Search results for " K"
showing 10 items of 22846 documents
Protonation of a Spherical Macrotricyclic Tetramine: Water Inclusion, Allosteric Effect, and Cooperativity
2017
The spherical macrotricyclic cryptand tetramine "C24" (1) displays remarkable protonation behaviour. It undergoes protonation in four successive steps for which pKa values of 11.17±0.05, 10.28±0.04, 6.00±0.06 and 3.08±0.08 have been determined at 298 K. The unusually close values for the first two protonations provide evidence for the encapsulation of a water molecule serving as effector for the second protonation, which is consistent with earlier observations that the exchange of protons bound in the diprotonated species with solvent protons is unusually slow and that 17 O NMR spectra show the presence of an oxygen centre in the same species quite distinct from that of solvent water. Encap…
Enantiomeric Resolution of Asymmetric-Carbon-Free Binuclear Double-Stranded Cobalt(III) Helicates and Their Application as Catalysts in Asymmetric Re…
2018
A series of double-stranded binuclear helicates [Co2(H1)2]4+, [Co2(H2)2]4+, and [Co2(H3)2]4+, derived from monodeprotonated bis-pyridyl hydrazine-based ligands of H21, H22, and H23 with one, two, and three -CH2 spacers, were obtained. These asymmetric-carbon-free racemic helicates were separated into their ΔΔ and ΛΛ enantiomers. The resolved helicates were examined for the first time as enantioselective catalysts in asymmetric benzoylation and nitroaldol reactions.
Joint interpretation of seismic refraction tomography and electrical resistivity tomography by cluster analysis to detect buried cavities
2020
Abstract In the last few years, the geophysical methods of seismic refraction tomography (SRT) and electrical resistivity tomography (ERT) are among the most used geophysical techniques for the reconstruction of subsoil geometries, for the investigation of underground cavities and also for the archaeological prospecting. However, the main disadvantage of each geophysical method is the difficulty of final interpretation of the data. In order to eliminate artifacts and generally improve the reliability and accuracy of geophysical interpretation, it is useful to perform a joint approach of different geophysical methods, also introducing the a priori information. In this work, it is shown the i…
Cosmic-Ray Anisotropies in Right Ascension Measured by the Pierre Auger Observatory
2020
We present measurements of the large-scale cosmic-ray anisotropies in right ascension, using data collected by the surface detector array of the Pierre Auger Observatory over more than 14 years. We determine the equatorial dipole component, ~d⊥, through a Fourier analysis in right ascension that includes weights for each event so as to account for the main detector-induced systematic effects. For the energies at which the trigger efficiency of the array is small, the “East-West” method is employed. Besides using the data from the array with detectors separated by 1500 m, we also include data from the smaller but denser sub-array of detectors with 750 m separation, which allows us to extend …
XMM-Newton observation of the supernova remnant Kes 78 (G32.8-0.1): Evidence for shock-cloud interaction
2017
The Galactic supernova remnant Kes 78 is surrounded by dense molecular clouds, whose projected position overlaps with the extended HESS gamma-ray source HESS J1852-000. The X-ray emission from the remnant has been recently revealed by Suzaku observations, which have shown indications for a hard X-ray component in the spectra, possibly associated with synchrotron radiation. We aim at describing the spatial distribution of the physical properties of the X-ray emitting plasma and at revealing the effects of the interaction of the remnant with the inhomogeneous ambient medium. We also aim at investigating the origin of the gamma-ray emission, which may be Inverse Compton radiation associated wi…
Turbulent jet through porous obstructions under Coriolis effect: an experimental investigation
2021
AbstractThe present study has the main purpose to experimentally investigate a turbulent momentum jet issued in a basin affected by rotation and in presence of porous obstructions. The experiments were carried out at the Coriolis Platform at LEGI Grenoble (FR). A large and unique set of velocity data was obtained by means of a Particle Image Velocimetry measurement technique while varying the rotation rate of the tank and the density of the canopy. The main differences in jet behavior in various flow configurations were assessed in terms of mean flow, turbulent kinetic energy and jet spreading. The jet trajectory was also detected. The results prove that obstructions with increasing density…
Supporting group decision makers to locate temporary relief distribution centres after sudden-onset disasters
2020
International audience; In the humanitarian response, multiple decision-makers (DMs) need to collaborate in various problems, such as locating temporary relief distribution centres (RDCs). Several studies have argued that maximising demand coverage, reducing logistics costs and minimising response time are among the critical objectives when locating RDCs after a sudden-onset disaster. However, these objectives are often conflicting and the trade-offs can considerably complicate the situation for finding a consensus.To address the challenge and support the DMs, we suggest investigating the stability of non-dominated alternatives derived from a multi-objective model based on Monte Carlo Simul…
The size, shape, density and ring of the dwarf planet Haumea from a stellar occultation
2017
Ortiz, José Luis et. al.
Astrometric detection of a low-mass companion orbiting the star AB Doradus
1997
International audience; We report submilliarcsecond-precise astrometric measurements for the late-type star AB Doradus via a combination of VLBI (very long baseline interferometry) and HIPPARCOS data. Our astrometric analysis results in the precise determination of the kinematics of this star, which reveals an orbital motion readily explained as caused by gravitational interaction with a low-mass companion. From the portion of the reÑex orbit covered by our data and using a revised mass of the primary star (0.76 M _) derived from our new value of the parallax (66.3 mas \ n \ 67.2 mas), we Ðnd the dynamical mass of the newly discovered companion to be between 0.08 and 0.11 If accurate photom…
Channel forms recovery in an ephemeral river after gravel mining (Palancia River, Eastern Spain)
2017
[EN] During the 1970s, the Palancia River was intensively affected by gravel mining instream. This activity completely destroyed the fluvial forms, devastating the original wandering pattern. At the end of the 1980s, gravel mining ceased and the river started a process of recovery, only altered by several clearing operations. The aim of this work is to describe these processes of change, analyzing the river's morphosedimentary conditions through a GIS analysis of aerial photographs previous to, simultaneous with, and subsequent to the intense gravel mining activity. Results explain the current difficulties of some ephemeral rivers to recover their original forms, because of the sediment and…