Search results for " Lithium"

The conductance of lithium-7 fluoride in dioxane-water mixtures at 25�C

1990

Conductance data for lithium-7 fluoride in dioxane-water mixtures covering the range 78.35>D>36 in dielectric constant are presented. These data and other previous data on lithium-7 chloride and lithium-7 iodide were analyzed by the Fuoss 1980 conductance equation in order to find the limiting conductance Δo, the pairing distance R and the conductometric association constant Kλ. Setting Ka=Kλ/VM (where VM is the molar volume of the solvent), the thermodynamic pairing constant and the corresponding change of the free energy Δg were calculated. Correlation among the values found for R and Δg=Δh−TΔs and the properties characteristic of the ions and solvents are discussed.

On the thermo-mechanical behaviour of DEMO water-cooled lithium lead equatorial outboard blanket module

2017

Abstract Within the framework of EUROfusion R&D activities an intense research campaign has been carried out at the University of Palermo, in close cooperation with ENEA Brasimone, in order to investigate the thermo-mechanical performances of the DEMO water-cooled lithium lead breeding blanket (WCLL). In particular, attention has been paid to the most recent geometric configuration of the DEMO WCLL outboard equatorial module, as designed by WCLL project team during 2015, endowed with an attachment system based on the use of radial pins, purposely outlined to connect the module back-plate to its back-supporting structure, that have been properly considered to simulate more realistically the …

MHD Free Convection in Helium-Cooled Lithium-Lead Blanket Modules for the Demonstration Fusion Reactor

2003

Calculation of size‐intensive transition moments from the coupled cluster singles and doubles linear response function

1994

Coupled cluster singles and doubles linear response (CCLR) calculations have been carried out for excitation energies and dipole transition strengths for the lowest excitations in LiH, CH+, and C4and the results compared with the results from a CI-like approach to equation of motion coupled cluster (EOMCC). The transition strengths are similar in the two approaches for single molecule calculations on small systems. However, the CCLR approach gives size-intensive dipole transition strengths, while title EOMCC formalism does not. Thus, EOMCC calculations can give unphysically dipole transition strengths, e.g., in EOMCC calculations on a sequence of noninteracting LiH systems we obtained a neg…

Sintesi per via elettrochimica di nanowires di leghe Co-Sn

2008

An Innovative Conversion Device to the Grid Interface of Combined RES-Based Generators and Electric Storage Systems

2015

This paper is focused on the development of an innovative device, which is based on a bidirectional converter, for the interface to the supply utility grid of combined renewable-energy-source-based generators and electric storage systems. The device can be controlled so as to ease the interface between the low-voltage grid and photovoltaic or wind generators combined with lithium-ion $\hbox{LiFePO}_{4} $ batteries, taking into account the requirements of the reference technical standards for users connection and offering different ancillary services. The operational functioning of the device, the architecture, and its electronic components, as well as laboratory and field test activities an…

Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations

2022

Abstract The Ordovician (∼487 to 443 Ma) ended with the formation of extensive Southern Hemisphere ice sheets, known as the Hirnantian glaciation, and the second largest mass extinction in Earth History. It was followed by the Silurian (∼443 to 419 Ma), one of the most climatically unstable periods of the Phanerozoic as evidenced by several large scale ( > 5 ‰ ) carbon isotope (δ13C) perturbations associated with further extinction events. Despite several decades of research, the cause of these environmental instabilities remains enigmatic. Here, we provide osmium (187Os/188Os) and lithium (δ7Li) isotope measurements of marine sedimentary rocks that cover four Silurian δ13C excursions. Osmi…

Spatial Simultons in 2D Photonic Crystals of Nonlinear Origin

2007

We observed for the very first time quadratic spatial solitons (simultons) in a two dimensional photonic lattice defined by periodic sign inversion of its susceptibilty. This is the first demonstration of quadratic self-confinement in a 2D purely nonlinear photonic crystal.

First-Order Quasi-Phase-Matched Blue Light Generation in Surface-Poled Ti:Indiffused waveguide

2004

The application of surface periodic poling method for first order quasi-phase-matched (QPM) second harmonic generation (SHG) in Ti:indiffused lithium niobate channel waveguides, was investigated. On a 2.5 μm wide channel waveguide which was periodically poled with a period of 2.47 μm for TM waveguide mode interaction, efficient SHG was observed. The CCD camera was used for monitoring the near-field waveguide mode profiles of both the fundamental and second harmonic waves. The potential of surface domain inversion for efficient nonlinear waveguide interactions was shown after the production of 6 mW of continous-wave blue radiation.

A field induced ferromagnetic-like transition below 2.8 K in Li2CuO2: An experimental and theoretical study

1998

The low temperature magnetic properties of the Li2CuO2 compound have been investigated by means of superconducting quantum interference device magnetometry. We find in addition to an antiferromagnetic phase below 9.5 K a ferromagnetic-like steep rise of the magnetization around 2.8 K. The observed low temperature behavior is discussed by considering second and fourth order magnetocrystalline effective anisotropy coefficients, in addition to the exchange couplings reported in the literature. Work at the Institut de Ciencia dels Materials was supported by the Spanish Comisión Interministerial de Ciencia y Technología Grant No. CICYT MAT 96-1037.