Search results for " Magnetic materials"
showing 10 items of 4666 documents
Electrochemical polymerization of ambipolar carbonyl-functionalized indenofluorene with memristive properties
2019
Abstract Carbonyl-functionalized indenofluorene was electropolymerized with a high faradaic efficiency of 85% and the solid state properties of the resulting polymeric thin films were investigated. They displayed modular optical properties depending on their oxidation state. The approach used for inorganic semiconductors was applied to polyindeonofluorene derivative. Mott-Schottky analysis evidenced a switching from p-type to n-type electrical conduction, suggesting an ambipolar behaviour of the polymer. As an application, flexible organic memristors were fabricated and resistive switching properties were observed.
Modelling chemical composition in electric systems - implications to the dynamics of dye-sensitised solar cells
2010
International audience; Classical electromagnetism provides limited means to model electric generators. To extend the classical theory in this respect, additional information on microscopic processes is required. In semiconductor devices and electrochemical generators such information may be obtained by modelling chemical composition. Here we use this approach for the modelling of dye-sensitised solar cells. We simulate the steady-state current-voltage characteristics of such a cell, as well as its transient response. Dynamic simulations show optoelectronic hysteresis in these cells under transient light pulse illumination.
Vibronic Model for Intercommunication of Localized Spins via Itinerant Electron
2019
In this article, we propose a vibronic pseudo Jahn–Teller model for partially delocalized mixed-valence molecules aimed to describe the magnetic coupling between the localized spins mediated by the delocalized electron. The simplest partially delocalized system that retains the main studied features is assumed to consist of a one-electron mixed-valence dimer, which is connected to the two terminal magnetic ions. The model involves the following key interactions: electron transfer in the spin-delocalized subsystem of a mixed-valence molecule, which is mimicked by a dimeric unit, coupling of the itinerant electrons with the molecular vibrations, and isotropic magnetic exchange between the loc…
Electron Spin Resonance study of charge trapping in α-ZnMoO4 single crystal scintillator
2015
The origin and properties of electron and hole traps simultaneously appearing in a-ZnMoO4 scintillator after X-ray irradiation at low temperatures (T < 35 K) were studied by Electron Spin Resonance (ESR). ESR spectrum of the electron type trap shows pronounced superhyperfine structure due to the interaction of electron spin with nuclear magnetic moments of 95,97Mo and 67Zn lattice nuclei. Considering the nearly tetragonal symmetry of the center this allows us to identify the electron trap as an electron self-trapped at the (Mo(1)O4) 2 complex. Nearly 60% reduction of the spin–orbit coupling at the Mo(1) ion is caused by the overlap of the Mo and ligand oxygen orbitals indicating an essentia…
Impact of accumulated dust particles' charge on the photovoltaic module performance
2016
Abstract This work is focused on analysing effect of accumulated dust particles' charge on PV module performance. In the Dundee University's laboratory, dust particles have been created through epoxy powder and charged by using corona and tribo-electric charging methods by varying the charge levels of the accumulated dust particles. The PV module output has analysed for finding a relation between charge levels of the accumulated dust particles and its output voltage. Obtained experimental results have shown that charge level of accumulated dust particles on PV module's have significant impact on its output and dust particle accumulations are not associated with panel tilt angle.
Definition of the thermographic regions of interest in cycling by using a factor analysis
2016
Abstract Research in exercise physiology using infrared thermography has increased in the last years. However, the definition of the Regions of Interest (ROIs) varies strongly between studies. Therefore, the aim of this study was to use a factor analysis approach to define highly correlated groups of thermographic ROIs during a cycling test. Factor analyses were performed based on the moment of measurement and on the variation of skin temperatures as a result of the cycling exercise. 19 male participants cycled during 45 min at 50% of their individual peak power output with a cadence of 90 rpm. Infrared thermography was used to measure skin temperatures in sixteen ROIs of the trunk and lowe…
Three-Dimensional Integral-Imaging Display From Calibrated and Depth-Hole Filtered Kinect Information
2016
We exploit the Kinect capacity of picking up a dense depth map, to display static three-dimensional (3D) images with full parallax. This is done by using the IR and RGB camera of the Kinect. From the depth map and RGB information, we are able to obtain an integral image after projecting the information through a virtual pinhole array. The integral image is displayed on our integral-imaging monitor, which provides the observer with horizontal and vertical perspectives of big 3D scenes. But, due to the Kinect depth-acquisition procedure, many depthless regions appear in the captured depth map. These holes spread to the generated integral image, reducing its quality. To solve this drawback we …
Using infrared thermography in order to compare laser and hybrid (laser plus MIG) welding processes
2009
International audience; In order to deepen the understanding of the differences between laser and laser-arc hybrid welding, comparisons were undertaken using thermography. The experiments were carried out for a T assembly of aluminium alloy plates. Modelling, based on the finite element method approach, was realized using IR temperature measurements and seam geometry. For a value of the power supply, depicted as a surface source in the hybrid case, agreement was found between simulated and measured temperatures. The arc power supply efficiency value is similar to the usually used value.
The use of exploratory experimental designs combined with thermal numerical modelling to obtain a predictive tool for hybrid laser/MIG welding and co…
2011
Abstract While hybrid laser welding and coating processes involve a large number of physical phenomena, it is currently impossible to predict, for a given set of influencing factors, the shape of the molten zone and the history of temperature fields inside the parts. This remains true for complex processes, such as the hybrid laser/MIG welding process, which consists in combining a laser beam with a MIG torch. The gains obtained result essentially from the synergy of the associated processes: the stability of the process, the quality of the seam realized, and the productivity are increased. This article shows how, by means of a reduced number of experiments (8), it is possible to predict th…
The numerical simulation of heat transfer during a hybrid laser–MIG welding using equivalent heat source approach
2014
International audience; The present study is dedicated to the numerical simulation of an industrial case of hybrid laser-MIG welding of high thickness duplex steel UR2507Cu with Y-shaped chamfer geometry. It consists in simulation of heat transfer phenomena using heat equivalent source approach and implementing in finite element software COMSOL Multiphysics. A numerical exploratory designs method is used to identify the heat sources parameters in order to obtain a minimal required difference between the numerical results and the experiment which are the shape of the welded zone and the temperature evolution in different locations. The obtained results were found in good correspondence with …