Search results for " Irradiation"

Assessment of contamination of Salmonella spp. in imported black pepper and sesame seed and salmonella inactivation by gamma irradiation

2021

This study shows the frequency of seeds samples contaminated by Salmonella spp. collected randomly from local markets; on 30 black pepper sample no contaminated sample was found while Salmonella spp. was detected in 3 of 36 (8.3%) analyzed sesame samples; three different serotypes were identified: S. Montevideo, S. Stanleyville e S. Tilene. The efficacy of gamma irradiation to inactivate Salmonella Montevideo in black pepper and sesame irradiated between 1 and 5 kGy was evaluated. 3 kGy is sufficient to reduce of 3-4 log CFU/g; whereas 5 kGy have been need to reduce 5.5-6 log CFU/g for samples of black pepper and sesame. No statistically significant differences were found between black pepp…

Non-conventional methods and media for the activation and manipulation of carbon nanoforms

2013

Very often, chemical transformations require tedious and long procedures, which, sometimes, can be avoided using alternative methods and media. New protocols, enabling us to save time and solvents, allow us also to explore new reaction profiles. This Tutorial Review focuses on the physical and chemical behavior of carbon nanoforms, CNFs (fullerenes, nanotubes, nanohorns, graphene, etc.) when non-conventional methods and techniques, such as microwave irradiation, mechano-chemistry or highly ionizing radiations are employed. In addition, the reactivity of CNFs in non-conventional media such as water, fluorinated solvents, supercritical fluids, or ionic liquids is also discussed.

Functional hydrogels containing polyaniline nanoparticles through e-beam irradiation

2009

Thermo-mechanical analysis of irradiation swelling and design optimization of the IFMIF target assembly with bayonet backplate

2017

Abstract The availability of a high flux neutron source for testing candidate materials under irradiation conditions, which will be typically encountered in future fusion power reactors (ITER, DEMO, FPR), is a fundamental step towards the development of fusion energy. To this purpose, the International Fusion Materials Irradiation Facility (IFMIF) represents the reference option to provide the fusion community with a DEMO-relevant neutron source capable of irradiating samples at a damage rate of up to 20 dpa/fpy (in steel) in a volume of 0.5 l. In the framework of the engineering design activities of IFMIF, ENEA is committed in the design of the lithium target assembly (TA) with removable (…

GaP/TiO2 Composite Photocatalyst for CO2 Reduction in Gas-Solid Regime under Simulated Solar Light Irradiation

2014

Photochemical genotoxicity: principles and test methods

2004

In recent years, assessing the photogenotoxic potential of a compound became an issue for certain drugs and cosmetical products. Therefore, existing methods performed according to international guidelines (e.g. OECD guidelines) were adapted to the use of concurrent UV-visible (UV-Vis) light irradiation for the assessment of photomutagenicity/photogenotoxicity. In this review, photobiological bases of the processes occurring in the cell after irradiation with UV- and/or visible (vis)-light as well as a compilation of testing methods is presented. Methods comprise cell free investigations on naked DNA and in vitro methods, such as the photo-Ames test, the photo-HPRT/photo-mouse lymphoma assay…

Photochemical sample treatment: a greener approach to chlorobenzene determination in sediments.

2014

Abstract Due to worker׳s exposure, solvent and stationary phases׳ consumption, sample purification is one of the most polluting steps in analytical procedures for determination of organic pollutants in real samples. The use of photochemical sample treatment represents a valid alternative methodology for extracts clean up allowing for a reduction of the used amount of organic solvents. In this paper we report the first application on the photolytic destruction of organic substances to eliminate some of the interferences in the analysis of Chlorobenzenes in sediment samples. The method׳s efficiency and robustness were compared with classic silica column purification process currently used in …

Boosting the methanolysis of polycarbonate by the synergy between ultrasound irradiation and task specific ionic liquids

2021

In an attempt to perform polycarbonate chemical recycling in a more sustainable way, we took into consideration the combined use of ultrasound irradiation and task specific ionic liquids. Towards this aim, the methanolysis of polycarbonate, into dimethylcarbonate and bisphenol A, was carried out in the presence of cholinium-based ionic liquids featuring anions derived from amino acids and other eco-friendly species. The target process was optimized in terms of both energy and material amounts as well as in terms of the nature of the catalysts used. The proposed protocol allowed high conversion and yields of bisphenol A to be obtained, under milder conditions compared to the ones so far repo…

Synthesis and characterization of CdS nanoparticles embedded in a polymethylmethacrylate matrix

2005

CdS nanopowder capped with sodium bis(2-ethylhexyl)sulfosuccinate was synthesized by using water-in-oil microemulsions. The CdS nanoparticles of about 5 nm obtained were embedded in polymethylmethacrylate matrix by a photocuring process. The transparent yellow solid compound was characterized by optical absorption and emission spectroscopy, high-resolution transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The properties of this compound were compared with those of the nanopowder dispersed in heptane and in methylmethacrylate. The results obtained indicate that the nanoparticles are homogeneously dispersed in the matrix and do not change in size during the embedding…

Proposal for SPS beam time for the baby MIND and TASD neutrino detector prototypes

2014

The design, construction and testing of neutrino detector prototypes at CERN are ongoing activities. This document reports on the design of solid state baby MIND and TASD detector prototypes and outlines requirements for a test beam at CERN to test these, tentatively planned on the H8 beamline in the North Area, which is equipped with a large aperture magnet. It is hoped that this will allow for the current proposal to be considered in light of the recently approved projects related to neutrino activities with the SPS in the North Area in the medium term 2015-2020. The design, construction and testing of neutrino detector prototypes at CERN are ongoing activities. This document reports on t…