Search results for " Liquid"

showing 10 items of 3037 documents

Dominant contribution of P450 3A4 to the hepatic carcinogenic activation of aflatoxin B1.

2006

The hepatic carcinogen aflatoxin B1 (AFB1) is metabolized in the liver by at least four different P450s, all of which exhibit large interindividual differences in the expression levels. These differences could affect the individual risk of hepatocellular carcinoma (HCC). We investigated the metabolism of AFB1 in a panel of 13 human liver microsomal preparations using a hepatic abundance model, which takes into account the specific kinetic parameters and the expression levels of these P450s. We found a 12-fold variability in the production rate of the carcinogenic metabolite AFB1-8,9-epoxide (AFBO) and a 22-fold variability in the production of the detoxification product AFQ1. The ratio betw…

AflatoxinAflatoxin B1MetabolitePharmacologyToxicology03 medical and health scienceschemistry.chemical_compound0302 clinical medicineCytochrome P-450 Enzyme SystemmedicineCytochrome P-450 CYP3AHumansCarcinogenBiotransformationChromatography High Pressure Liquid030304 developmental biologychemistry.chemical_classification0303 health sciencesPrimary metaboliteGeneral MedicineMetabolismmedicine.diseaseEnzymeBiochemistrychemistryLiver030220 oncology & carcinogenesisHepatocellular carcinomaMicrosomeCarcinogensChemical research in toxicology
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Occurrence of Aflatoxins in Tigernuts and Their Beverages Commercialized in Spain

2010

A method based on matrix solid phase dispersion extraction was applied to determine aflatoxins B(1), B(2), G(1), and G(2) from tigernuts and tigernut beverages. Recoveries of each aflatoxin from tigernut (spiked at 10 microg/kg level) and from tigernut beverages (spiked at 10 microg/L level) ranged from 72.3 to 82.1% and from 74.0 to 86.3%, respectively. The limits of quantification ranged from 0.21 to 1.49 microg/kg (for tigernuts) and from 0.13 to 0.57 microg/L (for tigernut beverages) studied using liquid chromatography with fluorescence detection. The proposed extraction method followed by liquid chromatography-fluorescence detection determination was applied to 37 and 25 samples of tig…

AflatoxinChromatographyRoot cropsExtraction (chemistry)Reproducibility of ResultsGeneral ChemistrySensitivity and SpecificityBeveragesMatrix (chemical analysis)chemistry.chemical_compoundSpectrometry FluorescenceAflatoxinschemistrySpainSolventsNutsUltrasonicsExtraction methodsFood scienceGeneral Agricultural and Biological SciencesMycotoxinControl methodsChromatography LiquidFood contaminantJournal of Agricultural and Food Chemistry
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Determination of aflatoxins in peanuts by matrix solid-phase dispersion and liquid chromatography

2003

A new method based on matrix solid-phase dispersion (MSPD) extraction was studied to determine aflatoxin B1, B2, G1 and G2 from peanuts. Optimization of different parameters, such as type of solid supports for matrix dispersion and elution solvents were carried out. The method used 2 g of peanut sample, 2 g of C18 bonded silica as MSPD sorbent and acetonitrile as eluting solvent. Recoveries of each aflatoxin spiked to peanut samples at 2.5 ng/g (5 ng/g for aflatoxin G2) level were between 78 and 86% with relative standard deviations ranging from 4 to 7%. The limits of quantification ranged from 0.125 to 2.5 ng/g for the four studied aflatoxins using liquid chromatography (LC) with fluoresce…

AflatoxinElectrosprayChromatographyArachisElutionChemistryOrganic ChemistryExtraction (chemistry)Enzyme-Linked Immunosorbent AssayGeneral MedicineSensitivity and SpecificityBiochemistryHigh-performance liquid chromatographyAnalytical ChemistryMatrix (chemical analysis)Spectrometry FluorescenceAflatoxinsSample preparationSolid phase extractionChromatography LiquidJournal of Chromatography A
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Limited survey for the presence of aflatoxins in foods from local markets and supermarkets in Valencia, Spain.

