.6 μg m − 3 , respectively, which contrasted their counterparts during the non-heating season of 0.32 ± 0.22, 0.79 ± 0.26, and 35.0 ± 20.1 μg m − 3 . Seasonal variations of τ a and PM 2.5 at Urumqi contrasted with corresponding values in…

Aerosol influence on radiative cooling

2011

Aerosol particles have a complex index of refraction and therefore contribute to atmospheric emission and radiative cooling rates. In this paper calculations of the longwave flux divergence within the atmosphere at different heights are presented including water vapour and aerosol particles as emitters and absorbers. The spectral region covered is 5 to 100 microns divided into 23 spectral intervals. The relevant properties of the aerosol particles, the single scattering albedo and the extinction coefficient, were first calculated by Mie-theory and later by an approximation formula with a complex index of refraction given by Volz. The particle growth with relative humidity is also incorporat…

Consistency between GRUAN sondes, LBLRTM and IASI

2017

Abstract. Radiosonde soundings from the GCOS Reference Upper-Air Network (GRUAN) data record are shown to be consistent with Infrared Atmospheric Sounding Instrument (IASI)-measured radiances via LBLRTM (Line-By-Line Radiative Transfer Model) in the part of the spectrum that is mostly affected by water vapour absorption in the upper troposphere (from 700 hPa up). This result is key for climate data records, since GRUAN, IASI and LBLRTM constitute reference measurements or a reference radiative transfer model in each of their fields. This is specially the case for night-time radiosonde measurements. Although the sample size is small (16 cases), daytime GRUAN radiosonde measurements seem to h…