Search results for " Magnetic materials"
showing 10 items of 4666 documents
Amorphous polyphosphate nanoparticles: application of the morphogenetically active inorganic polymer for personalized tissue regeneration
2019
Effects of VTE Treatment on Composition of Lithium Tantalate Single Crystals
2011
The vapour transport equilibration (VTE) is used to change the Li/Ta ratio in lithium tantalate single crystals of different crystallographic orientations (Z-cut and Y/128°-cut). Treatment by VTE is shown to provide thin layers in lithium tantalate plates composition of which is close to stoichiometric while the values of the coercive field are different, much smaller compared with congruent single crystals. There are several mechanisms of diffusion of the Li+ ions in LiTaO3 under conditions of VTE the contribution of each being dependent on the crystallographic orientation of the sample.
The Effects of Admixtures on Resistance to Radiation of Lithium Niobate Crystals
2015
The studies of optical absorption and transmission of crystalline lithium niobate compounds modified by rare-earth and alkali-earth elements: LiNbO3: Y (0.46 wt %), LiNbO3: Y (0.32 wt %), Mg (0.24 wt %), LiNbO3: Mg (0.27 wt %), LiNbO3: Gd (0.004, 0.04, 0.26, and 0.43 wt %), and ostensibly pure LiNbO3 is reported. The features of absorption and transmission are examined with respect to the dosage of γ-irradiation, the annealing temperature, and the type and concentration of modifying admixtures. The features revealed in different ways of bleaching γ-irradiated and annealed in vacuum ostensibly pure lithium niobate crystals are used to refine the mechanisms of developing electron and point de…
Process Development for Wet-Chemical Surface Functionalization of Gallium Arsenide Based Nanowires
2019
On lead-scandium tantalate solid solutions with high electrocaloric effect
1992
Abstract The PbSc0,5Ta0,5O3 solutions are found to be a useful material for active elements of microcryogenic devices based on electrocaloric effect. A temperature difference of ΔT = 1. 0-1.8 K at field intensities 20–30 kV/cm in the interval of 210–310 K can be achieved by simultaneous or separate introducing of Sb and Co ions in B-sites of the lattice. The most important contribution to the electrocaloric effect is due to field-induced Fn3m → R3m phase transition in the case of high ordering of B-ions in the perovskite structure ABO3.
Synthesis of chemisorbed imidazolium and phosphonium cations by reaction of ionic liquid precursors with silica.
2010
The reaction of four different basic ionic liquid precursors with Aerosil®300 is presented. Chemisorbed imidazolium and phosphonium cations, with silanolate anions as part of the silicatic support, were obtained and investigated with various solid state NMR techniques.
Recognition and sensing of fluoride anion.
2009
Fluoride anion recognition is attracting a mounting interest in the scientific community due to its duplicitous nature. It is a useful chemical for many industrial applications, and it has been used in human diet, but, recently it has been accused for several human pathologies. Here we describe the ample panorama of different approaches the chemists world-wide have employed to face the challenge of fluoride binding, and we outline some of the research which in our view can contribute to the development of this field, especially when fluoride binding has to be achieved in highly competitive protic solvents and water.
An efficient synthesis of new fluorinated uracil derivativesElectronic supplementary information (ESI) available: general procedures for the preparat…
2003
A series of potentially biologically active fluorinated uracil derivatives has been prepared in three steps from oxazolines and fluorinated nitriles with good chemical yields.
Uranium( iv ) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding
2019
The 1 : 1 reactions of uranium(IV) tetrakis(borohydride) with the sodium and potassium salts of the cyclobutadienyl anion [C4(SiMe3)4]2− (Cb′′′′) produce the half-sandwich complexes [Na(12-crown-4)2][U(η4-Cb′′′′)(BH4)3] and [U(η4-Cb′′′′)(μ-BH4)3{K(THF)2}]2. In the 1 : 2 reaction of U(BH4)4 with Na2Cb′′′′, formation of [U(η4-Cb′′′′)(η3-C4H(SiMe3)3-κ-(CH2SiMe2)(BH4))]− reveals that a Cb′′′′ ligand undergoes an intramolecular deprotonation, resulting in an allyl/tuck-in bonding mode. A computational study reveals that the uranium–Cb′′′′ bonding has an appreciable covalent component with contributions from the uranium 5f and 6d orbitals. peerReviewed
Non-covalent graphene nanobuds from mono- and tripodal binding motifs.
2017
Graphene nanobuds were prepared via the non-covalent anchoring of C60-based molecules endowed with one or three pyrene units, respectively. TGA, FTIR, UV-Vis and TEM investigations confirmed the formation of nanohybrids. For the two molecular derivatives, striking differences were determined in their interaction with graphene or carbon surfaces by Raman, cyclic voltammetry and molecular mechanics calculations, revealing the important role of pyrene adsorption in modulating the electronic properties of the nanohybrids.