2004

Aflatoxin B1 (AFB1), B2 (AFB2), G1 (AFG1) and G2 (AFG2) were extracted by matrix solid-phase dispersion with C18 silica and acetonitrile as the eluting solvent, analysed by liquid chromatography with fluorescence detection and confirmed by liquid chromatography with mass spectrometry using an electrospray interface in 58 samples grouped as cereals, dried fruits, herbs and spices, pulses, snacks, and nuts and nut products collected from local markets and supermarkets in Valencia, Spain. All samples analysed by the proposed method were previously studied with an enzyme-linked immunosorbent assay as a screening protocol for the fast detection of mycotoxins. The samples containing residues (3/5…

AflatoxinElectrosprayDried fruitHealth Toxicology and MutagenesisEnzyme-Linked Immunosorbent AssayFood ContaminationToxicologyMass spectrometryMatrix (chemical analysis)chemistry.chemical_compoundAflatoxinsmedia_common.cataloged_instanceHumansNutsEuropean unionMycotoxinChromatography High Pressure Liquidmedia_commonResidue (complex analysis)ChromatographyChemistryPublic Health Environmental and Occupational Healthfood and beveragesGeneral ChemistryFood InspectionChemistry (miscellaneous)SpainFood AnalysisFood ScienceFood additives and contaminants
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Presence of aflatoxin M1 in pasteurized milk from Morocco

2007

Fifty four samples of pasteurized milk produced by five different dairies from Morocco were surveyed for the presence of aflatoxin M1 (AFM1) using immunoaffinity columns and liquid chromatography coupled to fluorescence detection. Confirmation of AFM1 identity in positive samples was based on the formation of AFM1 hemi-acetal derivative (AFM2a) after derivatization with trifluoracetic acid. Analytical results showed that 88.8% of the samples were contaminated with AFM1; 7.4% being above the maximum level of 0.05 microg/L set by the Moroccan and European regulations for AFM1 in liquid milk. The incidence of AFM1 in milk from these dairies was 100, 92.3, 90, 83.3 and 77.7% respectively, with …

AflatoxinFood HandlingDaily intakePasteurizationFood ContaminationMicrobiologyPoisonslaw.inventionchemistry.chemical_compoundlawFood PreservationAnimalsHumansFood scienceMycotoxinDerivatizationMaximum levelFood preservationLiquid milkGeneral MedicineMoroccoMilkchemistryConsumer Product SafetyAflatoxin M1Food AnalysisChromatography LiquidFood ScienceInternational Journal of Food Microbiology
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High Pressure Processing Impact on Alternariol and Aflatoxins of Grape Juice and Fruit Juice-Milk Based Beverages.

2021

High-pressure processing (HPP) has emerged over the last 2 decades as a good alternative to traditional thermal treatment for food safety and shelf-life extension, supplying foods with similar characteristics to those of fresh products. Currently, HPP has also been proposed as a useful tool to reduce food contaminants, such as pesticides and mycotoxins. The aim of the present study is to explore the effect of HPP technology at 600 MPa during 5 min at room temperature on alternariol (AOH) and aflatoxin B1 (AFB1) mycotoxins reduction in different juice models. The effect of HPP has also been compared with a thermal treatment performed at 90 °C during 21 s. For this, different juice models, or…

AflatoxinFood industryFood HandlingLiquid Phase MicroextractionAlternariolPharmaceutical ScienceOrganic chemistryFood Contamination01 natural sciencesArticlealternariolAnalytical ChemistryPascalizationBeverageschemistry.chemical_compoundLactones0404 agricultural biotechnologyQD241-441AflatoxinsTandem Mass Spectrometryjuice modelsDrug Discoverydispersive liquid–liquid microextractionAnimalsVitisFood sciencePhysical and Theoretical ChemistryMycotoxinChromatography High Pressure LiquidOrange juicehigh-pressure processingbusiness.industry010401 analytical chemistry04 agricultural and veterinary sciencesMycotoxinsFood safety040401 food science0104 chemical sciencesFruit and Vegetable JuicesMilkchemistryChemistry (miscellaneous)Fruitaflatoxin B1Molecular Medicinebusinessliquid chromatography coupled to tandem mass spectrometryFood contaminantMolecules (Basel, Switzerland)
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Limited survey for the occurrence of aflatoxins in cereals and poultry feeds from Rabat, Morocco

