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RESEARCH PRODUCT
Non-covalent graphene nanobuds from mono- and tripodal binding motifs.
Laura Rodríguez-pérezJoaquín CalboMarina GarridoEnrique OrtíNazario MartínNazario MartínJuan AragóMa ÁNgeles Herranzsubject
chemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesCatalysislaw.inventionsymbols.namesakechemistry.chemical_compoundAdsorptionlawMaterials ChemistryOrganic chemistryMoleculeFourier transform infrared spectroscopyGrapheneMetals and Alloystechnology industry and agricultureQuímica orgánicaGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciences3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryCeramics and CompositessymbolsPyreneCyclic voltammetry0210 nano-technologyRaman spectroscopyCarbondescription
Graphene nanobuds were prepared via the non-covalent anchoring of C60-based molecules endowed with one or three pyrene units, respectively. TGA, FTIR, UV-Vis and TEM investigations confirmed the formation of nanohybrids. For the two molecular derivatives, striking differences were determined in their interaction with graphene or carbon surfaces by Raman, cyclic voltammetry and molecular mechanics calculations, revealing the important role of pyrene adsorption in modulating the electronic properties of the nanohybrids.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-10-31 | Chemical communications (Cambridge, England) |