Search results for " Liquid crystals"

Efficient light-induced phase transitions in halogen-bonded liquid crystals

2016

Here, we present a new family of light-responsive, fluorinated supramolecular liquid crystals (LCs) showing efficient and reversible light-induced LC-to-isotropic phase transitions. Our materials design is based on fluorinated azobenzenes, where the fluorination serves to strengthen the noncovalent interaction with bond-accepting stilbazole molecules, and increase the lifetime of the cis-form of the azobenzene units. The halogen-bonded LCs were characterized by means of X-ray diffraction, hot-stage polarized optical microscopy, and differential scanning calorimetry. Simultaneous analysis of light-induced changes in birefringence, absorption, and optical scattering allowed us to estimate tha…

Le Tecnologie Fotovoltaiche

2011

SYNTHESIS OF OXADIAZOLE BASED ORGANIC SALTS

2010

A Thermochromic Liquid Crystals Image Analysis technique to investigate temperature polarization in spacer-filled channels for Membrane Distillation

2013

The analysis of flow fields and temperature distributions is of paramount importance in the development and optimization of new spacer-filled channel geometries for Membrane Distillation modules. The literature reports only few studies on the experimental characterization of such channels and, to the authors’ knowledge, none of them presents local information concerning the temperature distribution on the membrane surface. In the present work, a non-intrusive experimental technique named TLC-IA-TP is presented: it is based on the use of Thermochromic Liquid Crystals (TLCs) and digital Image Analysis (IA) and it is applied here for the first time to the analysis of Temperature Polarization (…

CFD Investigation of Spacer-Filled Channels for Membrane Distillation

2019

The membrane distillation (MD) process for water desalination is affected by temperature polarization, which reduces the driving force and the efficiency of the process. To counteract this phenomenon, spacer-filled channels are used, which enhance mixing and heat transfer but also cause higher pressure drops. Therefore, in the design of MD modules, the choice of the spacer is crucial for process efficiency. In the present work, different overlapped spacers are investigated by computational fluid dynamics (CFD) and results are compared with experiments carried out with thermochromic liquid crystals (TLC). Results are reported for different flow attack angles and for Reynolds numbers (Re) ran…

Experimental and computational investigation of heat transfer in channels filled by woven spacers

2017

Abstract Models of woven-type spacer-filled channels were investigated by Computational Fluid Dynamics (CFD) and parallel experiments in order to characterize the performance of Membrane Distillation (MD) modules. The case of overlapped spacers was analysed in a companion paper. Experiments were based on a non-intrusive technique using Thermochromic Liquid Crystals (TLC) and digital image processing, and provided the distribution of the local convective heat transfer coefficient on a thermally active wall. CFD simulations ranged from steady-state conditions to unsteady and early turbulent flow, covering a Reynolds number interval of great practical interest in real MD applications. A specif…

Investigation of heat transfer in spacer-filled channels by experiments and direct numerical simulations

2016

Abstract The analysis of flow fields and heat or mass transfer phenomena is of great importance in the optimum design of spacer-filled channel geometries for a variety of membrane-based processes. In the present work, models of spacer-filled channels often adopted in Membrane Distillation are simultaneously investigated by experiments and Computational Fluid Dynamics (CFD). Experiments rely on a non-intrusive technique, based on the use of Thermochromic Liquid Crystals (TLC) and digital image processing, and provide the local distribution of the convective heat transfer coefficient on a thermally active wall. CFD relies on steady-state (laminar flow) simulations in the lower end of the Reyn…

Performance comparison between overlapped and woven spacers for membrane distillation

2017

The sustainable production of freshwater from seawater desalination is receiving increasing attention. Recently, some desalination technologies are taking advantage from the coupling with renewable resources; among them, membrane distillation (MD) is one of the most promising since it can be easily powered by low-grade thermal energy. MD being an emerging technology, efforts are required to optimize geometry and operating conditions of real units in order to reduce the unitary freshwater production cost. In particular, temperature polarization is a well-known detrimental effect for the process driving force; spacers are traditionally used to enhance mixing and make temperature boundary laye…

Experimental Analysis via Thermochromic Liquid Crystals of the Temperature Local Distribution in Membrane Distillation Modules

2013

A reliable and optimized design of channels for Membrane Distillation (MD) requires knowledge of local temperature distributions within the module. This information is essential to measure the temperature polarization, choice the module configuration (net spacer features, channel size, etc) providing the best process performance. Notwithstanding such crucial aspects, only few studies have been devoted to the experimental characterization of MD channels and none of them includes data on the local temperature distribution. In the present work, an experimental technique based on the use of Thermochromic Liquid Crystals (TLCs) and digital image processing, previously proposed by the authors (Pi…

ortho -Fluorination of azophenols increases the mesophase stability of photoresponsive hydrogen-bonded liquid crystals

2018

Photoresponsive liquid crystals (LCs) whose alignment can be controlled with UV-Visible light are appealing for a range of photonic applications. From the perspective of exploring the interplay between the light response and the self-assembly of the molecular components, supramolecular liquid crystals are of particular interest. They allow elaborating the structure-property relationships that govern the optical performance of LC materials by subtle variation of the chemical structures of the building blocks. Herein we present a supramolecular system comprising azophenols and stilbazoles as hydrogen-bond donors and acceptors, respectively, and show that ortho-fluorination of the azophenol dr…