Search results for " Magne"
showing 10 items of 8203 documents
Zn-substituted iron oxide nanoparticles from thermal decomposition and their thermally treated derivatives for magnetic solid-phase extraction
2020
Abstract Controlled thermal decomposition of zinc and iron acetylacetonates in the presence of oleic acid and oleylamine provided surfactant-capped magnetic nanoparticles with narrow size distribution and the mean diameter of ≈15 nm. The combined study by XRD, XRF and Mossbauer spectroscopy revealed three important features of the as-prepared nanoparticles. First, the actual ratio of Zn:Fe was considerably lower in the product compared to the initial ratio of metal precursors (0.14 vs. 0.50). Second, a pure stoichiometric Zn-doped magnetite system, specifically of the composition Zn0.37Fe2.63O4, with no signatures of oxidation to maghemite was formed. Third, Zn2+ ions were distributed at bo…
Mechanical properties of macroscopic magnetocrystals
2019
Abstract We studied experimentally and by numerical simulations the mechanical response of arrays of macroscopic magnetic spheres when an external stress is applied. First, the tensile strength of single chains and ribbons was analyzed. Then, simple cubic (cP), hexagonal (Hx) and hybrid (cP-Hx) structures, called here magnetocrystals , were assembled and subjected to tensile stress, bending stress and torsion until failure was reached. Atomistic crystalline structures are isotropic, but in the case of magnetocrystals, even when geometric isotropy is obeyed, dipolar magnetic interactions introduce a physical anisotropy which modifies, in a non-usual manner, the structures response to the kin…
Neutron diffraction study of microstructural and magnetic effects in fine particle NiO powders
2016
Nickel oxide powders with grain sizes ranging from 100 to 1500 nm have been studied by high-resolution neutron diffraction. We have found that the atomic structure, the antiferromagnetic ordering, and the value of the nickel magnetic moments inherent in the bulk material of NiO are still preserved and are nearly independent of the average size of the grains. The sizes of the coherently scattering atomic and magnetic domains were estimated independently owing to a complete separation of the nuclear and magnetic peaks in the neutron diffraction patterns. It is shown that the finite-size and surface disorder effects in particles at the submicron scale have a more pronounced influence on the ma…
Investigation of mechanical and electrical properties of Li doped sodium niobate ceramic system
2016
ABSTRACTThe Na0.96Li0.04NbO3 ceramic solid solution was prepared by means of a two-stage hot-pressing technology. The X-ray diffraction analysis showed the formation of a single perovskite phase with an orthorhombic symmetry in the investigated composition. The microstructure and EDS measurements were performed. They confirmed the high purity and the expected qualitative composition. A good homogeneity of the microstructures and a small degree of porosity were observed. The elastic modulus (the Young's modulus E, shear modulus G, and Poisson's ratio ν) of Na0.96Li0.04NbO3 were determined with the use of an ultrasonic method. The electrical properties of Na0.96Li0.04NbO3 ceramics were invest…
Molecular dynamics simulations of nanometric metallic multilayers: Reactivity of the Ni-Al system
2011
The reactivity of a layered Ni-Al-Ni system is studied by means of molecular dynamics simulations, using an embedded-atom method type potential. The system, made of an fcc-Al layer embedded in fcc-Ni, is initially thermalized at the fixed temperature of 600 K. The early interdiffusion of Ni and Al at interfaces is followed by the massive diffusion of Ni in the Al layer and by the spontaneous phase formation of $B2$-NiAl. The solid-state reaction is associated with a rapid system heating, which further enhances the diffusion processes. For longer times, the system may partly lose some its $B2$-NiAl microstructure in favor of the formation of $L{1}_{2}$-${\mathrm{Ni}}_{3}\mathrm{Al}$. This st…
Time-resolved pulsed OSL of ceramic YAP:Mn phosphors
2019
The paper deals with the results of comparative study on time-resolved pulsed optically stimulated luminescence (TR-OSL) response of ceramic YAP:Mn materials prepared by different methods. In parti...
Static and dynamic structure of $ZnWO_4$ nanoparticles
2011
Abstract Static and dynamic structure of ZnWO 4 nanoparticles, synthesized by co-precipitation technique, has been studied by temperature dependent x-ray absorption spectroscopy at the Zn K-edge and W L 3 -edge. Complementary experimental techniques, such as x-ray powder diffraction, Raman and photoluminescence spectroscopies, have been used to understand the variation of vibrational, optical, and structural properties of nanoparticles, compared to microcrystalline ZnWO 4 . Our results indicate that the structure of nanoparticles experiences strong relaxation leading to the significant distortions of the WO 6 and ZnO 6 octahedra, being responsible for the changes in optical and vibrational …
Comparing the luminescence processes of YVO4:Eu and core-shell YVO4@YF3 nanocrystals with bulk-YVO4:Eu
2017
Abstract Comparative analysis of bulk, non-coated and core-shelled nanocrystalline YVO4:Eu was performed by means of time-resolved luminescence and VUV excitation luminescence spectroscopy techniques. Nanocrystalline YVO4:Eu samples – both as-prepared and YF3 core-shelled – have been synthesized by means of a microwave-assisted synthesis in ionic liquids, which allows to obtain 10–12 nm nanoparticles with high crystallinity. The results show noticeable differences between bulk and nanocrystalline YVO4:Eu in photoluminescence experimental data, which explains by influence of the nanocrystal surface. A YF3 core-shell layer around YVO4:Eu nanoparticles partially recovers the intensity of the E…
Rhodamine (B) photocatalysis under solar light on high crystalline ZnO films grown by home-made DC sputtering
2018
Abstract ZnO thin films were deposited by home-made DC sputtering of zinc target under mixed gases (Argon, Oxygen) plasma on glass substrates. Films were deposited by varying oxygen partial pressure (PO2) from 0.09 to 1.3 mbar in the deposition chamber, at a fixed substrate temperature of 100 °C. The samples were characterized by photoluminescence (PL), X-ray diffraction (XRD), optical transmissions (UV–vis), scanning electron microscopy (SEM) and electrical (Hall effect) measurements. The results indicate that by varying the oxygen pressure in the deposition chamber, the films show a precise and well defined photoluminescence emissions for each range of pressure covering almost the entire …
Enhancing domain wall velocity through interface intermixing in W-CoFeB-MgO films with perpendicular anisotropy
2019
We study the influence of He+ irradiation induced interface intermixing on magnetic domain wall (DW) dynamics in W-CoFeB (0.6 nm)-MgO ultrathin films, which exhibit high perpendicular magnetic anisotropy and large Dzyaloshinskii-Moriya interaction (DMI) values. Whereas the pristine films exhibit strong DW pinning, we observe a large increase in the DW velocity in the creep regime upon He+ irradiation, which is attributed to the reduction of pinning centers induced by interface intermixing. Asymmetric in-plane field-driven domain expansion experiments show that the DMI value is slightly reduced upon irradiation, and a direct relationship between DMI and interface anisotropy is demonstrated. …