2007

Fifty eight (58) samples of cereals for human consumption (20 corn flour, 17 wheat flour) and poultry feeds (n=21) purchased from popular markets of Rabat in Morocco were analyzed for aflatoxins (AF) by HPLC with immunoaffinity column (IAC) clean-up and fluorimetric detection. The incidence of AF in corn, wheat flour and poultry feeds was about 80, 17.6 and 66.6% respectively. High contamination levels were found in corn and poultry feeds samples. Levels of contamination of analyzed samples with AFB1 ranged from 0.23 to 11.2, 0.03 to 0.15 and 0.05 to 5.38 ng/g for corn, wheat and poultry feeds respectively. Results showed also that the contamination of 10% of samples of corn was higher than…

AflatoxinWheat flourFood ContaminationBiologyZea maysMicrobiologyToxicologychemistry.chemical_compoundAflatoxinsCorn flourAnimalsFood scienceMycotoxinChromatography High Pressure LiquidPoultry DiseasesTriticumIncidencefood and beveragesGeneral MedicineContaminationAnimal FeedMoroccochemistryEdible GrainChickensFood ScienceInternational Journal of Food Microbiology
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MYCOTOXINS | Detection and Analysis by Classical Techniques

2014

This article is a revision of the previous edition article by Imad Ali Ahmed, volume 2, pp. 1526–1532, © 1999, Elsevier Ltd.

Aflatoxinchemistry.chemical_compoundChromatographychemistryVolume (thermodynamics)Liquid–liquid extractionAnalytical chemistrySample preparationGas chromatographyHigh-performance liquid chromatographyOchratoxinThin-layer chromatography
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Atrial Fibrillation Is Associated with a Marker of Endothelial Function and Oxidative Stress in Patients with Acute Myocardial Infarction

2015

International audience; Background Atrial fibrillation (AF), whether silent or symptomatic, is a frequent and severe complication of acute myocardial infarction (AMI). Asymmetric dimethylarginine (ADMA), an endogenous eNOS inhibitor, is a risk factor for endothelial dysfunction. We addressed the relationship between ADMA plasma levels and AF occurrence in AMI.Methods 273 patients hospitalized for AMI were included. Continuous electrocardiographic monitoring (CEM) !48 hours was recorded and ADMA was measured by High Performance Liquid Chromatography on admission blood sample.Results The incidence of silent and symptomatic AF was 39(14%) and 29 (11%), respectively. AF patients were markedly o…

Aged 80 and overMalelcsh:RMyocardial Infarctionlcsh:MedicineMiddle AgedArginineRisk Assessment[SDV.MHEP.CSC] Life Sciences [q-bio]/Human health and pathology/Cardiology and cardiovascular systemElectrocardiographyOxidative StressLogistic Models[SDV.MHEP.CSC]Life Sciences [q-bio]/Human health and pathology/Cardiology and cardiovascular systemRisk FactorsAtrial FibrillationMultivariate AnalysisHumansFemalelcsh:QEndotheliumlcsh:ScienceBiomarkersChromatography High Pressure LiquidResearch ArticleAged
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La créance de restitution d'une subvention de l'ANAH a pour fait générateur la décision de retrait prise par l'ANAH

2003

International audience; (Com. 13 mai 2003, pourvoi n° F 99-16.156, arrêt n° 787 FS-P, J.-L. Brenac c/ Agence nationale pour l'amélioration de l'habitat)

Agence pour l'amélioration de l'habitat[SHS.DROIT]Humanities and Social Sciences/LawPoursuite de l'activité[SHS.DROIT] Humanities and Social Sciences/LawREDRESSEMENT ET LIQUIDATION JUDICIAIRESPériode d'observationCréance prioritaire
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